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Erschienen in: Arabian Journal for Science and Engineering 1/2020

16.11.2019 | Research Article - Chemistry

Effects of Cinnamaldehyde as an Eco-Friendly Corrosion Inhibitor on Mild Steel in Aerated NaCl Solutions

verfasst von: S. M. Zakir Hossain, S. A. Kareem, A. F. Alshater, H. Alzubair, S. A. Razzak, M. M. Hossain

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 1/2020

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Abstract

This article investigates the impact of cinnamaldehyde as an eco-friendly inhibitor in mitigating corrosion detriment on mild steel in aerated NaCl (3% w/w) using weight loss and potentiodynamic polarization methods. The results indicate moderate inhibition efficiency of cinnamaldehyde reaching around 70% at an optimum level of 0.5 g/L or 500 ppm by establishing an adsorption film on metal surface. Adsorption of the cinnamaldehyde seemed to adhere to the Langmuir isotherm. The corrosion rate decreased with cinnamaldehyde dose up to the optimum level while increased slowly with the medium temperature. The activation energy (Ea) achieved with cinnamaldehyde was found to be lower than that of without cinnamaldehyde. The polarization curves revealed that the inhibitor performs as a mixed-type inhibitor since it diminishes both anodic and cathodic current densities. The calculated inhibition efficiencies using both corrosion monitoring techniques were found to be in good agreement. Additionally, the mild steel surfaces (inhibited and uninhibited) were examined by using SEM–EDX analysis.

