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Erschienen in: Shape Memory and Superelasticity 1/2016

01.03.2016 | Special Issue: High-Temperature Shape Memory Alloys, Invited Paper

Composition, Compatibility, and the Functional Performances of Ternary NiTiX High-Temperature Shape Memory Alloys

verfasst von: Ashley N. Bucsek, Grant A. Hudish, Glen S. Bigelow, Ronald D. Noebe, Aaron P. Stebner

Erschienen in: Shape Memory and Superelasticity | Ausgabe 1/2016

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Abstract

A general procedure to optimize shape memory alloys (SMAs) for specific engineering performance metrics is outlined and demonstrated through a study of ternary, NiTiX high-temperature SMAs, where X = Pd, Hf, Zr. Transformation strains are calculated using the crystallographic theory of martensite and compared to the cofactor conditions, both requiring only lattice parameters as inputs. Measurements of transformation temperatures and hysteresis provide additional comparisons between microstructural-based and transformation properties. The relationships between microstructural-based properties and engineering performance metrics are then thoroughly explored. Use of this procedure demonstrates that SMAs can be tuned for specific applications using relatively simple, fast, and inexpensive measurements and theoretical calculations. The results also indicate an overall trade-off between compatibility and strains, suggesting that alloys may be optimized for either minimal hysteresis or large transformation strains and work output. However, further analysis of the effects of aging shows that better combinations of uncompromised properties are possible through solid solution strengthening.

