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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 21/2017

08.07.2017

Sol–gel electrospun mesoporous ZnMn2O4 nanofibers with superior specific surface area

verfasst von: C. Shamitha, T. Senthil, Lixin Wu, B. Sachin Kumar, S. Anandhan

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 21/2017

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Abstract

ZnMn2O4 has application potential in lithium ion batteries, supercapacitors, sensors, and thermistors. In this study, mesoporous spinel ZnMn2O4 nanofibers were synthesized by sol–gel assisted electrospinning combined with calcination, using poly(styrene-co-acrylonitrile) as sacrificial polymeric binder. Structural, morphological and optical properties of these ceramic nanofibers were characterized. X-ray diffraction and X-ray photoelectron spectroscopy results revealed the presence of hexagonal ZnMnO3 and MnO phases in the ZnMn2O4 nanofibers produced. Based on these observations we propose a plausible mechanism of formation of ZnMn2O4 nanofibers. The nanofibers calcined at 773 K exhibit a specific surface area of 79.5 m2 g−1, which is higher than that of the zinc manganite nanofibers synthesized hitherto by sol–gel electrospinning. Moreover, this material exhibits four bandgaps, which is believed to be the first observation in ZnMn2O4 nanofibers.
Vorheriger Artikel Thermal analysis, AC conductivity and dielectric relaxation in Bis(2-methoxyanilinium) hexabromidostannate(IV) dihydrate: (C7H10NO)2SnBr6·2H2O
Nächster Artikel Sonication-assisted deposition–precipitation synthesis of graphitic C3N4/BiOCl heterostructured photocatalysts with enhanced rhodamine B photodegradation activity

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Metadaten
Titel
Sol–gel electrospun mesoporous ZnMn2O4 nanofibers with superior specific surface area
verfasst von
C. Shamitha
T. Senthil
Lixin Wu
B. Sachin Kumar
S. Anandhan
Publikationsdatum
08.07.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 21/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7479-0

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