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Erschienen in: Journal of Sol-Gel Science and Technology 2/2012

01.05.2012 | Original Paper

Sol–gel synthesis of Eu3+ incorporated CaMoO4: the enhanced luminescence performance

verfasst von: Haoyi Wu, Yihua Hu, Wei Zhang, Fengwen Kang, Nana Li, Guifang Ju

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2012

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Abstract

In order to develop high efficiency red emitting phosphors, Ca0.76MoO4: Eu 0.24 3+ samples are investigated via sol–gel and solid state reaction. The XRD analysis reveals that both methods can synthesize phosphors with tetragonal CaMoO4 phase successfully. Smaller crystal size of samples prepared by sol–gel can be observed, and the grain size of these samples are around 100–200 nm, which is also smaller than the one prepared by solid state reaction. All phosphors present a red emission at 616 nm wavelength and one sol–gel synthesized sample exhibits the strongest emission intensity because of the higher quantum efficiency. It is attributed to the removal of lattice defects by sol–gel, in which way luminescent efficiency is enhanced. This can be reflected by the longer fluorescent lifetime of phosphors.

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Literatur
1.
Zurück zum Zitat Nishiura S, Tanabe S, Fujioka K, Fujimoto Y (2011) Properties of transparent Ce: YAG ceramic phosphors for white LED. Optic Mater 33:688–691CrossRef Nishiura S, Tanabe S, Fujioka K, Fujimoto Y (2011) Properties of transparent Ce: YAG ceramic phosphors for white LED. Optic Mater 33:688–691CrossRef
2.
Zurück zum Zitat Won CW, Nersisyan HH, Won HI, Youn JW (2011) Integrated chemical process for exothermic wave synthesis of high luminance YAG: Ce phosphors. J Lumin 131:2174–2180CrossRef Won CW, Nersisyan HH, Won HI, Youn JW (2011) Integrated chemical process for exothermic wave synthesis of high luminance YAG: Ce phosphors. J Lumin 131:2174–2180CrossRef
3.
Zurück zum Zitat Wang Z, Liang H, Gong M, Su Q (2007) Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure. J Alloys Compd 432:308–312CrossRef Wang Z, Liang H, Gong M, Su Q (2007) Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure. J Alloys Compd 432:308–312CrossRef
4.
Zurück zum Zitat Ci Z, Wang Y, Zhang J, Sun Y (2008) Ca1−xMo1−ySiyO4: Eu x 3+ : a novel red phosphor for white light emitting diodes. Phys B 403:670–674CrossRef Ci Z, Wang Y, Zhang J, Sun Y (2008) Ca1−xMo1−ySiyO4: Eu x 3+ : a novel red phosphor for white light emitting diodes. Phys B 403:670–674CrossRef
5.
Zurück zum Zitat Wang XX, Xian YL, Shi JX, Su Q, Gong ML (2007) The potential red emitting Gd2−y Eu y (WO4)3−x (MoO4) x phosphors for UV InGaN-based light-emitting diode. Mater Sci Eng B 140:69–72CrossRef Wang XX, Xian YL, Shi JX, Su Q, Gong ML (2007) The potential red emitting Gd2−y Eu y (WO4)3−x (MoO4) x phosphors for UV InGaN-based light-emitting diode. Mater Sci Eng B 140:69–72CrossRef
6.
Zurück zum Zitat Hu Y, Zhang W, Ye H, Wang D, Zhang S, Huang X (2005) A novel red phosphor for white light emitting diodes. J Alloys Compd 390:226–229CrossRef Hu Y, Zhang W, Ye H, Wang D, Zhang S, Huang X (2005) A novel red phosphor for white light emitting diodes. J Alloys Compd 390:226–229CrossRef
