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Journal of Materials Science
Erschienen in: Journal of Materials Science 10/2016

11.02.2016 | Original Paper

Thermodynamics of dye adsorption on electrochemically exfoliated graphene

verfasst von: Zhishuang Xue, Shanlin Zhao, Zenghua Zhao, Ping Li, Jianhui Gao

Erschienen in: Journal of Materials Science | Ausgabe 10/2016

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Abstract

Graphene sheets prepared by electrochemical exfoliation have been used for the adsorption of methylene blue (MB), a cationic dye from aqueous solution. The maximum adsorbed amount of MB on exfoliated graphene (EG) reaches 511.7 mg g−1 when the initial concentration of MB is 500 mg L−1, with EG whose dosage is 10 mg. Further study on the adsorption mechanism of EG includes isothermal adsorption equilibrium, thermodynamics, and kinetics. The study on isothermal adsorption equilibrium shows that the adsorption follows the Langmuir isotherm. Various thermodynamic parameters such as Gibbs free energy (∆G 0), enthalpy (∆H 0), and entropy (∆S 0) change were also evaluated. It indicates that the adsorption is a spontaneous, endothermic, and physical adsorption process. The kinetic data reveals that the adsorption process of MB fits well with the pseudo second-order model. The Weber’s intra-particle diffusion model demonstrates that the adsorption rate is controlled by both external diffusion and intra-particle diffusion. EG as a cationic dye scavenger displays high speed and efficiency.
Vorheriger Artikel Change in failure mode of carbon nanofibers in nanocomposites as a function of loading rate
Nächster Artikel Synthesis and characterization of germanium, copper- and cobalt-substituted ITH-zeotype materials

