Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 2/2017

20.05.2017 | Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Chelate route for the synthesis of PbZrxTi1−xO3 thin films

verfasst von: L. Imhoff, S. Barolin, N. Pellegri, M. G. Stachiotti

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A chemical solution deposition route using the chelate approach was developed for the synthesis of PbZrxTi1−xO3 thin films. The route avoids the highly toxic 2-methoxyethanol used in previous formulations and offers the advantage of a simple and rapid solution synthesis without the need of distillation and refluxing strategies. The use of acetoin as chelating agent allows a transition between amorphous and final perovskite phases with no segregation of secondary phases during film growth. The obtained PbZrxTi1−xO3 films presented a thickness of ∼150 nm and exhibited good dielectric and ferroelectric properties. It was found that rapid thermal annealing facilitates the perovskite formation process and produces films with better ferroelectric properties than those sintered in conventional furnaces.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-017-4414-z/MediaObjects/10971_2017_4414_Figa_HTML.gif
Vorheriger Artikel Interplay of dopants and defects in magnetic evolution of La and Fe co-doped TiO 2 nanoparticle
Nächster Artikel Magnetic and optical properties of Cu1−xFexO nanosheets prepared by the hydrothermal method

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Izyumskaya N, Alivov Y-I, Cho S-J, Morko H, Lee H, Kang Y-S (2007) Processing, structure, properties and applications of PZT thin films. Crit Rev Solid State Mater Sci 32:111–202CrossRef
2.
Schwartz RS, Schneller T, Waser R (2004) Chemical solution deposition of electronic oxide films. C R Chim 7:433–461CrossRef
3.
Pandey SK, James AR, Raman R, Chatterjee SN, Goyal A, Prakash C, Goel TC (2005) Structural, ferroelectric and optical properties of PZT thin films. Physica B 369:135–142CrossRef
4.
Guo H, Bao D, Zhang Y (2008) Characterization of PZT ferroelectric thin films prepared by a modified sol-gel method. IEEE International Ultrasonics Symposium Proceedings 2130–2133.
5.
Mirzaei A, Bonyani M, Torkian S (2016) Synthesis and characterization of nanocrystalline PZT powders: from sol to dense ceramics. Process Appl Ceram 10(1):9–16CrossRef
6.
Schwartz RW (1997) Chemical solution deposition of perovskite thin films. Chem Mater 9:2325–2340CrossRef
7.
Bel Hadj Tahar R, Bel Hadj Tahar N, Ben Salah A (2007) Preparation and characterization of PZT solid solutions via sol–gel process. J Cryst Growth 307:40–43CrossRef
8.
Machado R, Santiago ML, Stachiotti MG, Frattini A, Pellegri N, Bolmaro R, de Sanctis O (2008) Effects of acetoin as chelating agent on the preparation of SrBi2Ta2O9 thin films from non-hydrolyzing precursors. J Sol-Gel Sci Techn 48:294–302CrossRef
9.
Ohya T, Kabata M, Ban T, Ohya Y, Takahashi Y (2002) Effect of α-hydroxyketones as chelate ligands on dip-coating of zirconia thin films. J Sol-Gel Sci Techn 25:43–50CrossRef
10.
Takahashi Y, Ohsugi A, Arafuka T, Ohya T, Ban T, Ohya Y (2000) Development of new modifiers for titanium alkoxide-based sol-gel process. J Sol-Gel Sci Techn 17:227–238CrossRef
11.
Doeuff S, Henry M, Sanchez C, Livage J (1987) Hydrolysis of titanium alkoxides: modification of the molecular precursor by acetic acid. J Non-Crys Solids 89:206–216CrossRef
12.
Shakeri A, Abdizadeh H, Golobostanfard MR (2014) Synthesis and characterization of thik PZT films via sol-gel dip coating method. Appl Surf Sci 314:711–719CrossRef
13.
Coffman PR, Barlingay CK, Gupta A, Dey SK (1996) Structure evolution in the PbO-ZrO2-TiO2 sol-gel system: part II-pyrolysis of acid and base-catalyzed bulk and thin film gels. J Sol-Gel Sci Techn 6:83–106CrossRef
14.
De-Qing Z, Shao-Jun W, Hong-Shan S, Xiu-Li W, Mao-Sheng C (2007) Synthesis and mechanism research of an ethylene glycol-based sol-gel method for preparing PZT nanopowders. J Sol-Gel Sci Techn 41:157–161CrossRef
15.
Fè JL, Norga G, Wouters DJ, Nouwen R, Van Poucke LC (2000) Absorption-reflection infrared spectroscopy studies of sol-gel prepared ferroelectric Pb(Zr,Ti)O3 thin films on Pt electrodes. J Sol-Gel Sci Techn 19:149–152CrossRef
16.
Méndez-Vivar J, Mendoza-Serna R, Gómez-Lara J, Gaviño R (1997) Spectroscopic study of SiO2-TiO2 sols prepared using stabilizing agents. J Sol-Gel Sci Techn 8:235–241
17.
Chapin L, Myers SA (1990) Microstructural characterization of ferroelectric thin films for non-volatile memory applications. Mater Res Soc Symp Proc Fall 200:231–235CrossRef
18.
Thomas R, Varadan VK, Komerneni S, Dube DC (2001) Diffuse phase transition, electrical conduction, and low temperature dielectric properties of sol-gel derived ferroelectric barium titanate thin films. J Appl Phys 90:1480–1488CrossRef
19.
Li J, Wang C, Liu M, Ma J (2013) Effect of annealing process on properties of Pb(Zr0.52Ti0.48)O3 thin films prepared by sol-gel method. Ferroelectrics 445:32–38CrossRef
20.
Xiao M, Li S, Lei Z (2015) Study of (111)-oriented PZT thin films prepared by a modified sol-gel method. J Mater Sci Mater Electron 26:4031–4037CrossRef
Metadaten
Titel
Chelate route for the synthesis of PbZrxTi1−xO3 thin films
verfasst von
L. Imhoff
S. Barolin
N. Pellegri
M. G. Stachiotti
Publikationsdatum
20.05.2017
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4414-z

Weitere Artikel der Ausgabe 2/2017

Journal of Sol-Gel Science and Technology 2/2017 Zur Ausgabe

Original Paper: Fundamentals of sol-gel and hybrid materials processing

Synthesis and characterization of oxime-modified phenylimido vanadium(V) isopropoxide and their hydrolytic study

Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Interplay of dopants and defects in magnetic evolution of La and Fe co-doped TiO 2 nanoparticle

Original Paper: Sol-gel, hybrids and solution chemistries

Hybrid polymer incorporating BN particles: Thermal, mechanical, and electrical properties

Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Sol–gel-derived Yb:YAG polycrystalline ceramics for laser applications

Original Paper: Fundamentals of sol-gel and hybrid materials processing

Preparation and grain-growth of chromia-yttrium aluminum garnet composites fibers by sol–gel method

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Photocatalytic activity inhancement of TiO2 nanoparticles with lanthanide ions and sandwich-type polyoxometalates

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise