nach oben

Journal of Sol-Gel Science and Technology

Erschienen in:

31.05.2018 | Original paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Novel synthetic route for low-cost carbon-modified TiO₂ with enhanced visible light photocatalytic activity: carbon content and calcination effects

verfasst von: Nicolas Perciani de Moraes, Maria Lucia Caetano Pinto da Silva, Tiago Moreira Bastos Campos, Gilmar Patrocínio Thim, Liana Alvares Rodrigues

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The aim of this study was the development of low-cost tannin-formaldehyde xerogel/TiO₂ (XTi-w) and carbon xerogel/TiO₂ (XTiC-w) photocatalysts. The materials used as precursors were recycled titanium scraps and black wattle tannin extract, highlighting the low-cost approach employed in the synthesis. The materials were characterized by diffuse reflectance spectroscopy, scanning electron microscopy, dispersive energy spectrophotometry, X-ray diffractometry, infrared and Raman spectroscopy. X-ray diffractometry showed that the XTiC-w have tetragonal crystalline structure (anatase), whereas the XTi-w has an amorphous structure. The Raman and infrared analysis also showed the presence of titanium dioxide in the composition of both XTi-w and XTiC-w. XTi-w and XTiC-w showed photocatalytic activity at the visible wavelength. Titanium dioxide displayed no photocatalytic activity at the visible wavelength. The XTi-60 composite displayed the highest efficiency in the removal of the methylene blue from the system, as well as good reusability properties. The radicals with higher influence in the photocatalytic reaction mechanism are the photo generated electron and the singlet oxygen molecule. The effect of the heat treatment is negative on the photocatalytic properties of the hybrids produced, due to the removal of acid sites, adsorbed water and OH surface groups.

Vorheriger Artikel Sintering properties of sol–gel derived lithium disilicate glass ceramics

Nächster Artikel Influence of solvent and pH on the synthesis of visible light active titanium dioxide nano particles

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Kasiri MB, Aleboyeh H, Aleboyeh a (2008) Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst. Appl Catal B Environ 84:9–15. https://doi.org/10.1016/j.apcatb.2008.02.024 CrossRef

Etaiw SEH, El-bendary MM (2012) Degradation of methylene blue by catalytic and photo-catalytic processes catalyzed by the organotin-polymer 3∞[(Me₃Sn)₄Fe(CN)₆]. Appl Catal B Environ 126:326–333. https://doi.org/10.1016/j.apcatb.2012.07.032 CrossRef

Thakur M, Sharma G, Ahamad T, Ghfar AA, Pathania D, Naushad M (2017) Efficient photocatalytic degradation of toxic dyes from aqueous environment using gelatin-Zr(IV) phosphate nanocomposite and its antimicrobial activity. Colloids Surf B Biointerfaces 157:456–463. https://doi.org/10.1016/j.colsurfb.2017.06.018 CrossRef

Bilal M, Asgher M, Parra-Saldivar R, Hu H, Wang W, Zhang X, Iqbal HMN (2017) Immobilized ligninolytic enzymes: an innovative and environmental responsive technology to tackle dye-based industrial pollutants – a review. Sci Total Environ 576:646–659. https://doi.org/10.1016/j.scitotenv.2016.10.137 CrossRef

Zhang S, Zhu D, Shi Q, Cheng M (2018) Which countries are more ecologically efficient in improving human well-being? An application of the index of ecological well-being performance. Resour Conserv Recycl 129:112–119. https://doi.org/10.1016/j.resconrec.2017.10.015 CrossRef

Baker L (2017) Of embodied emissions and inequality: rethinking energy consumption,. Energy Res Soc Sci 36:52–60. https://doi.org/10.1016/j.erss.2017.09.027 CrossRef

Rawat D, Sharma RS, Karmakar S, Arora LS, Mishra V (2018) Ecotoxic potential of a presumably non-toxic azo dye. Ecotoxicol Environ Saf 148:528–537. https://doi.org/10.1016/j.ecoenv.2017.10.049 CrossRef

Boyes SJ, Elliott M, Murillas-Maza A, Papadopoulou N, Uyarra MC (2016) Is existing legislation fit-for-purpose to achieve Good Environmental Status in European seas? Mar Pollut Bull 111:18–32. https://doi.org/10.1016/j.marpolbul.2016.06.079 CrossRef

Zeng Z, Chen S, Tan TTY, Xiao FX (2018) Graphene quantum dots (GQDs) and its derivatives for multifarious photocatalysis and photoelectrocatalysis. Catal. Today. 0–1. https://doi.org/10.1016/j.cattod.2018.01.005.

10.

