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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2014

01.09.2014 | Original Paper

New polyimide-based porous crosslinked beads by suspension polymerization: physical and chemical factors affecting their morphology

verfasst von: C. Hulubei, C. D. Vlad, I. Stoica, D. Popovici, G. Lisa, S. L. Nica, A. I. Barzic

Erschienen in: Journal of Polymer Research | Ausgabe 9/2014

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Abstract

Synthesis of a new partial-alicyclic copolyimide based on bicyclo [2.2.2] oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BOCA) is presented. This polymer was used to obtain porous microspheres by suspension polymerization method. It is copolymerized with N, N’- 4, 4′- diphenylmethanebismaleimide in the presence of two pairs of porogens: 1-methyl-2-pyrrolidone/benzyl alcohol, and 1,4 Dioxane/benzyl alcohol. Influence of different factors, such as diluents composition or crosslinker concentration, on the resulting polymer beads morphology is studied. Various characteristcis including the specific and apparent densities, porosity, pore volume, surface area and mean pore diameter are analyzed. Thermal behavior and tendency to swell in different organic diluents for some chosen samples are also determined. The best polymer beads, obtained in a reaction system with a solubility parameter value of 23.45 MPa ½ and a crosslinker concentration of 40 %, are thermally stable above 400 ºC, having a pore volume of 1.28 mL/g, a surface area of 74.20 m2/g and enhanced swelling properties.
Nächster Artikel Effects of internal-phase contents on porous polymers prepared by a high-internal-phase emulsion method

