Skip to main content
Erschienen in: Journal of Nanoparticle Research 4/2012

01.03.2012 | Research Paper

Preferential growth of Bi2Te3 films with a nanolayer structure: enhancement of thermoelectric properties induced by nanocrystal boundaries

verfasst von: Yuan Deng, Zhiwei Zhang, Yao Wang, Yibin Xu

Erschienen in: Journal of Nanoparticle Research | Ausgabe 4/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Preferential growth of different crystal planes in layered Bi2Te3 thin films with each layer <40 nm has been achieved by a simple magnetron co-sputtering method. The preferential growth of (015) plane or (001) was achieved at special depositing conditions due to the more sufficient growth along the in-plane direction induced by the enhanced diffusion of atoms and lower deposition rate. The Bi2Te3 film with preferential growth of (001) plane possesses about two times higher electrical conductivity and Seebeck coefficient as compared to the film with preferential growth of (015) plane, due to the greatly enhanced carrier mobility. Furthermore, the thermal conductivity has been suppressed due to more phonon scattering at grain boundaries, compared with ordinary Bi2Te3 alloys and films.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Arachchige IU, Wu JS, Dravid VP, Kanatzidis MG (2008) Nanocrystals of the quaternary thermoelectric materials: AgPbmSbTem+2 (m = 1-18): phase-segregated or solid solutions? Adv Mater 20:3638–3642CrossRef Arachchige IU, Wu JS, Dravid VP, Kanatzidis MG (2008) Nanocrystals of the quaternary thermoelectric materials: AgPbmSbTem+2 (m = 1-18): phase-segregated or solid solutions? Adv Mater 20:3638–3642CrossRef
Zurück zum Zitat Bassi AL, Bailini A, Casari CS, Donati F, Mantegazza A, Passoni M, Russo V, Bottani CE (2009) Thermoelectric properties of Bi–Te films with controlled structure and morphology. J Appl Phys 105:124307CrossRef Bassi AL, Bailini A, Casari CS, Donati F, Mantegazza A, Passoni M, Russo V, Bottani CE (2009) Thermoelectric properties of Bi–Te films with controlled structure and morphology. J Appl Phys 105:124307CrossRef
Zurück zum Zitat Bies WE, Radtke RJ, Ehrenreich H, Runge E (2002) Thermoelectric properties of anisotropic semiconductors. Phys Rev B 65:085208CrossRef Bies WE, Radtke RJ, Ehrenreich H, Runge E (2002) Thermoelectric properties of anisotropic semiconductors. Phys Rev B 65:085208CrossRef
Zurück zum Zitat Boulouz A, Chakraborty S, Giani A, Pascal Delannoy F, Boyer A, Schumann J (2001) Transport properties of V-VI semiconducting thermoelectric BiSbTe alloy thin films and their application to micromodule Peltier devices. J Appl Phys 89:5009–5014CrossRef Boulouz A, Chakraborty S, Giani A, Pascal Delannoy F, Boyer A, Schumann J (2001) Transport properties of V-VI semiconducting thermoelectric BiSbTe alloy thin films and their application to micromodule Peltier devices. J Appl Phys 89:5009–5014CrossRef
Zurück zum Zitat Carle M, Pierrat P, Lahalle-Gravier C, Scherrer S, Scherrer H (1995) Transport properties of n-type Bi2(Te1-xSex)3 single crystal solid solutions. J Phys Chem Solids 56:201–209CrossRef Carle M, Pierrat P, Lahalle-Gravier C, Scherrer S, Scherrer H (1995) Transport properties of n-type Bi2(Te1-xSex)3 single crystal solid solutions. J Phys Chem Solids 56:201–209CrossRef
Zurück zum Zitat Cho S, Kim Y, Ketterson JB (2004) Structural and thermoelectric properties in (Sb1-xBix)2Te3 thin films. Appl Phys A 79:1729–1731CrossRef Cho S, Kim Y, Ketterson JB (2004) Structural and thermoelectric properties in (Sb1-xBix)2Te3 thin films. Appl Phys A 79:1729–1731CrossRef
