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Journal of Materials Science
Erschienen in: Journal of Materials Science 7/2016

22.12.2015 | Original Paper

Luminescence properties of M3(VO4)2:Eu3+(M = Ca, Sr, Ba) phosphors

verfasst von: Xiaoyun Mi, Hui Shi, Zan Wang, Lingjie Xie, Hongyan Zhou, Jiangang Su, Jun Lin

Erschienen in: Journal of Materials Science | Ausgabe 7/2016

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Abstract

In this paper, M3(VO4)2:Eu3+(M = Ca, Sr, Ba) phosphors have been synthesized by high-temperature solid-state method. The phase composition and luminescence properties of the synthesized phosphors were characterized by X-ray powder diffraction and photoluminescence (PL) spectra, respectively. The influences of fluxing agent and doped concentration of rare-earth ions on PL properties of the phosphor were investigated. The results indicated that the energy transfers between VO4 3− and Eu3+ in the host occurred mainly via a dipole–dipole interaction mechanism. The increase in cation radius (from Ca2+ to Ba2+) in the host causes the emission peak originated from 5D0 → 7F2 transition of Eu3+ shifting from 615 to 621 nm, as well as decreasing the fluorescence lifetimes of Eu3+ from 0.77 to 0.19 ms and changing the CIE chromaticity coordinates from the orange-red region to the white region. Moreover, the emission colors of Ba3−x (VO4)2:xEu3+ can be firstly adjusted from cyan region to white light region via controlling the concentration of Eu3+. Temperature-dependent luminescence spectra proved the good thermal stability of the as-prepared phosphor. This work shows the potential application of europium-doped samples in UV converted pc-WLEDs.
Vorheriger Artikel Mesoporous activated carbon decorated with MnO as anode materials for lithium ion batteries
Nächster Artikel Acicular ferrite formation during isothermal holding in HSLA steel

