nach oben

Journal of Nanoparticle Research

Erschienen in:

01.06.2014 | Research Paper

Effects of sulfur sources on properties of Cu₂ZnSnS₄ nanoparticles

verfasst von: Wei Wang, Honglie Shen, Xiancong He, Jinze Li

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this paper, different shapes of Cu₂ZnSnS₄ (CZTS) nanoparticles were prepared using different sulfur sources in a microwave irradiation-assisted synthesis method. Factors influencing the morphology and size of the CZTS nanoparticles by different sulfur sources were studied by scanning electron microscopy and transmission electron microscopy. The optical properties of the CZTS nanoparticles were characterized by means of UV–vis–NIR spectroscopy. The results showed that flower-like nanocrystals and hollow sphere-like particles were obtained when using thiourea, thioacetamide, and l-cysteine as sulfur source. The size of CZTS nanoparticles from several nanometers to a few hundred nanometers could be obtained. The band gaps of CZTS nanoparticles became widened with the decrease of the size. A vesicle-template mechanism was proposed to explain the formation process of the hollow structure of CZTS nanoparticles.

Vorheriger Artikel Substituent effect of Fe(β-diketonate)3 on the control of self-assembly FePt-based nanoparticles

Nächster Artikel Optimizing Au/Ag core–shell nanorods: purification, stability, and surface modification

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Ahmed S, Reuter KB, Gunawan O, Guo L, Romankiw LT, Deligianni H (2012) A high efficiency electrodeposited Cu₂ZnSnS₄ solar cell. Adv Energy Mater 2(2):253–259CrossRef

Fan DH, Zhang R, Zhu YF, Peng HR, Zhang JZ (2014) Structural development and dynamic process in sulfurizing precursors to prepare Cu₂ZnSnS₄ absorber layer. J Alloy Compd 583:566–573CrossRef

Fernandes PA, Salomé PMP, da Cunha AF (2009) Growth and Raman scattering characterization of Cu₂ZnSnS₄ thin films. Thin Solid Films 517(7):2519–2523CrossRef

Guo QJ, Ford GM, Yang WC, Walker BC, Stach EA, Hillhouse HW, Agrawal R (2010) Fabrication of 7.2 % efficient CZTSSe solar cells using CZTS nanocrystals. J Am Chem Soc 132(49):17384–17386CrossRef

Kamoun N, Bouzouita H, Rezig B (2007) Fabrication and characterization of Cu₂ZnSnS₄ thin films deposited by spray pyrolysis technique. Thin Solid Films 515(15):5949–5952CrossRef

Kang CC, Chen HF, Yu TC, Lin TC (2013) Aqueous synthesis of wurtzite Cu₂ZnSnS₄ nanocrystals. Mater Lett 96:24–26CrossRef

Katagiri H, Jimbo K, Maw WS, Oishi K, Yamazaki M, Araki H, Takeuchi A (2009) Development of CZTS-based thin film solar cells. Thin Solid Films 517(7):2455–2460CrossRef

Liu WC, Guo BL, Wu XS, Zhang FM, Mak CL, Wong KH (2013) Facile hydrothermal synthesis of hydrotropic Cu₂ZnSnS₄ nanocrystal quantum dots: band-gap engineering and phonon confinement effect. J Mater Chem A 1:3182–3186CrossRef

Regulacio MD, Ye C, Lim SH, Bosman M, Ye EY, Chen SY, Xu QH, Han MY (2012) Colloidal Nanocrystals of Wurtzite-Type Cu₂ZnSnS₄: facile noninjection synthesis and formation mechanism. Chem Eur J 18(11):3127–3131CrossRef

Shin B, Gunawan O, Zhu Y, Bojarczuk NA, Chey SJ, Guha S (2013) Thin film solar cell with 8.4% power conversion efficiency using an earth-abundant Cu2ZnSnS4 absorber. Prog Photovolt Res Appl 21(1):72–76CrossRef

Singh A, Geaney H, Laffir F, Ryan KM (2012) Colloidal synthesis of wurtzite Cu₂ZnSnS₄ nanorods and their perpendicular assembly. J Am Chem Soc 134:2910–2913CrossRef