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Literatur
1.
Zurück zum Zitat Stebner AP, Bigelow GS, Yang J, Shukla DP, Saghaian SM, Rogers R, Garg A, Karaca HE, Chumlyakov Y, Bhattacharya K et al (2014) Transformation strains and temperatures of a nickel–titanium–hafnium high temperature shape memory alloy. Acta Mater 76:40–53CrossRef Stebner AP, Bigelow GS, Yang J, Shukla DP, Saghaian SM, Rogers R, Garg A, Karaca HE, Chumlyakov Y, Bhattacharya K et al (2014) Transformation strains and temperatures of a nickel–titanium–hafnium high temperature shape memory alloy. Acta Mater 76:40–53CrossRef
2.
Zurück zum Zitat Bigelow GS, Garg A, Padula SA, Gaydosh DJ, Noebe RD (2011) Load-biased shape-memory and superelastic properties of a precipitation strengthened high-temperature Ni50.3Ti29.7Hf20 alloy. Scr Mater 64(8):725–728CrossRef Bigelow GS, Garg A, Padula SA, Gaydosh DJ, Noebe RD (2011) Load-biased shape-memory and superelastic properties of a precipitation strengthened high-temperature Ni50.3Ti29.7Hf20 alloy. Scr Mater 64(8):725–728CrossRef
3.
Zurück zum Zitat Wang J, Sehitoglu H (2014) Modelling of martensite slip and twinning in NiTiHf shape memory alloys. Philos Mag 94(20):2297–2317CrossRef Wang J, Sehitoglu H (2014) Modelling of martensite slip and twinning in NiTiHf shape memory alloys. Philos Mag 94(20):2297–2317CrossRef
4.
Zurück zum Zitat Wu Y, Patriarca L, Li G, Sehitoglu H, Soejima Y, Ito T, Nishida M (2015) Shape memory response of polycrystalline NiTi12.5Hf alloy: transformation at small scales. Shape Mem Superelast 1(3):387–397CrossRef Wu Y, Patriarca L, Li G, Sehitoglu H, Soejima Y, Ito T, Nishida M (2015) Shape memory response of polycrystalline NiTi12.5Hf alloy: transformation at small scales. Shape Mem Superelast 1(3):387–397CrossRef
5.
Zurück zum Zitat Chluba C, Ge W, de Miranda RL, Strobel J, Kienle L, Quandt E, Wuttig M (2015) Ultralow-fatigue shape memory alloy films. Science 348(6238):1004–1007CrossRef Chluba C, Ge W, de Miranda RL, Strobel J, Kienle L, Quandt E, Wuttig M (2015) Ultralow-fatigue shape memory alloy films. Science 348(6238):1004–1007CrossRef
6.
Zurück zum Zitat James RD (2015) Taming the temperamental metal transformation. Science 348(6238):968–969CrossRef James RD (2015) Taming the temperamental metal transformation. Science 348(6238):968–969CrossRef
7.
Zurück zum Zitat Duerig TW (1990) Engineering aspects of shape memory alloys. Butterworth-Heinemann, London Duerig TW (1990) Engineering aspects of shape memory alloys. Butterworth-Heinemann, London
8.
Zurück zum Zitat Eggeler G, Hornbogen E, Yawny A, Heckmann A, Wagner M (2004) Structural and functional fatigue of NiTi shape memory alloys. Mater Sci Eng A 378(1–2):24–33CrossRef Eggeler G, Hornbogen E, Yawny A, Heckmann A, Wagner M (2004) Structural and functional fatigue of NiTi shape memory alloys. Mater Sci Eng A 378(1–2):24–33CrossRef
9.
Zurück zum Zitat Cui J, Chu YS, Famodu OO, Furuya Y, Hattrick-Simpers J, James RD, Ludwig A, Thienhaus S, Wuttig M, Zhang Z et al (2006) Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width. Nat Mater 5(4):286–290CrossRef Cui J, Chu YS, Famodu OO, Furuya Y, Hattrick-Simpers J, James RD, Ludwig A, Thienhaus S, Wuttig M, Zhang Z et al (2006) Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width. Nat Mater 5(4):286–290CrossRef
10.
Zurück zum Zitat Kato H, Ozu T, Hashimoto S, Miura S (1999) Cyclic stress–strain response of superelastic Cu–Al–Mn alloy single crystals. Mater Sci Eng A 264(1):245–253CrossRef Kato H, Ozu T, Hashimoto S, Miura S (1999) Cyclic stress–strain response of superelastic Cu–Al–Mn alloy single crystals. Mater Sci Eng A 264(1):245–253CrossRef
11.
Zurück zum Zitat Bhattacharya K (2003) Microstructure of martensite: why it forms and how it gives rise to the shape memory effect. Oxford University Press, Oxford, New York Bhattacharya K (2003) Microstructure of martensite: why it forms and how it gives rise to the shape memory effect. Oxford University Press, Oxford, New York
12.
Zurück zum Zitat Otsuka K, Ren X (2005) Physical metallurgy of Ti–Ni-based shape memory alloys. Prog Mater Sci 50(5):511–678CrossRef Otsuka K, Ren X (2005) Physical metallurgy of Ti–Ni-based shape memory alloys. Prog Mater Sci 50(5):511–678CrossRef
13.
Zurück zum Zitat Richards AW, Lebensohn RA, Bhattacharya K (2013) Interplay of martensitic phase transformation and plastic slip in polycrystals. Acta Mater 61(12):4384–4397CrossRef Richards AW, Lebensohn RA, Bhattacharya K (2013) Interplay of martensitic phase transformation and plastic slip in polycrystals. Acta Mater 61(12):4384–4397CrossRef
14.
Zurück zum Zitat Shu YC, Bhattacharya K (1998) The influence of texture on the shape-memory effect in polycrystals. Acta Mater 46(15):5457–5473CrossRef Shu YC, Bhattacharya K (1998) The influence of texture on the shape-memory effect in polycrystals. Acta Mater 46(15):5457–5473CrossRef