Zurück zum Zitat Chowdhury I, Prasher R, Lofgreen K, Chrysler G, Narasimhan S, Mahajan R, Koester D, Alley R, Venkatasubramanian R (2009) On-chip cooling by superlattice-based thin-film thermoelectric. Nat Nanotechnol 4:235–238CrossRef Chowdhury I, Prasher R, Lofgreen K, Chrysler G, Narasimhan S, Mahajan R, Koester D, Alley R, Venkatasubramanian R (2009) On-chip cooling by superlattice-based thin-film thermoelectric. Nat Nanotechnol 4:235–238CrossRef
Zurück zum Zitat Cutler M, Mott NF (1969) Observation of Anderson localization in an electron gas. Phys Rev 181:1336–1340CrossRef Cutler M, Mott NF (1969) Observation of Anderson localization in an electron gas. Phys Rev 181:1336–1340CrossRef
Zurück zum Zitat Delves RT, Bowley AE, Hazelden DW, Goldsmid HJ (1961) Anisotropy of the electrical conductivity in bismuth telluride. Proc Phys Soc 78:838–844CrossRef Delves RT, Bowley AE, Hazelden DW, Goldsmid HJ (1961) Anisotropy of the electrical conductivity in bismuth telluride. Proc Phys Soc 78:838–844CrossRef
Zurück zum Zitat Faleev SV, Léonard F (2008) Theory of enhancement of thermoelectric properties of materials with nanoinclusions. Phys Rev B 77:214304CrossRef Faleev SV, Léonard F (2008) Theory of enhancement of thermoelectric properties of materials with nanoinclusions. Phys Rev B 77:214304CrossRef
Zurück zum Zitat Ham J, Shim W, Kim DH, Lee S, Roh J, Sohn SW, Oh KH, Voorhees PW, Lee W (2009) Direct growth of compound semiconductor nanowires by on-film formation of nanowires: bismuth telluride. Nano Lett 9:2867–2872CrossRef Ham J, Shim W, Kim DH, Lee S, Roh J, Sohn SW, Oh KH, Voorhees PW, Lee W (2009) Direct growth of compound semiconductor nanowires by on-film formation of nanowires: bismuth telluride. Nano Lett 9:2867–2872CrossRef
Zurück zum Zitat Huang H, Luan WL, Tu ST (2009) Influence of annealing on thermoelectric properties of bismuth telluride films grown via radio frequency magnetron sputtering. Thin Solid Films 517:3731–3734CrossRef Huang H, Luan WL, Tu ST (2009) Influence of annealing on thermoelectric properties of bismuth telluride films grown via radio frequency magnetron sputtering. Thin Solid Films 517:3731–3734CrossRef
Zurück zum Zitat Jeon SJ, Oh M, Jeon H, Hyun S, Lee HJ (2011) Effects of post-annealing on thermoelectric properties of bismuth-tellurium thin films deposited by co-sputtering. Microelectron Eng 88:541CrossRef Jeon SJ, Oh M, Jeon H, Hyun S, Lee HJ (2011) Effects of post-annealing on thermoelectric properties of bismuth-tellurium thin films deposited by co-sputtering. Microelectron Eng 88:541CrossRef
Zurück zum Zitat Kashiwagi M, Hirata S, Harada K, Zheng Y, Miyazaki K, Yahiro M, Adachi C (2011) Enhanced figure of merit of a porous thin film of bismuth antimony telluride. Appl Phys Lett 98:023114CrossRef Kashiwagi M, Hirata S, Harada K, Zheng Y, Miyazaki K, Yahiro M, Adachi C (2011) Enhanced figure of merit of a porous thin film of bismuth antimony telluride. Appl Phys Lett 98:023114CrossRef
Zurück zum Zitat Kim DH, Lee GH (2006) Effect of rapid thermal annealing on thermoelectric properties of bismuth telluride films grown by co-sputtering. Mater Sci Eng, B 131:106–111CrossRef Kim DH, Lee GH (2006) Effect of rapid thermal annealing on thermoelectric properties of bismuth telluride films grown by co-sputtering. Mater Sci Eng, B 131:106–111CrossRef
Zurück zum Zitat Kim DH, Byon E, Lee GH, Cho S (2006) Effect of deposition temperature on the structural and thermoelectric properties of bismuth telluride thin films grown by co-sputtering. Thin Solid Films 510:148–153CrossRef Kim DH, Byon E, Lee GH, Cho S (2006) Effect of deposition temperature on the structural and thermoelectric properties of bismuth telluride thin films grown by co-sputtering. Thin Solid Films 510:148–153CrossRef