Flores N, Sharif F, Yasri N, Brillas E, Sirés I, Roberts EPL (2018) Removal of tyrosol from water by adsorption on carbonaceous materials and electrochemical advanced oxidation processes. Chemosphere. https://doi.org/10.1016/j.chemosphere.2018.03.028.

11.

Ge M, Liu L, Chen W, Zhou Z (2012) Sunlight-driven degradation of Rhodamine B by peanut-shaped porous BiVO₄ nanostructures in the H₂O₂-containing system. CrystEngComm 14:1038. https://doi.org/10.1039/c1ce06264f CrossRef

12.

Bandara J, Kuruppu SS, Pradeep UW (2006) The promoting effect of MgO layer in sensitized photodegradation of colorants on TiO₂/MgO composite oxide, colloids. Surf A Physicochem Eng Asp 276:197–202. https://doi.org/10.1016/j.colsurfa.2005.10.059 CrossRef

13.

Basturk E, Karatas M (2015) Decolorization of antraquinone dye Reactive Blue 181 solution by UV/H₂O₂ process. J Photochem Photobiol A Chem 299:67–72. https://doi.org/10.1016/j.jphotochem.2014.11.003 CrossRef

14.

Peng Z, Liu X, Lin G (2016) The synergistic degreasing treatment of background irradiated photocatalysis and microreactor. Catal Commun 90:79–82. https://doi.org/10.1016/j.catcom.2016.11.008 CrossRef

15.

Macedo L, Pauli E (2006) Remediação de águas residuais por Fotocatálise Heterogênea: Estudo dosparâmetros experimentais aplicados a fotocatálise eletroquímica Semin Ciências Exatas 27:11–21CrossRef

16.

Kudo A, Miseki Y (2009) Heterogeneous photocatalyst materials for water splitting. Chem Soc Rev 38:253–78. https://doi.org/10.1039/b800489g CrossRef

17.

de Souza ML, Corio P (2013) Effect of silver nanoparticles on TiO₂-mediated photodegradation of Alizarin Red S. Appl Catal B Environ 136–137:325–333. https://doi.org/10.1016/j.apcatb.2013.02.012 CrossRef

18.

Han F, Kambala VSR, Srinivasan M, Rajarathnam D, Naidu R (2009) Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: a review. Appl Catal A Gen 359:25–40. https://doi.org/10.1016/j.apcata.2009.02.043 CrossRef

19.

Li J, Xu X, Liu X, Qin W, Wang M, Pan L (2017) Metal-organic frameworks derived cake-like anatase/rutile mixed phase TiO₂ for highly efficient photocatalysis. J Alloy Compd 690:640–646. https://doi.org/10.1016/j.jallcom.2016.08.176 CrossRef

20.

Tan P, Chen X, Wu L, Shang YY, Liu W, Pan J, Xiong X (2017) Hierarchical flower-like SnSe₂ supported Ag₃PO₄ nanoparticles: towards visible light driven photocatalyst with enhanced performance. Appl Catal B Environ 202:326–334. https://doi.org/10.1016/j.apcatb.2016.09.033 CrossRef

21.

Yao J, Chen H, Jiang F, Jiao Z, Jin M (2017) Titanium dioxide and cadmium sulfide co-sensitized graphitic carbon nitride nanosheets composite photocatalysts with superior performance in phenol degradation under visible-light irradiation. J Colloid Interface Sci 490:154–162. https://doi.org/10.1016/j.jcis.2016.11.051 CrossRef

22.

Rodrigues LA, Parmentier J, Parra JB, patrocínio Thim G (2013) Preparation of nodular carbon cryogel from simple and inexpensive polycondensation reaction of commercial modified black wattle tannin. J Sol-Gel Sci Technol 67:519–526. https://doi.org/10.1007/s10971-013-3109-3 CrossRef

23.

Pekala RW, Alviso CT, Kong FM, Hulsey SS (1992) Aerogels derived from multifunctional organic monomers Journal of Non-Crystalline Solids 145:90–98CrossRef

24.

Al-Muhtaseb SA, Ritter JA (2003) Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv Mater 15:101–114. https://doi.org/10.1002/adma.200390020 CrossRef

25.

Sánchez-Martín J, Beltrán-Heredia J, Carmona-Murillo C (2011) Adsorbents from Schinopsis balansae: optimisation of significant variables. Ind Crops Prod 33:409–417. https://doi.org/10.1016/j.indcrop.2010.10.038 CrossRef

26.

Queiroz EA, Morais CRAAQ, Nascimento SAL (2002) Caracterizaçao dos taninos da aroeira-preta. Árvore 26:485–492CrossRef

27.

