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Journal of Nanoparticle Research

Erschienen in:

01.01.2011 | Brief Communication

Low temperature synthesis of iron containing carbon nanoparticles in critical carbon dioxide

verfasst von: Takashi Hasumura, Takahiro Fukuda, Raymond L. D. Whitby, Ortrud Aschenbrenner, Toru Maekawa

Erschienen in: Journal of Nanoparticle Research | Ausgabe 1/2011

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Abstract

We develop a low temperature, organic solvent-free method of producing iron containing carbon (Fe@C) nanoparticles. We show that Fe@C nanoparticles are self-assembled by mixing ferrocene with sub-critical (25.0 °C), near-critical (31.0 °C) and super-critical (41.0 °C) carbon dioxide and irradiating the solutions with UV laser of 266-nm wavelength. The diameter of the iron particles varies from 1 to 100 nm, whereas that of Fe@C particles ranges from 200 nm to 1 μm. Bamboo-shaped structures are also formed by iron particles and carbon layers. There is no appreciable effect of the temperature on the quantity and diameter distributions of the particles produced. The Fe@C nanoparticles show soft ferromagnetic characteristics. Iron particles are crystallised, composed of bcc and fcc lattice structures, and the carbon shells are graphitised after irradiation of electron beams.

Vorheriger Artikel Surface modification of permalloy (Ni80Fe20) nanoparticles for biomedical applications

Nächster Artikel Computational approach to drying a nanoparticle-suspended liquid droplet

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Titel: Low temperature synthesis of iron containing carbon nanoparticles in critical carbon dioxide
verfasst von: Takashi Hasumura
Takahiro Fukuda
Raymond L. D. Whitby
Ortrud Aschenbrenner
Toru Maekawa
Publikationsdatum: 01.01.2011
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 1/2011
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-010-0142-9

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