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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 3/2014

01.03.2014 | Original Paper

The effect of carbonate-phthalate plasticizers on structural, morphological and electrical properties of polyacrylonitrile-based solid polymer electrolytes

verfasst von: W. G. Chong, Z. Osman

Erschienen in: Journal of Polymer Research | Ausgabe 3/2014

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Abstract

Polyacrylonitrile (PAN) based solid polymer electrolyte consisting lithium tetrafluoroborate (LiBF4), ethylene carbonate (EC) and dimethyl phthalate (DMP) have been prepared using solution casting method. Comparative studies were done on unplasticized PAN-LiBF4 system and the PAN plasticized system with the novel binary plasticizers of EC and DMP in the ratio of 1:1 by the variation of LiBF4 concentration. The highest room temperature conductivity of electrolyte in PAN-LiBF4 system is 1.83 × 10−3 S cm−1 while 1.08 × 10−2 S cm−1 is obtained from PAN-EC-DMP-LiBF4 system. The complexation and structure of polymer electrolytes have been investigated as function of LiBF4 content at different weight percentages. The morphology and crystalline phase of polymer host is completely changed on the addition of salt and plasticizers. The fraction of free ions is greatly dependent on the amount of salt and the presence of plasticizers.
Vorheriger Artikel First/second generation of dendritic ester-co-aldehyde-terminated poly(amidoamine) as modifying components of melamine urea formaldehyde (MUF) adhesives: subsequent use in particleboards production
Nächster Artikel Blends of 4,4′-diaminodiphenyl methane-based benzoxazine and polysulfone: morphologies and properties

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Metadaten
Titel
The effect of carbonate-phthalate plasticizers on structural, morphological and electrical properties of polyacrylonitrile-based solid polymer electrolytes
verfasst von
W. G. Chong
Z. Osman
Publikationsdatum
01.03.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 3/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0381-z

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