Zurück zum Zitat Lan YC, Minnich AJ, Chen G, Ren ZF (2010) Enhancement of thermoelectric figure-of-merit by a bulk nanostructuring approach. Adv Funct Mater 20:357–376CrossRef Lan YC, Minnich AJ, Chen G, Ren ZF (2010) Enhancement of thermoelectric figure-of-merit by a bulk nanostructuring approach. Adv Funct Mater 20:357–376CrossRef
Zurück zum Zitat Lee HJ, Hyun S, Park HS, Han SW (2011) Thermoelectric properties of n-type Bi–Te thin films with various compositions. Microelectron Eng 88:593–596CrossRef Lee HJ, Hyun S, Park HS, Han SW (2011) Thermoelectric properties of n-type Bi–Te thin films with various compositions. Microelectron Eng 88:593–596CrossRef
Zurück zum Zitat Li L, Yang YW, Huang XH, Li GH, Ang R, Zhang LD (2006) Fabrication and electronic transport properties of Bi nanotube arrays. Appl Phys Lett 88:103119CrossRef Li L, Yang YW, Huang XH, Li GH, Ang R, Zhang LD (2006) Fabrication and electronic transport properties of Bi nanotube arrays. Appl Phys Lett 88:103119CrossRef
Zurück zum Zitat Makala RS, Jagannadham K, Sales BC (2003) Pulsed laser deposition of Bi2Te3-based thermoelectric thin films. J Appl Phys 94:3907–3918CrossRef Makala RS, Jagannadham K, Sales BC (2003) Pulsed laser deposition of Bi2Te3-based thermoelectric thin films. J Appl Phys 94:3907–3918CrossRef
Zurück zum Zitat Mehta RJ, Karthik C, Singh B, Teki R, Borca-Tasciuc T, Ramanath G (2010) Seebeck tuning in chalcogenide nanoplate assemblies by nanoscale heterostructuring. ACS Nano 4:5055–5060CrossRef Mehta RJ, Karthik C, Singh B, Teki R, Borca-Tasciuc T, Ramanath G (2010) Seebeck tuning in chalcogenide nanoplate assemblies by nanoscale heterostructuring. ACS Nano 4:5055–5060CrossRef
Zurück zum Zitat Motohashi T, Nonaka Y, Sakai K, Karppinen M, Yamauchi H (2008) Fabrication and thermoelectric characteristics of [(Bi, Pb)2Ba2O4±w]0.5CoO2 bulks with highly aligned grain structure. J Appl Phys 103:033705CrossRef Motohashi T, Nonaka Y, Sakai K, Karppinen M, Yamauchi H (2008) Fabrication and thermoelectric characteristics of [(Bi, Pb)2Ba2O4±w]0.5CoO2 bulks with highly aligned grain structure. J Appl Phys 103:033705CrossRef
Zurück zum Zitat Ohta H, Kim S, Mune Y, Mizoguchi T, Nomura K, Ohta S, Nomura T, Nakanishi Y, Ikuhara Y, Hirano M, Hosono H, Koumoto K (2007) Giant thermoelectric Seebeck coefficient of a two-dimensional electron gas in SrTiO3. Nat Mater 6:129–134CrossRef Ohta H, Kim S, Mune Y, Mizoguchi T, Nomura K, Ohta S, Nomura T, Nakanishi Y, Ikuhara Y, Hirano M, Hosono H, Koumoto K (2007) Giant thermoelectric Seebeck coefficient of a two-dimensional electron gas in SrTiO3. Nat Mater 6:129–134CrossRef
Zurück zum Zitat Peranio N, Eibl O, Nurnus J (2006) Structural and thermoelectric properties of epitaxially grown Bi2Te3 thin films and superlattices. J Appl Phys 100:114306CrossRef Peranio N, Eibl O, Nurnus J (2006) Structural and thermoelectric properties of epitaxially grown Bi2Te3 thin films and superlattices. J Appl Phys 100:114306CrossRef
Zurück zum Zitat Pinisetty D, Gupta M, Karki AB, Young DP, Devireddy RV (2011) Fabrication and characterization of electrodeposited antimony telluride crystalline nanowires and nanotubes. J Mater Chem 21:4098–4107CrossRef Pinisetty D, Gupta M, Karki AB, Young DP, Devireddy RV (2011) Fabrication and characterization of electrodeposited antimony telluride crystalline nanowires and nanotubes. J Mater Chem 21:4098–4107CrossRef
Zurück zum Zitat Popescu A, Woods LM, Martin J, Nolas GS (2009) Model of transport properties of thermoelectric nanocomposite materials. Phys Rev B 79:205302CrossRef Popescu A, Woods LM, Martin J, Nolas GS (2009) Model of transport properties of thermoelectric nanocomposite materials. Phys Rev B 79:205302CrossRef