Tai GA, Guo WL (2008) Sonochemistry-assisted microwave synthesis and optical study of single-crystalline CdS nanoflowers. Ultrason Sonochem 15:350–356CrossRef

Wada T, Nakamura S, Maeda T (2012) Ternary and multinary Cu-chalcogenide photovoltaic materials from CuInSe₂ to Cu₂ZnSnS₄ and other compounds. Prog Photovolt Res Appl 20(5):520–525CrossRef

Wang Y, Gong H (2011) Cu₂ZnSnS₄ synthesized through a green and economic process. J Alloy Compd 509(40):9627–9630CrossRef

Wang B, Chen JS, Wu HB, Wang ZY, Lou XW (2011) Quasiemulsion-Templated Formation of α-Fe₂O₃ Hollow Spheres with Enhanced Lithium Storage Properties. J Am Chem Soc 133:17146–17148CrossRef

Wei M, Du QY, Wang DC, Liu WF, Jiang GS, Zhu CF (2012) Synthesis of spindle-like kesterite Cu₂ZnSnS₄ nanoparticles using thiorea as sulfur source. Mater Lett 79:177–179CrossRef

Xu J, Yang X, Yang QD, Wong TL, Lee CS (2012) Cu₂ZnSnS₄ hierarchical microspheres as an effective counter electrode material for quantum dot sensitized solar cells. J Phys Chem C 116(37):19718–19723CrossRef

Yang X, Xu J, Xi LJ, Yao YL, Yang QD, Chung CY, Lee CS (2012) Microwave-assisted synthesis of Cu2ZnSnS4 nanocrystals as a novel anode material for lithium ion battery. J Nanopart Res 14:931–936CrossRef

Zeng YP, Li HX, Qu BH, Xiang BY, Wang L, Zhang QL, Li QH, Wang TH, Wang YG (2012) Facile synthesis of flower-like Cu₃BiS₃ hierarchical nanostructures and their electrochemical properties for lithium-ion batteries. CrystEngComm 14:550–554CrossRef

Zhang AY, Ma Q, Lu MK, Yu GW, Zhou YY, Qiu ZF (2008) Copper-indium sulfide hollow nanospheres synthesized by a facile solution-chemical method. Cryst Growth Des 8(7):2402–2405CrossRef

Zhou YL, Zhou WH, Du YF, Li M, Wu SX (2011a) Sphere-like kesterite Cu₂ZnSnS₄ nanoparticles synthesized by a facile solvothermal method. Mater Lett 65:1535–1537CrossRef

Zhou YL, Zhou WH, Li M, Du YF, Wu SX (2011b) Hierarchical Cu₂ZnSnS₄ particles for a low-cost solar cell: morphology control and growth mechanism. J Phys Chem C 115(40):19632–19639CrossRef

Zhou JC, You L, Li SW, Yang YL (2012) Preparation and characterization of Cu₂ZnSnS₄ microparticles via a facile solution route. Mater Lett 81:248–250CrossRef

Titel: Effects of sulfur sources on properties of Cu2ZnSnS4 nanoparticles
verfasst von: Wei Wang
Honglie Shen
Xiancong He
Jinze Li
Publikationsdatum: 01.06.2014
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 6/2014
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-014-2437-8

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 6/2014

Erratum to: Optical properties of uniformly sized silicon nanocrystals within a single silicon oxide layer

Toward standardized test methods to determine the effectiveness of filtration media against airborne nanoparticles

Magnetite decorated multi-walled carbon nanotubes for removal of toxic dyes from aqueous solutions

Synthesis and characterization of lipophilic bismuth dimercaptopropanol nanoparticles and their effects on oral microorganisms growth and biofilm formation

A solid phospholipid-bile salts-mixed micelles based on the fast dissolving oral films to improve the oral bioavailability of poorly water-soluble drugs

Facile preparation of magnetically functionalized graphite nanosheets for porcine pancreatic lipase immobilization

Premium Partner

Marktübersichten