7.
Zurück zum Zitat Yan S, Zhang J, Zhang X, Lu S, Ren X, Nie Z, Wang X (2007) Enhanced red emission in CaMoO4: Bi3+, Eu3+. J Phys Chem C 111:13256–13260CrossRef Yan S, Zhang J, Zhang X, Lu S, Ren X, Nie Z, Wang X (2007) Enhanced red emission in CaMoO4: Bi3+, Eu3+. J Phys Chem C 111:13256–13260CrossRef
8.
Zurück zum Zitat Liu J, Lian H, Shi C (2007) Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4: Eu3+. Optic Mater 29:1591–1594CrossRef Liu J, Lian H, Shi C (2007) Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4: Eu3+. Optic Mater 29:1591–1594CrossRef
9.
Zurück zum Zitat Xie A, Yuan X, Hai S, Wang J, Wang F, Li L (2009) Enhancement emission intensity of CaMoO4: Eu3+, Na+ phosphor via Bi co-doping and Si substitution for application to white LEDs. J Phys D Appl Phys 42:105107CrossRef Xie A, Yuan X, Hai S, Wang J, Wang F, Li L (2009) Enhancement emission intensity of CaMoO4: Eu3+, Na+ phosphor via Bi co-doping and Si substitution for application to white LEDs. J Phys D Appl Phys 42:105107CrossRef
10.
Zurück zum Zitat Zhou Y, Liu J, Yang X, Yu X, Wang L (2011) Self-assembly and photoluminescence characterization of CaMoO4: Eu3+, Na+ superstructure via a facile surfactant-free hydrothermal method. J Electrochem Soc 158:K74–K80CrossRef Zhou Y, Liu J, Yang X, Yu X, Wang L (2011) Self-assembly and photoluminescence characterization of CaMoO4: Eu3+, Na+ superstructure via a facile surfactant-free hydrothermal method. J Electrochem Soc 158:K74–K80CrossRef
11.
Zurück zum Zitat Parchur AK, Ningthoujam RS (2011) Preparation and structure refinement of Eu3+ doped CaMoO4 nanoparticles. Dalton Trans 40:7590–7594CrossRef Parchur AK, Ningthoujam RS (2011) Preparation and structure refinement of Eu3+ doped CaMoO4 nanoparticles. Dalton Trans 40:7590–7594CrossRef
12.
Zurück zum Zitat Parchur AK, Ningthoujam RS, Rai SB, Okram GS, Singh RA, Tyagi M, Gadkari SC, Tewari R, Vatsa RK (2011) Luminescence properties of Eu3+ doped CaMoO4 nanoparticles. Dalton Trans 40:7595–7601CrossRef Parchur AK, Ningthoujam RS, Rai SB, Okram GS, Singh RA, Tyagi M, Gadkari SC, Tewari R, Vatsa RK (2011) Luminescence properties of Eu3+ doped CaMoO4 nanoparticles. Dalton Trans 40:7595–7601CrossRef
13.
Zurück zum Zitat Yang Y, Li X, Feng W, Yang W, Li W, Tao C (2011) Effect of surfactants on morphology and luminescent properties of CaMoO4: Eu3+ red phosphors. J Alloy Compd 509:845–848CrossRef Yang Y, Li X, Feng W, Yang W, Li W, Tao C (2011) Effect of surfactants on morphology and luminescent properties of CaMoO4: Eu3+ red phosphors. J Alloy Compd 509:845–848CrossRef
14.
Zurück zum Zitat Zhou L, Wang L, Gong F, Wei J (2007) Synthesis and photoluminescence of CaMoO4 superfine powder. Nat Sci (EdGuangxi University) 32:394–397 (in Chinese) Zhou L, Wang L, Gong F, Wei J (2007) Synthesis and photoluminescence of CaMoO4 superfine powder. Nat Sci (EdGuangxi University) 32:394–397 (in Chinese)
15.
Zurück zum Zitat Patterson AL (1939) The Scheerer formula for X-Ray particle size determination. Phys Rew 56:978–982CrossRef Patterson AL (1939) The Scheerer formula for X-Ray particle size determination. Phys Rew 56:978–982CrossRef
16.