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Literatur
4.
Zurück zum Zitat Ghods, P.; Isgor, O.B.; McRae, G.A.; Cu, G.P.: Electrochemical investigation of chloride-induced depassivation of black steel rebar under simulated service conditions. Corros. Sci. 52, 1649–1659 (2010)CrossRef Ghods, P.; Isgor, O.B.; McRae, G.A.; Cu, G.P.: Electrochemical investigation of chloride-induced depassivation of black steel rebar under simulated service conditions. Corros. Sci. 52, 1649–1659 (2010)CrossRef
15.
Zurück zum Zitat Duan, Z.; Sun, R.: An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar. Chem. Geol. 193, 257–271 (2003)CrossRef Duan, Z.; Sun, R.: An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar. Chem. Geol. 193, 257–271 (2003)CrossRef
18.
Zurück zum Zitat Ramezanzadeh, M.; Sanaei, Z.; Bahlakeh, G.; Ramezanzadeh, B.: Highly effective inhibition of mild steel corrosion in 3.5% NaCl solution by green Nettle leaves extract and synergistic effect of eco-friendly cerium nitrate additive: experimental, MD simulation and QM investigations. J. Mol. Liq. 256, 67–83 (2018). https://doi.org/10.1016/j.molliq.2018.02.021 CrossRef Ramezanzadeh, M.; Sanaei, Z.; Bahlakeh, G.; Ramezanzadeh, B.: Highly effective inhibition of mild steel corrosion in 3.5% NaCl solution by green Nettle leaves extract and synergistic effect of eco-friendly cerium nitrate additive: experimental, MD simulation and QM investigations. J. Mol. Liq. 256, 67–83 (2018). https://​doi.​org/​10.​1016/​j.​molliq.​2018.​02.​021 CrossRef
19.
Zurück zum Zitat Shabani-Nooshabadi, M.; Hoseiny, F.S.; Jafari, Y.: Corrosion inhibition of copper by ephedra sarcocarpa plant extract as green corrosion inhibitor in strong acidic medium. Anal. Bioanal. Electrochem. 6, 341–354 (2014) Shabani-Nooshabadi, M.; Hoseiny, F.S.; Jafari, Y.: Corrosion inhibition of copper by ephedra sarcocarpa plant extract as green corrosion inhibitor in strong acidic medium. Anal. Bioanal. Electrochem. 6, 341–354 (2014)
22.
Zurück zum Zitat Lebrini, M.; Robert, F.; Roos, C.: Alkaloids extract from Palicourea guianensis plant as corrosion inhibitor for C38 steel in 1 M hydrochloric acid medium. Int. J. Electrochem. Sci. 6, 847–859 (2011) Lebrini, M.; Robert, F.; Roos, C.: Alkaloids extract from Palicourea guianensis plant as corrosion inhibitor for C38 steel in 1 M hydrochloric acid medium. Int. J. Electrochem. Sci. 6, 847–859 (2011)
23.
Zurück zum Zitat El Ouariachi, E.; Bouyanzer, A.; Salghi, R.; Hammouti, B.; Desjobert, J.M.; Costa, J.; Paolini, J.; Majidi, L.: Inhibition of corrosion of mild steel in 1 M HCl by the essential oil or solvent extracts of Ptychotis verticillata. Res. Chem. Intermed. 41, 935–946 (2015). https://doi.org/10.1007/s11164-013-1246-5 CrossRef El Ouariachi, E.; Bouyanzer, A.; Salghi, R.; Hammouti, B.; Desjobert, J.M.; Costa, J.; Paolini, J.; Majidi, L.: Inhibition of corrosion of mild steel in 1 M HCl by the essential oil or solvent extracts of Ptychotis verticillata. Res. Chem. Intermed. 41, 935–946 (2015). https://​doi.​org/​10.​1007/​s11164-013-1246-5 CrossRef
24.
Zurück zum Zitat Lahhit, N.; Bouyanzer, A.; Desjobert, J.-M.; Hammouti, B.; Salghi, R.; Costa, J.; Jama, C.; Bentiss, F.; Majidi, L.: Fennel (Foeniculum Vulgare) essential oil as green corrosion inhibitor of carbon steel in hydrochloric acid solution. Port. Electrochim. Acta. 29, 127–138 (2011). https://doi.org/10.4152/pea.201102127 CrossRef Lahhit, N.; Bouyanzer, A.; Desjobert, J.-M.; Hammouti, B.; Salghi, R.; Costa, J.; Jama, C.; Bentiss, F.; Majidi, L.: Fennel (Foeniculum Vulgare) essential oil as green corrosion inhibitor of carbon steel in hydrochloric acid solution. Port. Electrochim. Acta. 29, 127–138 (2011). https://​doi.​org/​10.​4152/​pea.​201102127 CrossRef
27.
Zurück zum Zitat Growcock, F.B.; Frenier, W.W.: Kinetics of steel corrosion in hydrochloric acid inhibited with trans-cinnamaldehyde. J. Electrochem. Soc. 135, 817–823 (1988)CrossRef Growcock, F.B.; Frenier, W.W.: Kinetics of steel corrosion in hydrochloric acid inhibited with trans-cinnamaldehyde. J. Electrochem. Soc. 135, 817–823 (1988)CrossRef
30.
Zurück zum Zitat Negm, A.N.; Yousef, A.M.; Tawfik, M.S.: Impact of synthesized and natural compounds in corrosion inhibition of carbon steel and aluminium in acidic media. Recent Patents Corros. Sci. 3, 58–68 (2013)CrossRef Negm, A.N.; Yousef, A.M.; Tawfik, M.S.: Impact of synthesized and natural compounds in corrosion inhibition of carbon steel and aluminium in acidic media. Recent Patents Corros. Sci. 3, 58–68 (2013)CrossRef
32.
Zurück zum Zitat Jafferji, H.; Sharifi, N.P.; Schneider, E.M.; Sakulic, A.R.: Investigation of incorporating cinnamaldehyde into Lightweight Aggregate for potential corrosion reduction in cementitious materials. Cement Concr. Compos. 87, 1–9 (2018)CrossRef Jafferji, H.; Sharifi, N.P.; Schneider, E.M.; Sakulic, A.R.: Investigation of incorporating cinnamaldehyde into Lightweight Aggregate for potential corrosion reduction in cementitious materials. Cement Concr. Compos. 87, 1–9 (2018)CrossRef
33.
Zurück zum Zitat Jafferji, H.; Sakulich, A.R.; Schiffman, J.D.: Preliminary study on mitigating steel reinforcement corrosion with bioactive agent. Cement Concr. Compos. 69, 9–17 (2016)CrossRef Jafferji, H.; Sakulich, A.R.; Schiffman, J.D.: Preliminary study on mitigating steel reinforcement corrosion with bioactive agent. Cement Concr. Compos. 69, 9–17 (2016)CrossRef