Amaral-Labat G, Szczurek A, Fierro V, Stein N, Boulanger C, Pizzi A, Celzard A (2012) Pore structure and electrochemical performances of tannin-based carbon cryogels. Biomass Bioenergy 39:274–282. https://doi.org/10.1016/j.biombioe.2012.01.019 CrossRef

28.

Szczurek A, Amaral-Labat G, Fierro V, Pizzi A, Masson E, Celzard A (2011) The use of tannin to prepare carbon gels. Part I: carbon aerogels. Carbon N Y 49:2773–2784. https://doi.org/10.1016/j.carbon.2011.03.007 CrossRef

29.

de Moraes NP, Carvalho T, da Silva MLCP, Rodrigues LA, Thim GP, Campos TMB (2017) A novel synthesis route of titanium dioxide with (NH₄)_0.3TiO_1.1F_2.1 as byproduct. Ceram Int 43:13677–13682. https://doi.org/10.1016/j.ceramint.2017.07.078 CrossRef

30.

de Moraes NP, Bacani R, da Silva MLCP, Campos TMB, Thim GP, Rodrigues LA (2018) Effect of Nb/C ratio in the morphological, structural, optical and photocatalytic properties of novel and inexpensive Nb₂O₅/carbon xerogel composites. Ceram Int 0–1. https://doi.org/10.1016/j.ceramint.2018.01.073.

31.

Mishra AK, Ramaprabhu S (2011) Carbon dioxide adsorption in graphene sheets. AIP Adv 1:0–6. https://doi.org/10.1063/1.3638178

32.

El-Sheikh SM, Khedr TM, Hakki A, Ismail AA, Badawy WA, Bahnemann DW (2017) Visible light activated carbon and nitrogen co-doped mesoporous TiO₂ as efficient photocatalyst for degradation of ibuprofen. Sep Purif Technol 173:258–268. https://doi.org/10.1016/j.seppur.2016.09.034 CrossRef

33.

do Prado NT, Oliveira LCA (2017) Nanostructured niobium oxide synthetized by a new route using hydrothermal treatment: high efficiency in oxidation reactions. Appl Catal B Environ 205:481–488. https://doi.org/10.1016/j.apcatb.2016.12.067 CrossRef

34.

Bailón-García E, Elmouwahidi A, Álvarez MA, Carrasco-Marín F, Pérez-Cadenas AF, Maldonado-Hódar FJ (2017) New carbon xerogel-TiO₂ composites with high performance as visible-light photocatalysts for dye mineralization. Appl Catal B Environ 201:29–40. https://doi.org/10.1016/j.apcatb.2016.08.015 CrossRef

35.

Rashidzadeh M (2008) Synthesis of high-thermal stable titanium dioxide nanoparticles, Int J Photoenergy. https://doi.org/10.1155/2008/245981.

36.

Busca G, Marchetti L, Centi G, Trifirò F (1985) Surface characterization of a grafted vanadium-titanium dioxide catalyst, J Chem Soc Faraday Trans 1 Phys Chem Condens Phases 1003–1014. https://doi.org/10.1039/F19858101003.

37.

Ma X, Chen Y, Li H, Cui X, Lin Y (2015) Annealing-free synthesis of carbonaceous Nb₂O₅ microspheres by flame thermal method and enhanced photocatalytic activity for hydrogen evolution. Mater Res Bull 66:51–58. https://doi.org/10.1016/j.materresbull.2015.02.005 CrossRef

38.

Rodrigues LA, Campos TMB, Alvarez-Mendes MO, Coutinho ADR, Sakane KK, Thim GP (2012) Phenol removal from aqueous solution by carbon xerogel. J Sol-Gel Sci Technol 63:202–210. https://doi.org/10.1007/s10971-012-2745-3 CrossRef

39.

Schwan J, Ulrich S, Batori V, Ehrhardt H, Silva SRP (1996) Raman spectroscopy on amorphous carbon films. J Appl Phys 80:440–447. https://doi.org/10.1063/1.362745 CrossRef

40.

Altomare M, Selli E (2013) Effects of metal nanoparticles deposition on the photocatalytic oxidation of ammonia in TiO₂ aqueous suspensions. Catal Today 209:127–133. https://doi.org/10.1016/j.cattod.2012.12.001 CrossRef

41.

Lopes OF, Paris EC, Ribeiro C (2014) Synthesis of Nb₂O₅ nanoparticles through the oxidant peroxide method applied to organic pollutant photodegradation: a mechanistic study. Appl Catal B Environ 144:800–808. https://doi.org/10.1016/j.apcatb.2013.08.031 CrossRef

42.