15.
Zurück zum Zitat Frankel D, Olson G (2015) Design of Heusler precipitation strengthened NiTi- and PdTi-base SMAs for cyclic performance. Shape Mem Superelast 1(2):162–179CrossRef Frankel D, Olson G (2015) Design of Heusler precipitation strengthened NiTi- and PdTi-base SMAs for cyclic performance. Shape Mem Superelast 1(2):162–179CrossRef
16.
Zurück zum Zitat Paranjape HM (2014) Modeling of shape memory alloys: phase transformation/plasticity interaction at the nano scale and the statistics of variation in pseudoelastic performance. The Ohio State University, Doctor of Philosophy Paranjape HM (2014) Modeling of shape memory alloys: phase transformation/plasticity interaction at the nano scale and the statistics of variation in pseudoelastic performance. The Ohio State University, Doctor of Philosophy
17.
Zurück zum Zitat James R, Zhang Z (2005) A way to search for multiferroic materials with ‘unlikely’ combinations of physical properties. Springer Ser Mater Sci 79:159CrossRef James R, Zhang Z (2005) A way to search for multiferroic materials with ‘unlikely’ combinations of physical properties. Springer Ser Mater Sci 79:159CrossRef
18.
Zurück zum Zitat Chen X, Srivastava V, Dabade V, James RD (2013) Study of the cofactor conditions: conditions of supercompatibility between phases. J Mech Phys Solids 61(12):2566–2587CrossRef Chen X, Srivastava V, Dabade V, James RD (2013) Study of the cofactor conditions: conditions of supercompatibility between phases. J Mech Phys Solids 61(12):2566–2587CrossRef
19.
Zurück zum Zitat Zarnetta R, Takahashi R, Young ML, Furuya Y, Thienhaus S (2010) Identification of quaternary shape memory alloys with near-zero thermal hysteresis and unprecedented functional stability. Adv Funct Mater 20(12):1917–1923CrossRef Zarnetta R, Takahashi R, Young ML, Furuya Y, Thienhaus S (2010) Identification of quaternary shape memory alloys with near-zero thermal hysteresis and unprecedented functional stability. Adv Funct Mater 20(12):1917–1923CrossRef
20.
Zurück zum Zitat Song Y, Chen X, Dabade V, Shield TW, James RD (2013) Enhanced reversibility and unusual microstructure of a phase-transforming material. Nature 502(7469):85–88CrossRef Song Y, Chen X, Dabade V, Shield TW, James RD (2013) Enhanced reversibility and unusual microstructure of a phase-transforming material. Nature 502(7469):85–88CrossRef
21.
Zurück zum Zitat Delville R, Schryvers D, Zhang Z, James RD (2009) Transmission electron microscopy investigation of microstructures in low-hysteresis alloys with special lattice parameters. Scr. Mater. 60(5):293–296CrossRef Delville R, Schryvers D, Zhang Z, James RD (2009) Transmission electron microscopy investigation of microstructures in low-hysteresis alloys with special lattice parameters. Scr. Mater. 60(5):293–296CrossRef
22.
Zurück zum Zitat Frenzel J, Wieczorek A, Opahle I, Maaß B, Drautz R, Eggeler G (2015) On the effect of alloy composition on martensite start temperatures and latent heats in Ni–Ti-based shape memory alloys. Acta Mater 90:213–231CrossRef Frenzel J, Wieczorek A, Opahle I, Maaß B, Drautz R, Eggeler G (2015) On the effect of alloy composition on martensite start temperatures and latent heats in Ni–Ti-based shape memory alloys. Acta Mater 90:213–231CrossRef
23.
Zurück zum Zitat Miyazaki S, Imai T, Igo Y, Otsuka K (1986) Effect of cyclic deformation on the pseudoelasticity characteristics of Ti-Ni alloys. Metall Trans A 17(1):115–120CrossRef Miyazaki S, Imai T, Igo Y, Otsuka K (1986) Effect of cyclic deformation on the pseudoelasticity characteristics of Ti-Ni alloys. Metall Trans A 17(1):115–120CrossRef
24.
Zurück zum Zitat Otsuka K, Wayman CM (1998) Shape memory materials. Cambridge University Press, Cambridge Otsuka K, Wayman CM (1998) Shape memory materials. Cambridge University Press, Cambridge
25.
Zurück zum Zitat Nishiyama Z (1978) Martensitic transformation. Academic Press Inc, New York Nishiyama Z (1978) Martensitic transformation. Academic Press Inc, New York
26.
Zurück zum Zitat Hane KF, Shield TW (1998) Symmetry and microstructure in martensites. Philos Mag A 78(6):1215–1252CrossRef Hane KF, Shield TW (1998) Symmetry and microstructure in martensites. Philos Mag A 78(6):1215–1252CrossRef
27.
Zurück zum Zitat Bilby B, Crocker A (1965) The theory of the crystallography of deformation twinning. Proc R Soc Lond A 288:240–255CrossRef Bilby B, Crocker A (1965) The theory of the crystallography of deformation twinning. Proc R Soc Lond A 288:240–255CrossRef
28.
Zurück zum Zitat Ball JM, James RD (1989) Fine phase mixtures as minimizers of energy. Analysis and continuum mechanics. Springer, Berlin, pp 647–686CrossRef Ball JM, James RD (1989) Fine phase mixtures as minimizers of energy. Analysis and continuum mechanics. Springer, Berlin, pp 647–686CrossRef
29.