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Literatur
1.
Dusek K (1982) Network formation by chain crosslinking (co)polymerization, in Developments in polymerization-3. In: Haward RN (ed) ScD. Publ. Appl. Science publisher in LTD, England
2.
Okay O (2000) Macroporous copolymer networks. Prog Polym Sci 25(6):711–779CrossRef
3.
Clarisse M, Queirуs Y, Barbosa C, Barbosa L, Lucas E (2012) Synthesis and Characterization of Polymeric Resins Based on Methyl Methacrylate and Divinylbenzene. Chemistry & Chemical Technology, The Journal 6(2):145–152
4.
Gawdzik B, Sobiesiak M (2003) Chemical composition of plasma treated polyimide microspheres. Appl Surf Sci 214:52–55CrossRef
5.
Gao JG, Zhang Y, Yu YF, Han YC, Zhang BZ, Gao CH (2011) Preparation of chitosan microspheres loading of 3,5-dihydroxy-4-i-propylstilbene and in vitro release. J Polym Res 18:1501–1508CrossRef
6.
Kun KA, Kunin R (1968) Macroreticular resins. III. Formation of macroreticular styrene–divinylbenzene copolymers. J Polym Sci Part A-1:Polym Chem 6:2689–2701CrossRef
7.
Sederel WL, De Jong GJ (1973) Styrene–divinylbenzene copolymers. Construction of porosity in styrene divinylbenzene matrices. J App Polym Sci 17(9):2835–2846CrossRef
8.
Brooks BW (1990) Basis aspects and recent developement in suspension polymerisation. Makromol Chem, Macromol Symp 35/36:121–140CrossRef
9.
Svec F, Frechet MJ (1996) New design of macroporous polymers and supports from separation to biocatalysis. Science 273:205–21CrossRef
10.
Bortel E (1965) Porous ion exchangers. I. Porosity of styrene-divinylbenzene copolymers. Przemysl Chem 44:255–270
11.
Nicolescu T-V, Meouche W, Branger C, Margaillan A, Sarbu A, Donescu D (2012) Tailor-made polymer beads for gallic acid recognition and separation. J Polym Res 19:2–13CrossRef
12.
Flory PJ (1953) Principles of Polymer Chemistry. Press, Cornell University
13.
Chen CW, Chen CY, Lin CL (2011) Preparation of monodisperse poly (methyl methacrylate)microspheres: effect of reaction parameters on particle formation, and optical performances of its diffusive agent application. J Polym Res 18:587–594CrossRef
14.
Grochowicz M, Bartnicki A, Gawdzik B (2008) Preparation and Characterization of Porous Polymeric Microspheres Obtained from Multifunctional Methacrylate Monomers. J Polym Sci: Part A: Polym Chem 46(18):6165–6174CrossRef
15.
16.
Mathews AS, Kim I, Ha CS (2007) Synthesis, characterization, and properties of fully aliphatic polyimides and their derivatives for microelectronics and optoelectronics applications. Macromol Res 15(2):114–128CrossRef
17.
Wilson D, Stenzenberger HD, Hergenrother PM (1990) Polyimides. Chapman and Hall, New YorkCrossRef
18.
Chisca S, Musteata VE, Stoica I, Sava I, Bruma M (2013) Effect of the chemical structure of aromatic-cycloaliphatic copolyimide films on their surface morphology, relaxation behavior and dielectric properties. J Polym Res 20:111–121CrossRef
19.
Ree M (2006) High performance polyimides for applications in microelectronics and flat panel displays. Macromol Res 14(1):1–33CrossRef
20.
Ando S (2004) Optical Properties of Fluorinated Polyimides and Their Applications to Optical Components and Waveguide Circuits. J Photopolym Sci Technol 17(2):219–232CrossRef
21.
Cosutchi AI, Hulubei C, Stoica I, Ioan S (2011) A new approach for patterning epiclon-based polyimide precursor films using a lyotropic liquid crystal template. J Polym Res 18(6):2389–2402CrossRef
22.
Mittal KL (1984) Polyimides: synthesis, characterization and applications, vol 1 & 2. Springer (Plenum Press), New YorkCrossRef
23.
Ismail AF, Aziz F (2012) Chemical Cross-Linking Modifications of Polymeric Membranes for Gas Separation Applications, Chap. 11. In: Hilal N, Khayet M, Wright CJ (eds) Membrane Modification Technology and Applications. CRC Press, US
24.
Takekoshi T (1996) In: Ghosh MK, Mittal KL (eds) Polyimides: Fundamentals and Applications, vol 1, 1st edn. Marcel Dekker, New York
25.
Chen JC, Tseng WY, Tseng IH, Tsai MH (2011) High transparency and thermal stability of alicyclic polyimide with crosslinking structure by triallylamine. Adv Mater Res 287–290:1388–1396CrossRef
26.
Ioan S, Hulubei C, Popovici D, Musteata VE (2013) Origin of dielectric response and conductivity of some alicyclic polyimides. Polym Eng Sci 53(7):1430–1447CrossRef
27.
Kumar SV, Yu HC, Choi J, Kudo K, Jang YH, Chung CM (2011) Structure–property relationships for partially aliphatic polyimides. J Polym Res 18:1111–1117CrossRef
28.
Chen G, Pei X, Liu J, Fang X (2013) Synthesis and properties of transparent polyimides derived from trans- and cis-1,4-bis(3,4-dicarboxyphenoxy)cyclohexane Dianhydrides. J Polym Res 20:159–169CrossRef
29.
Hou Y, Chen G, Pei X, Fang X (2012) Synthesis and characterization of novel optically transparent and organosoluble polyimides based on diamines containing cyclohexane moiety. J Polym Res 19:9955–9963CrossRef
30.
Barzic AI, Stoica I, Fifere N, Vlad CD, Hulubei C (2013) Morphological effects on transparency and absorption edges of some semi-alicyclic polyimides. J Polym Res 20:130–137CrossRef
31.
Brock T, Sherrington DC, Swindell J (1994) Synthesis and characterisation of porous particulate polyimides. J Mater Chem 4(2):229–236CrossRef
32.
Sherrington D (1998) Preparation, structure and morphology of polymer supports. Chem Commun 21:2275–2286CrossRef
33.
