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Journal of Polymer Research

Erschienen in:

01.10.2020 | ORIGINAL PAPER

RETRACTED ARTICLE: Synthesis and characterization of a novel locally high dense sulfonated poly (aryl ether ketone sulfone) for DMFCs applications

verfasst von: Chengyun Yuan, Yinghan Wang

Erschienen in: Journal of Polymer Research | Ausgabe 10/2020

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Abstract

A new sulfonated poly (aryl ether ketone sulfone) (SPAEKS-x) with locally dense sulfonic acid groups is synthesized by post-sulfonation. The SPAEKS-x membranes have a number average molecular weight of 45,000–58,000 g/mol and exhibit excellent mechanical properties. In addition, SPAEKS-x membranes have moderate water absorption, swelling rate, excellent thermal stability and good oxidative stability. The proton conductivity of SPAEKS-x membranes ranges from 35.6 to 52.4 mS/cm. All membranes show much lower methanol permeability than Nafion 117 membrane. Therefore, all membranes show higher proton selectivity than Nafion 117 membrane. In particularly, proton selectivity of SPAEKS-40 (15.8 × 10⁴ S s cm⁻³) is about 5 times higher than that of Nafion 117 membrane (3.5 × 10⁴ S s cm⁻³). Overall, SPAEKS-x membranes as a proton exchange membrane have shown very great application prospects in direct methanol fuel cells.

Vorheriger Artikel Using facile one-pot thiol-ene reaction to prepare elastomers filled with silica

Nächster Artikel Study of thermomechanical properties of glycidoxypropyl trimethoxy silane functionalized nanosilica/amine terminated poly (butadiene-co-acrylonitrile) rubber modified novolac epoxy composites for high performance applications

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Titel: RETRACTED ARTICLE: Synthesis and characterization of a novel locally high dense sulfonated poly (aryl ether ketone sulfone) for DMFCs applications
verfasst von: Chengyun Yuan
Yinghan Wang
Publikationsdatum: 01.10.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 10/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-020-02282-3

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