Zurück zum Zitat Poudel B, Hao Q, Ma Y, Lan YC, Minnich A, Yu B, Yan X, Wang DZ, Muto A, Vashaee D, Chen XY, Liu JM, Dresselhaus MS, Chen G, Ren ZF (2008) High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320:634–638CrossRef Poudel B, Hao Q, Ma Y, Lan YC, Minnich A, Yu B, Yan X, Wang DZ, Muto A, Vashaee D, Chen XY, Liu JM, Dresselhaus MS, Chen G, Ren ZF (2008) High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320:634–638CrossRef
Zurück zum Zitat Purkayastha A, Yan QY, Raghuveer MS, Gandhi DD, Li HF, Liu ZW, Ramanujan RV, Borca-Tasciuc T, Ramanath G (2008) Surfactant-directed synthesis of branched bismuth telluride/sulfide core/shell nanorods. Adv Mater 20:2679–2683CrossRef Purkayastha A, Yan QY, Raghuveer MS, Gandhi DD, Li HF, Liu ZW, Ramanujan RV, Borca-Tasciuc T, Ramanath G (2008) Surfactant-directed synthesis of branched bismuth telluride/sulfide core/shell nanorods. Adv Mater 20:2679–2683CrossRef
Zurück zum Zitat Scheele M, Oeschler N, Meier K, Kornowski A, Klinke C, Weller H (2009) Synthesis and thermoelectric characterization of Bi2Te3 nanoparticles. Adv Funct Mater 19:3476–3483CrossRef Scheele M, Oeschler N, Meier K, Kornowski A, Klinke C, Weller H (2009) Synthesis and thermoelectric characterization of Bi2Te3 nanoparticles. Adv Funct Mater 19:3476–3483CrossRef
Zurück zum Zitat Shi WD, Zhou L, Song SY, Yang JH, Zhang HJ (2008) Hydrothermal synthesis and thermoelectric transport properties of impurity-free antimony telluride hexagonal nanoplates. Adv Mater 20:1892–1897CrossRef Shi WD, Zhou L, Song SY, Yang JH, Zhang HJ (2008) Hydrothermal synthesis and thermoelectric transport properties of impurity-free antimony telluride hexagonal nanoplates. Adv Mater 20:1892–1897CrossRef
Zurück zum Zitat Sootsman JR, Chung DY, Kanatzidis MG (2009) New and old concepts in thermoelectric materials. Angew Chem Int Ed 48:8616–8639CrossRef Sootsman JR, Chung DY, Kanatzidis MG (2009) New and old concepts in thermoelectric materials. Angew Chem Int Ed 48:8616–8639CrossRef
Zurück zum Zitat Takashiri M, Miyazaki K, Tanaka S, Kurosaki J, Nagai D, Tsukamoto H (2008) Effect of grain size on thermoelectric properties of n-type nanocrystalline bismuth-telluride based thin films. J Appl Phys 104:084302CrossRef Takashiri M, Miyazaki K, Tanaka S, Kurosaki J, Nagai D, Tsukamoto H (2008) Effect of grain size on thermoelectric properties of n-type nanocrystalline bismuth-telluride based thin films. J Appl Phys 104:084302CrossRef
Zurück zum Zitat Tritt TM, Böttnera H, Chen LD (2008) Thermoelectrics: direct solar thermal energy conversion. MRS Bull 33:366–368CrossRef Tritt TM, Böttnera H, Chen LD (2008) Thermoelectrics: direct solar thermal energy conversion. MRS Bull 33:366–368CrossRef
Zurück zum Zitat Venkatasubramanian R, Siivola E, Colpitts T, O’Quinn B (2001) Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 413:597–602CrossRef Venkatasubramanian R, Siivola E, Colpitts T, O’Quinn B (2001) Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 413:597–602CrossRef
Zurück zum Zitat Vineis CJ, Shakouri A, Majumdar A, Kanatzidis MG (2010) Nanostructured thermoelectrics: big efficiency gains from small features. Adv Mater 22:3970–3980CrossRef Vineis CJ, Shakouri A, Majumdar A, Kanatzidis MG (2010) Nanostructured thermoelectrics: big efficiency gains from small features. Adv Mater 22:3970–3980CrossRef