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Literatur
1.
Yu B, Zhang X, Xie J et al (2015) Magnetic graphene sponge for the removal of methylene blue. Appl Surf Sci 351:765–771CrossRef
2.
Wu T, Cai X, Tan S et al (2011) Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions. Chem Eng J 173:144–149CrossRef
3.
Yang S, Chen S, Chang Y et al (2011) Removal of methylene blue from aqueous solution by graphene oxide. J Colloid Interface Sci 359:24–29CrossRef
4.
Parmar KR, Patel I, Basha S et al (2014) Synthesis of acetone reduced graphene oxide/Fe3O4 composite through simple and efficient chemical reduction of exfoliated graphene oxide for removal of dye from aqueous solution. J Mater Sci 49:6772–6783. doi:10.​1007/​s10853-014-8378-x CrossRef
5.
de Matos JB, Cardoso MJEM, Barcia OE et al (2010) Study of oxygen reduction on copper applied to the peroxidase-mediated oxidation of methylene blue. J Mater Sci 45:1677–1682. doi:10.​1007/​s10853-009-4151-y CrossRef
6.
Chen Z, Chen H, Pan X et al (2015) Investigation of methylene blue biosorption and biodegradation by Bacillus thuringiensis 016. Water Air Soil Pollut 226:146CrossRef
7.
Lamdab U, Wetchakun K, Phanichphant S et al (2015) Highly efficient visible light-induced photocatalytic degradation of methylene blue over InVO4/BiVO4 composite photocatalyst. J Mater Sci 50:5788–5798. doi:10.​1007/​s10853-015-9126-6 CrossRef
8.
Cui L, Guo X, Wei Q et al (2015) Removal of mercury and methylene blue from aqueous solution by xanthate functionalized magnetic graphene oxide: sorption kinetic and uptake mechanism. J Colloid Interface Sci 439:112–120CrossRef
9.
Liu X, Zhou Y, Nie W et al (2015) Fabrication of hydrogel of hydroxypropyl cellulose (HPC)composited with graphene oxide and its application for methylene blue removal. J Mater Sci 50:6113–6123. doi:10.​1007/​s10853-015-9166-y CrossRef
10.
Li C, Zhong H, Wang S et al (2015) Removal of basic dye (methylene blue) from aqueous solution using zeolite synthesized from electrolytic manganese residue. J Ind Eng Chem 23:344–352CrossRef
11.
Elmoubarki R, Mahjoubi FZ, Tounsadi H et al (2015) Adsorption of textile dyes on raw and decanted Moroccan clays: kinetics, equilibrium and thermodynamics. Water Resour Ind 9:16–29CrossRef
12.
Kumar PS, Palaniyappan M, Priyadharshini M et al (2014) Adsorption of basic dye onto raw and surface-modified agricultural waste. Environ Prog Sustain Energy 33:87–98CrossRef
13.
Namazi AB, Jia CQ, Allen DG (2010) Production and characterization of lignocellulosic biomass-derived activated carbon. Water Sci Technol 62:2637–2646CrossRef
14.
Kim H, Kang SO, Park S et al (2015) Adsorption isotherms and kinetics of cationic and anionic dyes on three-dimensional reduced graphene oxide macrostructure. J Ind Eng Chem 21:1191–1196CrossRef
15.
Moradi O, Gupta VK, Agarwal S et al (2015) Characteristics and electrical conductivity of graphene and graphene oxide for adsorption of cationic dyes from liquids: kinetic and thermodynamic study. J Ind Eng Chem 28:294–301CrossRef
16.
17.
Yan H, Tao X, Yang Z et al (2014) Effects of the oxidation degree of graphene oxide on the adsorption of methylene blue. J Hazard Mater 268:191–198CrossRef
18.
Zamani S, Tabrizi N (2015) Removal of methylene blue from water by graphene oxide aerogel: thermodynamic, kinetic, and equilibrium modeling. Res Chem Intermed 41:7945–7963CrossRef
19.
Marcano DC, Kosynkin DV, Berlin JM et al (2010) Improved synthesis of graphene oxide. ACS Nano 4:4806–4814CrossRef
20.
Shen J, Hu Y, Shi M et al (2010) One step synthesis of graphene oxide-magnetic nanoparticle composite. J Phys Chem C 114:1498–1503CrossRef
21.
Parvez K, Li R, Puniredd SR et al (2013) Electrochemically exfoliated graphene as solution-processable, highly conductive electrodes for organic electronics. ACS Nano 7:3598–3606CrossRef
22.
Liu J, Notarianni M, Will G et al (2013) Electrochemically exfoliated graphene for electrode films: effect of graphene flake thickness on the sheet resistance and capacitive properties. Langmuir 29:13307–13314CrossRef
23.
Parvez K, Wu ZS, Li R et al (2014) Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. J Am Chem Soc 136:6083–6091CrossRef
24.
Gee CM, Tseng CC, Wu FY et al (2013) Flexible transparent electrodes made of electrochemically exfoliated graphene sheets from low-cost graphite pieces. Displays 34:315–319CrossRef
25.
Buglione L, Chng ELK, Ambrosi A et al (2012) Graphene materials preparation methods have dramatic influence upon their capacitance. Electrochem Commun 14:5–8CrossRef
26.
Ferrari AC, Basko DM (2013) Raman spectroscopy as a versatile tool for studying the properties of graphene. Nat Nanotechnol 8:235–246CrossRef
27.
Zhou M, Tang J, Cheng Q et al (2013) Few-layer graphene obtained by electrochemical exfoliation of graphite cathode. Chem Phys Lett 572:61–65CrossRef
28.
Abdelkader AM, Kinloch IA, Dryfe RAW (2014) Continuous electrochemical exfoliation of micrometer-Sized graphene using synergistic ion intercalations and organic solvents. ACS Appl Mater Interfaces 6:1632–1639CrossRef
29.
Sing KSW, Everett DH, Haul RAW et al (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619CrossRef
30.
Ai L, Jiang J (2012) Removal of methylene blue from aqueous solution with self-assembled cylindrical graphene-carbon nanotube hybrid. Chem Eng J 192:156–163CrossRef
31.
Zhang W, Zhou C, Zhou W et al (2011) Fast and considerable adsorption of methylene blue dye onto graphene oxide. Bull Environ Contam Toxicol l87:86–90
32.
Liu F, Chung S, Oh G et al (2012) Three-Dimensional graphene oxide nanostructure for fast and efficient water-soluble dye removal. ACS Appl Mater Interfaces 4:922–927CrossRef
33.
Sharma P, Das MR (2013) Removal of a cationic dye from aqueous solution using graphene oxide nanosheets: investigation of adsorption parameters. J Chem Eng Data 58:151–158CrossRef
34.
Cheng C, Deng J, Lei B et al (2013) Toward 3D graphene oxide gels based adsorbents for high-efficient water treatment via the promotion of biopolymers. J Hazard Mater 263:467–478CrossRef
35.
Fu J, Chen Z, Wang M et al (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 259:53–61CrossRef
36.
Bai L, Li Z, Zhang Y et al (2015) Synthesis of water-dispersible graphene-modified magnetic polypyrrole nanocomposite and its ability to efficiently adsorb methylene blue from aqueous solution. Chem Eng J 279:757–766CrossRef
37.
Kumar YP, King P, Prasad VSRK (2006) Zinc. biosorption on Tectona grandis L.f. leaves biomass: equilibrium and kinetic studies. Chem Eng J 124:63–70CrossRef
38.
Ma T, Chang PR, Zheng P et al (2014) Fabrication of ultra-light graphene-based gels and their adsorption of methylene blue. Chem Eng J 240:595–600CrossRef
39.
Aluigi A, Rombaldoni F, Tonetti C et al (2014) Study of Methylene Blue adsorption on keratin nano fibrous membranes. J Hazard Mater 268:156–165CrossRef
40.
Rahman N, Haseen U (2014) Equilibrium modeling, kinetic, and thermodynamic studies on adsorption of Pb(II) by a hybrid inorganic-organic material: polyacrylamide zirconium(IV) iodate. Ind Eng Chem Res 53:8198–8207CrossRef
41.
Eskandarian L, Arami M, Pajootan E (2014) Evaluation of adsorption characteristics of multiwalled carbon nanotubes modified by a poly(propylene imine) dendrimer in single and multiple dye solutions: isotherms, kinetics, and thermodynamics. J Chem Eng Data 59:444–454CrossRef
Metadaten
Titel
Thermodynamics of dye adsorption on electrochemically exfoliated graphene
verfasst von
Zhishuang Xue
Shanlin Zhao
Zenghua Zhao
Ping Li
Jianhui Gao
Publikationsdatum
11.02.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9798-6

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