Zurück zum Zitat Hane KF, Shield T (1999) Microstructure in the cubic to monoclinic transition in titanium–nickel shape memory alloys. Acta Mater 47(9):2603–2617CrossRef Hane KF, Shield T (1999) Microstructure in the cubic to monoclinic transition in titanium–nickel shape memory alloys. Acta Mater 47(9):2603–2617CrossRef
30.
Zurück zum Zitat James RD, Hane KF (2000) Martensitic transformations and shape-memory materials. Acta Mater 48(1):197–222CrossRef James RD, Hane KF (2000) Martensitic transformations and shape-memory materials. Acta Mater 48(1):197–222CrossRef
31.
Zurück zum Zitat Stebner A, Vogel S, Noebe R, Sisneros T, Clausen B, Brown D, Garg A, Brinson L (2013) Micromechanical quantification of elastic, twinning, and slip strain partitioning exhibited by polycrystalline, monoclinic nickel–titanium during large uniaxial deformations measured via in situ neutron diffraction. J Mech Phys Solids 61(11):2302–2330CrossRef Stebner A, Vogel S, Noebe R, Sisneros T, Clausen B, Brown D, Garg A, Brinson L (2013) Micromechanical quantification of elastic, twinning, and slip strain partitioning exhibited by polycrystalline, monoclinic nickel–titanium during large uniaxial deformations measured via in situ neutron diffraction. J Mech Phys Solids 61(11):2302–2330CrossRef
32.
Zurück zum Zitat Delville R, James R, Salman U, Finel A, Schryvers D (2009) Transmission electron microscopy study of low-hysteresis shape memory alloys. In: European Symposium on Martensitic Transformations, 2009, p 02005 Delville R, James R, Salman U, Finel A, Schryvers D (2009) Transmission electron microscopy study of low-hysteresis shape memory alloys. In: European Symposium on Martensitic Transformations, 2009, p 02005
33.
Zurück zum Zitat Bigelow G, Padula SA, Garg A, Gaydosh D, Noebe R (2010) Characterization of ternary NiTiPd high-temperature shape-memory alloys under load-biased thermal cycling. Metall Mater Trans A 41(12):3065–3079CrossRef Bigelow G, Padula SA, Garg A, Gaydosh D, Noebe R (2010) Characterization of ternary NiTiPd high-temperature shape-memory alloys under load-biased thermal cycling. Metall Mater Trans A 41(12):3065–3079CrossRef
34.
Zurück zum Zitat Otsuka K, Sawamura T, Shimizu K (1971) Crystal structure and internal defects of equiatomic TiNi martensite. Phys Status Solidi A 5(2):457–470CrossRef Otsuka K, Sawamura T, Shimizu K (1971) Crystal structure and internal defects of equiatomic TiNi martensite. Phys Status Solidi A 5(2):457–470CrossRef
35.
Zurück zum Zitat Potapov P, Shelyakov A, Gulyaev A, Svistunov E, Matveeva N, Hodgson D (1997) Effect of Hf on the structure of Ni-Ti martensitic alloys. Mater Lett 32(4):247–250CrossRef Potapov P, Shelyakov A, Gulyaev A, Svistunov E, Matveeva N, Hodgson D (1997) Effect of Hf on the structure of Ni-Ti martensitic alloys. Mater Lett 32(4):247–250CrossRef
36.
Zurück zum Zitat Hane KF, Shield TW (2000) Microstructure in a cubic to orthorhombic transition. J Elast Phys Sci Solids 59(1–3):267–318 Hane KF, Shield TW (2000) Microstructure in a cubic to orthorhombic transition. J Elast Phys Sci Solids 59(1–3):267–318
37.
Zurück zum Zitat Karaca HE, Saghaian SM, Ded G, Tobe H, Basaran B, Maier HJ, Noebe RD, Chumlyakov YI (2013) Effects of nanoprecipitation on the shape memory and material properties of an Ni-rich NiTiHf high temperature shape memory alloy. Acta Mater 61(19):7422–7431CrossRef Karaca HE, Saghaian SM, Ded G, Tobe H, Basaran B, Maier HJ, Noebe RD, Chumlyakov YI (2013) Effects of nanoprecipitation on the shape memory and material properties of an Ni-rich NiTiHf high temperature shape memory alloy. Acta Mater 61(19):7422–7431CrossRef
38.
Zurück zum Zitat Yang F, Coughlin DR, Phillips PJ, Yang L, Devaraj A, Kovarik L, Noebe RD, Mills MJ (2013) Structure analysis of a precipitate phase in an Ni-rich high-temperature NiTiHf shape memory alloy. Acta Mater 61(9):3335–3346CrossRef Yang F, Coughlin DR, Phillips PJ, Yang L, Devaraj A, Kovarik L, Noebe RD, Mills MJ (2013) Structure analysis of a precipitate phase in an Ni-rich high-temperature NiTiHf shape memory alloy. Acta Mater 61(9):3335–3346CrossRef
39.
Zurück zum Zitat Lieberman DS, Wechsler MS, Read TA (1955) Cubic to orthorhombic diffusionless phase change— experimental and theoretical studies of AuCd. J Appl Phys 26(4):473–484CrossRef Lieberman DS, Wechsler MS, Read TA (1955) Cubic to orthorhombic diffusionless phase change— experimental and theoretical studies of AuCd. J Appl Phys 26(4):473–484CrossRef
Metadaten
Titel
Composition, Compatibility, and the Functional Performances of Ternary NiTiX High-Temperature Shape Memory Alloys
verfasst von
Ashley N. Bucsek
Grant A. Hudish
Glen S. Bigelow
Ronald D. Noebe
Aaron P. Stebner
Publikationsdatum
01.03.2016
Verlag
Springer International Publishing
Erschienen in
Shape Memory and Superelasticity / Ausgabe 1/2016
Print ISSN: 2199-384X
Elektronische ISSN: 2199-3858
DOI
https://doi.org/10.1007/s40830-016-0052-5

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