Shaban YA, El Sayed MA, El Maradny AA, Al Farawati RK, Al Zobidi MI, Khan SUM (2016) Photocatalytic removal of polychlorinated biphenyls (PCBs) using carbon-modified titanium oxide nanoparticles. Appl Surf Sci 365:108–113. https://doi.org/10.1016/j.apsusc.2016.01.001 CrossRef

43.

Zhang H, Tang Y, Cai D, Liu X, Wang X, Huang Q, Yu Z (2010) Hexavalent chromium removal from aqueous solution by algal bloom residue derived activated carbon: equilibrium and kinetic studies. J Hazard Mater 181:801–8. https://doi.org/10.1016/j.jhazmat.2010.05.084 CrossRef

44.

Liang Z, Cao Y, Qin H, Jia D (2016) Low-heating solid-state chemical synthesis of monoclinic scheelite BiVO₄ with different morphologies and their enhanced photocatalytic property under visible light. Mater Res Bull 84:397–402. https://doi.org/10.1016/j.materresbull.2016.08.038 CrossRef

45.

Jones W, Martin DJ, Caravaca A, Beale AM, Bowker M, Maschmeyer T, Hartley G, Masters A (2016) A comparison of photocatalytic reforming reactions of methanol and triethanolamine with Pd supported on titania and graphitic carbon nitride. Appl Catal B Environ 1–7. https://doi.org/10.1016/j.apcatb.2017.01.042.

46.

Zhao X, Hongda C, Wang T (2017) Novel synthesis of plasmonic Bi₂Sn₂O₇/Ag-AgCl nanocomposite with enhanced visible light photocatalytic property. Mater Lett 95:392–401. https://doi.org/10.1016/j.matlet.2015.01.097

47.

Bancirova M (2011) Sodium azide as a specific quencher of singlet oxygen during chemiluminescent detection by luminol and Cypridina luciferin analogues. Luminescence 26:685–688. https://doi.org/10.1002/bio.1296 CrossRef

48.

Li M, Yin J-J, Wamer WG, Lo YM (2014) Mechanistic characterization of titanium dioxide nanoparticle-induced toxicity using electron spin resonance. J Food Drug Anal 22:76–85. https://doi.org/10.1016/j.jfda.2014.01.006 CrossRef

49.

Nosaka Y, Daimon T, Nosaka AY, Murakami Y (2004) Singlet oxygen formation in photocatalytic TiO₂ aqueous suspension Phys Chem Chem Phys 6:2917–2918CrossRef

50.

Nakajima N, Ito Y, Yokoyama K, Uno A, Kato K, Iwasaki A, Arakawa Y, Kinukawa N, Nemoto N, Lacy ER (2005) The expresssion of Mdm2 on Helicobacter pylori infected intestinal metaplasia and gastric cancer. J Clin Biochem Nutr 128:A401–A402. https://doi.org/10.3164/jcbn.16

51.

Xu T, Zhang L, Cheng H, Zhu Y (2011) Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study. Appl Catal B Environ 101:382–387. https://doi.org/10.1016/j.apcatb.2010.10.007 CrossRef

52.

Zhang L, Ni C, Jiu H, Xie C, Yan J, Qi G (2017) One-pot synthesis of Ag-TiO₂/reduced graphene oxide nanocomposite for high performance of adsorption and photocatalysis. Ceram Int 43:5450–5456. https://doi.org/10.1016/j.ceramint.2017.01.041 CrossRef

53.

Li B, Yuan H, Yang P, Yi B, Zhang Y (2016) Fabrication of the composite nanofibers of NiO/Al₂O₃ for potential application in photocatalysis. Ceram Int 42:17405–17409. https://doi.org/10.1016/j.ceramint.2016.08.040 CrossRef

Titel: Novel synthetic route for low-cost carbon-modified TiO2 with enhanced visible light photocatalytic activity: carbon content and calcination effects
verfasst von: Nicolas Perciani de Moraes
Maria Lucia Caetano Pinto da Silva
Tiago Moreira Bastos Campos
Gilmar Patrocínio Thim
Liana Alvares Rodrigues
Publikationsdatum: 31.05.2018
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 2/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-018-4700-4

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 2/2018

Adsorption behavior of inorganic- and organic-modified kaolinite for Congo red dye from water, kinetic modeling, and equilibrium studies

Fabrication of PZT/CuO composite films and their photovoltaic properties

Preparation and characterization of silicagel from silicate solution obtained by autoclave treatment of copper slag

Facile preparation of superhydrophobic silica nanoparticles by hydrothermal-assisted sol–gel process and effects of hydrothermal time on surface modification

Synthesis and properties of magnetic zeolite with good magnetic stability from fly ash

Sol-gel synthesis of yttrium aluminum garnet (YAG): effects of the precursor nature and concentration on the crystallization

Premium Partner

Marktübersichten