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Literatur
1.
Pitale SS, Gohain M, Nagpure IM, Ntwaeaborwa OM, Bezuidenhoudt BCB, Swart HC (2012) A comparative study on structural, morphological and luminescence characteristics of Zn3(VO4)2 phosphor prepared via hydrothermal and citrate-gel combustion routes. Phys B 407:1485–1488CrossRef
2.
Sohn KS, Zeon W, Chang H, Lee SK, Park HD (2002) Combinatorial search for new red phosphors of high efficiency at VUV excitation based on the YRO4 (R = As, Nb, P, V) system. Chem Mater 14:2140–2148CrossRef
3.
Guo C, Zhang W, Luan L, Chen T, Cheng H, Huang D (2008) A promising red-emitting phosphor for white light emitting diodes prepared by sol–gel method. Sens Actuator B-Chem 133:9–33CrossRef
4.
Bai X, Song HW, Pan GH, Lei YQ, Wang T, Ren XG, Lu SZ, Dong B, Dai QL, Fan LB (2007) Size-dependent up-conversion luminescence in Er3+/Yb3+Co-doped nanocrystalline yttria: saturation and thermal effects. J Phys Chem C 111:13611–13617CrossRef
5.
Ghosh P, Oliva J, Rosa EDL, Haldar KK, Solis D, Patra A (2008) Enhancement of up-conversion emission of LaPO4: Er@Yb core–shell nanoparticles/nanorods. J Phys Chem C 112:9650–9658CrossRef
6.
Grzechnik A, Mcmillan PF (1997) High pressure behavior of Sr3(VO4)2 and Ba3(VO4)2. J Solid State Chem 132(1):156–162CrossRef
7.
Brixner LH, Flournoy PA (1965) Calcium orthovanadate Ca3(VO4)2: a new laser host crystal. J Electrochem Soc 112(3):303–308CrossRef
8.
Zhou XC, Zhong LP, Liu QP, Kuang RY, Chen HM (2009) Luminescence properties of Bi Co doped and P Co doped Ca3(VO4)2: Eu3+. Inorg Mater 45(3):1295–1298CrossRef
9.
Larson C, Dreele RBV (1994) General structure analysis system (GSAS). Los Alamos National Laboratory, Los Alamos, pp 86–748
10.
Lv WZ, Jiao MM, Zhao Q, Shao BQ, Lü W, You HP (2014) Ba1.3Ca0.7SiO4:Eu2+, Mn2+: a promising single-phase, color-tunable phosphor for near-ultraviolet white-light-emitting diodes. Inorg Chem 53:11007–11014CrossRef
11.
Knyazev AV, Chernorukov NG, Sazonov AA, Bulanov EN (2012) Synthesis and study of compounds of the general formula MIITh(VO4)2(MII = Mn, Cd, Ca, Sr, Pb, Ba). Russ J Inorg Chem 57(5):639–645CrossRef
12.
Evans JSO, Huang J, Sleight AW (2001) Synthesis and structure of ACa9(VO4)7 compounds, A = Bi or a rare earth. J Solid State Chem 157:255–260CrossRef
13.
Belik AA, Morozov VA, Khasanov SS, Lazoryak BI (1997) Crystal structures of double vanadates Ca9R(VO4)7: I.R = La, Pr, and Eu. Crystallogr Rep 42(5):751
14.
Liu G, Greedan JE (1994) Syntheses structures and characterization of 5-layer BaVO3−x (X = 0.2, 0.1, 0.0). J Solid State Chem 110:274–289CrossRef
15.
Qiu KH, Li JF, Li JF, Lu XG, Gong YC, Li JH (2010) Luminescence property of Ca3(VO4)2: Eu3+ dependence on molar ratio of Ca/V and solution combustion synthesis temperature. J Mater Sci 45:5456–5462. doi:10.​1007/​s10853-010-4598-x CrossRef
16.
Chen X, Xia ZG (2013) Luminescence properties of Li2Ca2ScV3O12 and Li2Ca2ScV3O12: Eu3+ synthesized by solid-state reaction method. Opt Mater 35(12):2736–2739CrossRef
17.
Blasse G (2006) The Luminescence of closed-shell transition-metal complexes. New developments. In: Luminescence and energy transfer. Springer, Berlin, pp 1–41
18.
Nakajima T, Isobe M, Tsuchiya T, Ueda Y, Manabe T (2010) Correlation between luminescence quantum efficiency and structural properties of vanadate phosphors with chained, dimerized, and isolated VO4 tetrahedra. J Phys Chem C 114:5160–5167CrossRef
19.
Riwotzki K, Hasse M (1998) Wet-chemical synthesis of doped colloidal nanoparticles YVO4: Ln (Ln = Eu, Sm, Dy). J Phys Chem B 102:10129–10235CrossRef
20.
21.
Mi XY, Du K, Huang K, Zhou P, Geng DL, Zhang Y, Shang MM, Lin J (2014) Synthesis and luminescence of Ca9Eu1−xLnx(VO4)7 (Ln = Y, La, Gd, Lu) phosphors. Mater Res Bull 60:72–78CrossRef
22.
Zhou Z, Wang NF, Zhou N, He ZX, Liu SQ, Liu YN, Tian ZW, Mao ZY, Hintzen HT (2013) High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7: Eu3+. J Phys D Appl Phys 46:6035104
23.
Harabor NA (2013) Thermal and spectral behavior of (Y, Eu)VO4 powder. J Therm Anal Calorim 111:1211–1219CrossRef
24.
Muhammad R, Iqbal Y, Reaney IM (2015) Structure and microwave dielectric properties of La5−xSrxTi4+xGa1−xO17 ceramics. J Mater Sci 50:3510–3516. doi:10.​1007/​s10853-015-8914-3
25.
Wang ZJ, Li PL, Zhang X, Li QX, Li T, Yang ZP, Guo QL (2013) Improvement orange-red emitting by codoping A+(A = Li, Na, K) in Ca2BO3Cl:Sm3+ phosphor. Phys B 414:56–59CrossRef
26.
Zhou XC, Zhong LP, Liu QP, Kuang RY, Chen HM (2009) Luminescence properties of Bi co-doped and P co-doped Ca3(VO4)2: Eu3+. Inorg Mater 45(11):1295–1298CrossRef
27.
Blasse G (1969) Energy transfer in oxiidic phosphors. Philips Res Rep 24:131–134
28.
Dorenbos P (2002) Relating the energy of the [Xe]5d1 configuration of Ce3+ in inorganic compounds with anion polarizability and cation electronegativity. Phys Rev B 65(1–6):235110CrossRef
29.
Dorenbos P (2003) Calculation of the energy of the 5d barycenter of La3F3[Si3O9]:Ce3+. J Lumin 105:117–119CrossRef
30.
Van Uitert L (1967) Up-conversion and excited state energy transfer in rare-earth doped materials. J Electrochem Soc 114(10):1048–1053CrossRef
31.
Mi XY, Sun JC, Zhou P, Zhou HY, Song D, Li K, Shang MM, Lin J (2015) Tunable luminescence and energy transfer properties in Ca8MgLu(PO4)7:Ce3+, Tb3+, Mn2+ phosphors. J Mater Chem C 3:4471–4481CrossRef
32.
Han LL, Wang YH, Zhang J, Wang YZ (2013) Enhancement of red emission intensity of Ca9Y(VO4)7:Eu3+ phosphor via Bi co-doping for the application to white LEDs. Mater Chem Phys 139:87–91CrossRef
33.
Dutczak D, Ronda C, Meijerink A, Justel T (2013) Red luminescence and persistent luminescence of Sr3Al2O5 Cl2: Eu2+, Dy3+. J Lumin 141:150–154CrossRef
34.
Yeh CW, Liu RS, Chen WT, Hu SF, Sheu HS, Chen JM, Hintzen HT (2012) Origin of thermal degradation of Sr2−xSi5N8: Eux phosphors in air for light-emitting diodes. J Am Chem Soc 134:14108–14117CrossRef
35.
Huang Y, Nakai Y, Tsuboi T, Seo HJ (2011) The new red-emitting phosphor of oxyfluoride Ca2RF4PO4: Eu3+ (R = Gd, Y) for solid state lighting applications. Opt Express 19:6303–6311CrossRef
36.
Liu WR, Yeh CW, Huang CH, Lin CC, Chiu YC, Yeh YT, Liu RS (2011) (Ba, Sr)Y2Si2Al2O2N5: Eu2+: a novel near-ultraviolet converting green phosphor for white light-emitting diodes. J Mater Chem 21:3740–3744CrossRef
37.
Chen L, Lin CC, Yeh CW, Liu RS (2010) Light converting inorganic phosphors for white light-emitting diodes. Materials 3:2172–2195CrossRef
38.
Geng DL, Shang MM, Zhang Y, Cheng ZC, Lin J (2013) Tunable and white-light emission from single-phase Ca2YF4PO4: Eu2+, Mn2+ phosphors for application in W-LEDs. Eur J Inorg Chem 16:2947–2953CrossRef
Metadaten
Titel
Luminescence properties of M3(VO4)2:Eu3+(M = Ca, Sr, Ba) phosphors
verfasst von
Xiaoyun Mi
Hui Shi
Zan Wang
Lingjie Xie
Hongyan Zhou
Jiangang Su
Jun Lin
Publikationsdatum
22.12.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9674-9

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