Zurück zum Zitat Walachová J, Zeipl R, Zelinka J, Malina V, Pavelka M, Jelínek M, Studnička V, Lošt’ák P (2005) High room-temperature figure of merit of thin layers prepared by laser ablation from Bi2Te3 target. Appl Phys Lett 87:081902CrossRef Walachová J, Zeipl R, Zelinka J, Malina V, Pavelka M, Jelínek M, Studnička V, Lošt’ák P (2005) High room-temperature figure of merit of thin layers prepared by laser ablation from Bi2Te3 target. Appl Phys Lett 87:081902CrossRef
Zurück zum Zitat Xiao F, Yoo BY, Lee KH, Myung NV (2007) Synthesis of Bi2Te3 nanotubes by galvanic displacement. J Am Chem Soc 129:10068–10069CrossRef Xiao F, Yoo BY, Lee KH, Myung NV (2007) Synthesis of Bi2Te3 nanotubes by galvanic displacement. J Am Chem Soc 129:10068–10069CrossRef
Zurück zum Zitat Yan X, Poudel B, Ma Y, Liu WS, Joshi G, Wang H, Lan YC, Wang DZ, Chen G, Ren ZF (2010) Experimental studies on anisotropic thermoelectric properties and structures of n-type Bi2Te2.7Se0.3. Nano Lett 10:3373–3378CrossRef Yan X, Poudel B, Ma Y, Liu WS, Joshi G, Wang H, Lan YC, Wang DZ, Chen G, Ren ZF (2010) Experimental studies on anisotropic thermoelectric properties and structures of n-type Bi2Te2.7Se0.3. Nano Lett 10:3373–3378CrossRef
Zurück zum Zitat Yu FR, Zhang JJ, Yu DL, He JL, Liu ZY, Xu B, Tian YJ (2009) Enhanced thermoelectric figure of merit in nanocrystalline Bi2Te3 bulk. J Appl Phys 105:094303CrossRef Yu FR, Zhang JJ, Yu DL, He JL, Liu ZY, Xu B, Tian YJ (2009) Enhanced thermoelectric figure of merit in nanocrystalline Bi2Te3 bulk. J Appl Phys 105:094303CrossRef
Zurück zum Zitat Yu C, Ryu Y, Yin L, Yang H (2011) Modulating electronic transport properties of carbon nanotubes to improve the thermoelectric power factor via nanoparticle decoration. ACS Nano 5:1297–1303CrossRef Yu C, Ryu Y, Yin L, Yang H (2011) Modulating electronic transport properties of carbon nanotubes to improve the thermoelectric power factor via nanoparticle decoration. ACS Nano 5:1297–1303CrossRef
Zurück zum Zitat Zhang GQ, Yu QX, Wang W, Li XG (2010) Nanostructures for thermoelectric applications: synthesis, growth mechanism, and property studies. Adv Mater 22:1959–1962CrossRef Zhang GQ, Yu QX, Wang W, Li XG (2010) Nanostructures for thermoelectric applications: synthesis, growth mechanism, and property studies. Adv Mater 22:1959–1962CrossRef
Zurück zum Zitat Zhao LD, Zhang BP, Li JF, Zhang HL, Liu WS (2008) Enhanced thermoelectric and mechanical properties in textured n-type Bi2Te3 prepared by spark plasma sintering. Solid State Sci 10:651–658CrossRef Zhao LD, Zhang BP, Li JF, Zhang HL, Liu WS (2008) Enhanced thermoelectric and mechanical properties in textured n-type Bi2Te3 prepared by spark plasma sintering. Solid State Sci 10:651–658CrossRef
Zurück zum Zitat Zhao LD, Zhang BP, Liu WS, Li JF (2009) Effect of mixed grain sizes on thermoelectric performance of Bi2Te3 compound. J Appl Phys 105:023704CrossRef Zhao LD, Zhang BP, Liu WS, Li JF (2009) Effect of mixed grain sizes on thermoelectric performance of Bi2Te3 compound. J Appl Phys 105:023704CrossRef
Zurück zum Zitat Zhou WW, Zhu JX, Li D, Hng HH, Boey FYC, Ma J, Zhang H, Yan QY (2009) Binary-phased nanoparticles for enhanced thermoelectric properties. Adv Mater 21:3196–3200CrossRef Zhou WW, Zhu JX, Li D, Hng HH, Boey FYC, Ma J, Zhang H, Yan QY (2009) Binary-phased nanoparticles for enhanced thermoelectric properties. Adv Mater 21:3196–3200CrossRef
Metadaten
Titel
Preferential growth of Bi2Te3 films with a nanolayer structure: enhancement of thermoelectric properties induced by nanocrystal boundaries
verfasst von
Yuan Deng
Zhiwei Zhang
Yao Wang
Yibin Xu
Publikationsdatum
01.03.2012
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 4/2012
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-0775-y

Weitere Artikel der Ausgabe 4/2012

Journal of Nanoparticle Research 4/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.