Zurück zum Zitat Ha MG, Lee JH, Bae JS, Kim JP, Hong KS, Yang HS (2011) Photophysical properties of highly efficient red-emitting CaTiO3: Eu3+ phosphors under near ultra-violet excitation. Curr Appl Phys 11:1379–1383CrossRef Ha MG, Lee JH, Bae JS, Kim JP, Hong KS, Yang HS (2011) Photophysical properties of highly efficient red-emitting CaTiO3: Eu3+ phosphors under near ultra-violet excitation. Curr Appl Phys 11:1379–1383CrossRef
17.
Zurück zum Zitat Chambers MD, Rousseve PA, Clarke DR (2009) Decay pathway and high-temperature luminescence of Eu3+ in Ca2Gd8Si6O26. J Lumin 129:263–269CrossRef Chambers MD, Rousseve PA, Clarke DR (2009) Decay pathway and high-temperature luminescence of Eu3+ in Ca2Gd8Si6O26. J Lumin 129:263–269CrossRef
18.
Zurück zum Zitat Rakov N, Ramos FE, Hirata G, Xiao M (2003) Strong photoluminescence and cathodoluminescence due to f–f transitions in Eu3+ doped Al2O3 powders prepared by direct combustion synthesis and thin films deposited by laser ablation. Appl Phys Lett 83:272–274CrossRef Rakov N, Ramos FE, Hirata G, Xiao M (2003) Strong photoluminescence and cathodoluminescence due to ff transitions in Eu3+ doped Al2O3 powders prepared by direct combustion synthesis and thin films deposited by laser ablation. Appl Phys Lett 83:272–274CrossRef
19.
Zurück zum Zitat Werts MHV, Jukes RTF, Verhoeven JW (2002) The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes. Phys Chem Chem Phys 4:1542–1548CrossRef Werts MHV, Jukes RTF, Verhoeven JW (2002) The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complexes. Phys Chem Chem Phys 4:1542–1548CrossRef
20.
Zurück zum Zitat Sakka S (2005) Handbook of sol–gel science and technology: processing, characterization and applications, volume II: characterization of sol–gel materials and products. Kluwer Academic Publishers, Heidelberg, pp 359–388 Sakka S (2005) Handbook of sol–gel science and technology: processing, characterization and applications, volume II: characterization of sol–gel materials and products. Kluwer Academic Publishers, Heidelberg, pp 359–388
21.
Zurück zum Zitat Ribeiro SJL, Dahmouche K, Ribeiro CA, Santilli CV, Pulcinelli SH (1998) Study of hybrid silica-polyethyleneglycol xerogels by Eu3+ luminescence spectroscopy. J Sol–Gel Sci Techn 13:427–432 Ribeiro SJL, Dahmouche K, Ribeiro CA, Santilli CV, Pulcinelli SH (1998) Study of hybrid silica-polyethyleneglycol xerogels by Eu3+ luminescence spectroscopy. J Sol–Gel Sci Techn 13:427–432
22.
Zurück zum Zitat Cao FB, Li LS, Tian YW, Chen YJ, Wu XR (2011) Investigation of red-emission phosphors (Ca, Sr)(Mo, W)O: Eu3+ crystal structure, luminous characteristics and calculation of Eu3+ 5D0 quantum efficiency. Thin Solid Films 519:7971–7976CrossRef Cao FB, Li LS, Tian YW, Chen YJ, Wu XR (2011) Investigation of red-emission phosphors (Ca, Sr)(Mo, W)O: Eu3+ crystal structure, luminous characteristics and calculation of Eu3+ 5D0 quantum efficiency. Thin Solid Films 519:7971–7976CrossRef
Metadaten
Titel
Sol–gel synthesis of Eu3+ incorporated CaMoO4: the enhanced luminescence performance
verfasst von
Haoyi Wu
Yihua Hu
Wei Zhang
Fengwen Kang
Nana Li
Guifang Ju
Publikationsdatum
01.05.2012
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2012
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-012-2716-8

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