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Journal of Materials Science

Erschienen in:

10.05.2022 | Composites & nanocomposites

Fabrication of superhydrophobic PVDF membrane based on thiol-ene click chemistry reaction for humidification

verfasst von: Hongyou Jia, Yanan Ge, Huayan Chen, Wenxin Zhang, Xiaolong Lu, Yue Jia

Erschienen in: Journal of Materials Science | Ausgabe 20/2022

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Abstract

To improve the air humidification capacity of polyvinylidene fluoride hollow fiber membranes, surface coating method is applied to superhydrophobicly modify the hollow fiber membranes to achieve high performance. Chemical bonds were used as a bridge to connect the membrane and the coating. Silica is loaded on the membrane surface firstly, and then, polyhedral oligomeric silsesquioxane (POSS) and polydimethylsiloxane containing mercapto groups (PDMS) were introduced on the surface of the membrane through the click reaction to build a superhydrophobic surface with a reentrant structure. Then the effect of the content of POSS and PDMS on the humidification performance was explored. The superhydrophobic membrane coated with SiO₂-PDMS-POSS was obtained, and the surface contact angle was 156.2°. The modification process occurs only on the outer surface of the hollow fiber membrane and not in the cross-sectional pores of the fiber. Besides, the coating of the modified superhydrophobic membrane exhibited excellent mechanical stability. The reentrant structure produced by nano-SiO₂, POSS and the low surface energy of PDMS together gives the composite membrane superhydrophobic characteristics. The results of the humidification experiment shows that the humidification efficiency increased from 48.26 to 58.21%.

Vorheriger Artikel Sandwiched-resistive sensors based on the 3D printing of TPU/CNTs–ILs

Nächster Artikel Synthesis and electromagnetic wave absorbing properties of high-entropy metal diboride-silicon carbide composite powders

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Titel: Fabrication of superhydrophobic PVDF membrane based on thiol-ene click chemistry reaction for humidification
verfasst von: Hongyou Jia
Yanan Ge
Huayan Chen
Wenxin Zhang
Xiaolong Lu
Yue Jia
Publikationsdatum: 10.05.2022
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 20/2022
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-022-07233-5

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