Fu GD, Li GL, Neoh KG, Kang ET (2011) Hollow polymeric nanostructures—Synthesis, morphology and function. Prog Polym Sci 36(1):127–167CrossRef
34.
Ishizaka T, Kasai H (2012) In: Abadie MJM (ed) High Performance Polymers - Polyimides Based - From Chemistry to Applications, Fabrication of Polyimide Porous Nanostructures for Low-k Materials. Novi Sad, InTech
35.
Hren J, Polanc S, Kočevar M (2008) The synthesis and transformations of fused bicyclo[2.2.2]octenes. Special Issue Reviews and Accounts ARKIVOC 209–231 ISSN 1551–7012
36.
Ioan S, Cosutchi AI, Hulubei C, Macocinschi D, Ioanid G (2007) Surface and interfacial properties of poly(amic acid)s and polyimides. Polym Eng Sci 47(4):381–389CrossRef
37.
Dix LR, Ebdon JR, Flint NJ, Hodge P, O’Dell R (1995) Chain extension and crosslinking of telechelic oligomers—I. Michael additions of bisamines to bismaleimides and bis(acetylene ketone)s. Eur Polym J 31(7):647–652CrossRef
38.
Freeman ES, Carroll B (1958) The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate. J Phys Chem 62(4):394–397CrossRef
39.
Brunauer S (1957) Adsorption of Gases and Vapors Princeton University Press. New Jersey Press, New York
40.
Choi YS, Hong SR, Lee YM, Song KW, Park MH, Nam YS (1999) Study on gelatin-containing artificial skin: I. Preparation and characteristics of novel gelatin-alginate sponge Biomaterials 20(5):409–417
41.
Park HY, Song IH, Kim JH, Kim WS (1998) Preparation of thermally denatured albumin gel and its pH-sensitive swelling. Int J Pharm 175(2):231–236CrossRef
42.
ISO 25178–2:2012, Geometrical product specifications (GPS) - Surface texture: Areal - Part 2: Terms, definitions and surface texture parameters
43.
Nic M, Jirat J, Kosata B updates compiled by Jenkins A (1997) IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford. XML on-line corrected version: http://​goldbook.​iupac.​org
44.
Ishida H, Wellinghoff ST, Baer E, Koenig JL (1980) Spectroscopic Studies of Poly [N, N’-bis(phenoxyphenyl)pyromellitimide]. 1. Structures of the Polyimide and Three Model Compounds. Macromolecules 13(4):826–834CrossRef
45.
Kotoulas C, Kiparissides C (2006) A generalized population balance model for the prediction of particle size distribution in suspension polymerization reactors. Chem Eng Sci 61(2):332–346CrossRef
46.
Chatzi EG, Kiparissides C (1994) Drop size distributions in high holdup fraction dispersion systems: effect of the degree of hydrolysis of PVA stabilizer. Chem Eng Sci 49(24, Part 2):5039–5052CrossRef
47.
Jalili K, Abbasi F, Nasiri M, Ghasemi M, Haddadi NDE (2009) Preparation and Characterization of Expandable St/MMA Copolymers Produced by Suspension Polymerization. J Cell Plast 45:197–224CrossRef
48.
Ioan S, Filimon A, Hulubei C, Stoica I, Dunca S (2013) Origin of rheological behavior and surface/interfacial properties of some semi-alicyclic polyimides for biomedical applications. Polym Bull 70(10):2873–2893CrossRef
49.
Jahanzad F, Sajjadi S, Brooks BW (2005) Comparative Study of Particle Size in Suspension Polymerization and Corresponding Monomer − Water Dispersion. Ind Eng Chem Res 44(11):4112–4119CrossRef
50.
Svec F, Frechet JMJ (1995) Temperature, a Simple and Efficient Tool for the Control of Pore Size Distribution in Macroporous Polymers. Macromolecules 28(22):7580–7582CrossRef
51.
Koenhen DM, Smolders CA (1975) The determination of solubility parameters of solvents and polymers by means of correlations with other physical quantities. J Appl Polym Sci 19(4):1163–1179CrossRef
52.
van Krevelen DW, te Nijenhuis K (2009) Properties of Polymers: Their Correlation with Chemical Structure; their Numerical Estimation and Prediction from Additive Group Contributions. Elsevier Science, Amsterdam
53.
Allan F, Barton M (1983) Handbook of Solubility Parameters, Ph.D. Thesis. CRC Press, 153–157
54.
Chompff A J, Newman S, Society A C (1971) Polymer networks: structure and mechanical properties: proceedings. Press, Plenum
55.
Small PA (1953) Some factors affecting the solubility of polymers. J Appl Chem 3(2):71–80CrossRef
56.
Stoica I, Barzic AI, Hulubei C, Timpu T (2013) Statistical Analysis on Morphology Development of Some Semi-alicyclic Polyimides Using Atomic Force Microscopy Microsc. Res Techn 76:503–513CrossRef
57.
Marcu Puscas T, Signorini M, Molinari A, Straffelini G (2003) Image analysis investigation of the effect of the process variables on the porosity of sintered chromium steels. Mater Character 50(1):1–10CrossRef
58.
Dickie RA, Labana SS, Bauer RS, Science ACSDoPM, Engineering (1988) Cross-Linked Polymers: Chemistry, Properties, and Applications. American Chemical Society
59.
Silverstein MS, Cameron NR, Hillmyer MA (2011) Porous Polymers. Wiley
60.
Calvino-Casilda V, Lopez-Peinado AJ, Vaganova E, Yitzchaik S, Pacios IE, Pierola IF (2008) Porosity Inherent to Chemically Crosslinked Polymers. Poly(N-vinylimidazole) Hydrogels. J Phys Chem B 112(10):2809–2817CrossRef
61.
Poinescu I, Vlad C, Carpov A, Ioanid A (1988) On the structure of macroreticular styrene-divinylbenzene copolymers. Die Angewandte Makromolekulare Chemie 156(1):105–121CrossRef
Metadaten
Titel
New polyimide-based porous crosslinked beads by suspension polymerization: physical and chemical factors affecting their morphology
verfasst von
C. Hulubei
C. D. Vlad
I. Stoica
D. Popovici
G. Lisa
S. L. Nica
A. I. Barzic
Publikationsdatum
01.09.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0514-4

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