34.
Zurück zum Zitat Hossain, S.M.Z.; Al-Shater, A.; Kareem, S.A.R.: Cinnamaldehyde as a green inhibitor in mitigating AISI 1015 carbon steel corrosion in HCl. Arab J Sci Eng 44, 5489–5499 (2019)CrossRef Hossain, S.M.Z.; Al-Shater, A.; Kareem, S.A.R.: Cinnamaldehyde as a green inhibitor in mitigating AISI 1015 carbon steel corrosion in HCl. Arab J Sci Eng 44, 5489–5499 (2019)CrossRef
35.
Zurück zum Zitat Rekkab, S.; Zarrok, H.; Salghi, R.; Zarrouk, A.; Bazzi, L.; Hammouti, B.; Kabouche, Z.; Touzani, R.; Zougagh, M.: Green corrosion inhibitor from essential oil of eucalyptus globulus (Myrtaceae) for C38 steel in sulfuric acid solution. J. Mater. Environ. Sci. 3, 613–627 (2012) Rekkab, S.; Zarrok, H.; Salghi, R.; Zarrouk, A.; Bazzi, L.; Hammouti, B.; Kabouche, Z.; Touzani, R.; Zougagh, M.: Green corrosion inhibitor from essential oil of eucalyptus globulus (Myrtaceae) for C38 steel in sulfuric acid solution. J. Mater. Environ. Sci. 3, 613–627 (2012)
37.
Zurück zum Zitat Messaadia, L.; Id El mouden, O.; Anejjar, A.; Messali, M.; Salghi, R.; Benali, O.; Cherkaoui, O.; Lallam, A.: Adsorption and corrosion inhibition of new synthesized pyridazinium-based ionic liquid on carbon steel in 05 M H2SO4. J. Mater. Environ. Sci. 6, 598–606 (2015) Messaadia, L.; Id El mouden, O.; Anejjar, A.; Messali, M.; Salghi, R.; Benali, O.; Cherkaoui, O.; Lallam, A.: Adsorption and corrosion inhibition of new synthesized pyridazinium-based ionic liquid on carbon steel in 05 M H2SO4. J. Mater. Environ. Sci. 6, 598–606 (2015)
39.
Zurück zum Zitat Cristofari, G.; Znini, M.; Majidi, L.; Bouyanzer, A.; Al-Deyab, S.S.; Paolini, J.; Hammouti, B.; Costa, J.: Chemical composition and anti-corrosive activity of Pulicaria mauritanica essential oil against the corrosion of mild steel in 0.5 M H 2SO 4. Int. J. Electrochem. Sci. 6, 6699–6717 (2011) Cristofari, G.; Znini, M.; Majidi, L.; Bouyanzer, A.; Al-Deyab, S.S.; Paolini, J.; Hammouti, B.; Costa, J.: Chemical composition and anti-corrosive activity of Pulicaria mauritanica essential oil against the corrosion of mild steel in 0.5 M H 2SO 4. Int. J. Electrochem. Sci. 6, 6699–6717 (2011)
43.
Zurück zum Zitat Manssouri, M.; El Ouadi, Y.; Znini, M.; Costa, J.; Bouyanzer, A.; Desjobert, J.M.; Majidi, L.: Adsorption proprieties and inhibition of mild steel corrosion in HCl solution by the essential oil from fruit of Moroccan Ammodaucus leucotrichus. J. Mater. Environ. Sci. 6, 631–646 (2015) Manssouri, M.; El Ouadi, Y.; Znini, M.; Costa, J.; Bouyanzer, A.; Desjobert, J.M.; Majidi, L.: Adsorption proprieties and inhibition of mild steel corrosion in HCl solution by the essential oil from fruit of Moroccan Ammodaucus leucotrichus. J. Mater. Environ. Sci. 6, 631–646 (2015)
46.
Zurück zum Zitat Guan, N.M.; Xueming, L.; Fei, L.: Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Mater. Chem. Phys. 86, 59–68 (2004)CrossRef Guan, N.M.; Xueming, L.; Fei, L.: Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Mater. Chem. Phys. 86, 59–68 (2004)CrossRef
49.
Zurück zum Zitat Andreani, S.; Znini, M.; Paolini, J.; Majidi, L.; Hammouti, B.; Costa, J.; Muselli, A.: Study of corrosion inhibition for mild steel in hydrochloric acid solution by Limbarda crithmoides (L.) essential oil of Corsica. J. Mater. Environ. Sci. 7, 187–195 (2016) Andreani, S.; Znini, M.; Paolini, J.; Majidi, L.; Hammouti, B.; Costa, J.; Muselli, A.: Study of corrosion inhibition for mild steel in hydrochloric acid solution by Limbarda crithmoides (L.) essential oil of Corsica. J. Mater. Environ. Sci. 7, 187–195 (2016)
50.
Zurück zum Zitat Eduok, U.M.; Khaled, M.: Corrosion inhibition for low-carbon steel in 1 MH 2 SO 4 solution by phenytoin: evaluation of the inhibition potency of another “anticorrosive drug”. Res. Chem. Intermed. 41(9), 6309–6324 (2015)CrossRef Eduok, U.M.; Khaled, M.: Corrosion inhibition for low-carbon steel in 1 MH 2 SO 4 solution by phenytoin: evaluation of the inhibition potency of another “anticorrosive drug”. Res. Chem. Intermed. 41(9), 6309–6324 (2015)CrossRef
52.
Zurück zum Zitat Singh, A.; Ansari, K.R.; Quraishi, M.A.; Lgaz, H.: Effect of electron donating functional groups on corrosion inhibition of J55 steel in a sweet corrosive environment: experimental, density functional theory, and molecular dynamic simulation. Materials (Basel). 12, (2018). https://doi.org/10.3390/ma12010017 CrossRef Singh, A.; Ansari, K.R.; Quraishi, M.A.; Lgaz, H.: Effect of electron donating functional groups on corrosion inhibition of J55 steel in a sweet corrosive environment: experimental, density functional theory, and molecular dynamic simulation. Materials (Basel). 12, (2018). https://​doi.​org/​10.​3390/​ma12010017 CrossRef
Metadaten
Titel
Effects of Cinnamaldehyde as an Eco-Friendly Corrosion Inhibitor on Mild Steel in Aerated NaCl Solutions
verfasst von
S. M. Zakir Hossain
S. A. Kareem
A. F. Alshater
H. Alzubair
S. A. Razzak
M. M. Hossain
Publikationsdatum
16.11.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 1/2020
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-019-04236-4

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