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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 3/2020

13.01.2020 | Original Contribution

Luminescent lanthanide metallogels: situ fabrication, self-healing and rheological properties

verfasst von: Min Xue, Ming Chen, Wenhao Chang, Ruiyang Chen, Pengna Li

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2020

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Abstract

We have presented a simple method for situ fabrication of photoluminescent lanthanide metallogels. A series of lanthanide metallogels could be rapidly formed through mixing the aqueous solution of Tb3+ or Eu3+ and organic solution of synthesized aromatic carboxylic ligands (DCn, n = 14, 16,18) at room temperature. The gelation tests revealed that the ligand with longer alkyl chain (DC18) showed stronger gelling abilities, indicating that the structure of non-coordinated groups in ligand molecules could affect self-assembly processes and, hence, the microstructures and properties of lanthanide metallogels. FT-IR measurements demonstrated that the driving force of formation of the metallogels was the coordination interaction between DCn and Tb3+ or Eu3+. XRD analysis revealed that DC14 metallogels took a mixture of hexagonal and tetragonal packing modes. All obtained metallogels have shown typical luminescent emissions of the lanthanide complex. In particular, DC18/Tb(NO3)3 metallogel in DMF/H2O (v:v = 1:1) has shown excellent self-supporting, self-healing, film-forming, and rheological properties.
Vorheriger Artikel Synthesis of sub-100 nm PMMA nanoparticles initiated by ammonium persulfate/ascorbic acid in acetone-water mixture
Nächster Artikel Rheological properties of multi-walled carbon nanotubes/silica shear thickening fluid suspensions

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Literatur
1.
Whitesides GM, Grzybowski BA (2005) Self-assembly at all scales. Science 295(29):2418–2421
2.
Jones CD, Steed JW (2016) Gels with sense: supramolecular materials that respond to heat, light and sound. Chem Soc Rev 45(23):6546–6596PubMed
3.
Kishimura A, Yamashita T, Aida T (2005) Phosphorescent organogels via “metallophilic” interactions for reversible RGB-color switching. J Am Chem Soc 127(1):179–183PubMed
4.
Dong S, Luo Y, Yan X, Zheng B, Ding X, Yu Y, Ma Z, Zhao Q, Huang F (2011) A dual-responsive supramolecular polymer gel formed by crown ether based molecular recognition. Angew Chem Int Ed Engl 50(8):1905–1909PubMed
5.
Rodriguez F, Miravet JF, Escuder B (2009) A supramolecular hydrogel as a reusable heterogeneous catalyst for the direct aldol reaction. Chem Commun 47:7303–7305
6.
Kawano SI, Tamaru SI, Fujita N, Shinkai S (2004) Sol-gel polycondensation of tetraethyl orthosilicate (TEOS) in sugar-based porphyrin organogels: inorganic conversion of a sugar-directed porphyrinic fiver library through sol-gel transcription processes. Chem Eur J 10(2):343–351PubMed
7.
Okesola BO, Smith DK (2016) Applying low-molecular weight supramolecular gelators in an environmental setting - self-assembled gels as smart materials for pollutant removal. Chem Soc Rev 45(15):4226–4251PubMed
8.
Xu ZY, Peng JX, Yan N, Yu H, Zhang SS, Liu KQ, Fang Y (2013) Simple design but marvelous performances: molecular gels of superior strength and self-healing properties. Soft Matter 9(4):1091–1099
9.
Piepenbrock MM, Lloyd GO, Clarke N, Steed JW (2010) Metal- and anion-binding supramolecular gels. Chem Rev 110(4):1960–2004PubMed
10.
Tam AYY, Yam VWW (2013) Recent advances in metallogels. Chem Soc Rev 42(4):1540–1567PubMed
11.
Zhang J, Su CY (2013) Metal-organic gels: from discrete metallogelators to coordination polymers. Coord Chem Rev 257(7–8):1373–1408
12.
Sutar P, Maji TK (2016) Coordination polymer gels: soft metal-organic supramolecular materials and versatile applications. Chem Commun 52(52):8055–8074
13.
Häring M, Díaz DD (2016) Supramolecular metallogels with bulk self-healing properties prepared by in situ metal complexation. Chem Commun 52(89):13068–13081
14.
Karak S, Kumar S, Bera S, Díaz Díaz D, Banerjee S, Vanka K, Banerjee R (2017) Interplaying anions in a supramolecular metallohydrogel to form metal organic framework. Chem Commun 53(26):3705–3708
15.
Ganta S, Chand DK (2018) Multi-stimuli-responsive metallogel molded from a Pd2L4-type coordination cage: selective removal of anionic dyes. Inorg Chem 57(7):3634–3645PubMed
16.
Xue M, Lü YC, Sun QQ, Liu KQ, Liu Z, Sun P (2015) Ag(I)-coordinated supramolecular metallogels based on Schiff base ligands: structural characterization and reversible thixotropic property. Cryst Growth Des 15(11):5360–5367
17.
Park J, Lee JH, Jawprski J, Shinkai S, Jung JH (2014) Luminescent calyx[4]arene-based metallogel formed at different solvent composition. Inorg Chem 53(14):7181–7187PubMed
18.
Karan CK, Sau MC, Bhattacharjee M (2017) A copper(II) metal-organic hydrogel as a multifunctional precatalyst for CuAAC reactions and chemical fixation of CO2 under solvent free conditions. Chem Commun 53(9):1526–1529
19.
Mitsumoto K, Cameron JM, Wei RJ, Nishikawa H, Shiga T, Nihei M, Newton GN, Oshio H (2017) A multi-redox responsive cyanometalate-based metallogel. Chem Eur J 23(7):1502–1506PubMed
20.
Lin Q, Lu TT, Zhu X, Sun B, Yang QP, Wei TB, Zhang YM (2015) A novel supramolecular metallogel-based high-resolution anion sensor array. Chem Commun 51(9):1635–1638
21.
Mallick A, Schön E, Panda T, Sreenivas K, Díaz D, Banerjee R (2012) Fine-tuning the balance between crystallization and gelation and enhancement of CO2 uptake on functionalized calcium based MOFs and metallogels. J Mater Chem 22(30):14951–14963
22.
Qin X, Liu XW, Huang W, Bettinelli M, Liu XG (2017) Lanthanide-activated phosphors based on 4f-5d optical transitions: theoretical and experimental aspects. Chem Rev 117(5):4488–4527PubMed
23.
Eliseeva SV, Bünzli JG (2010) Lanthanide luminescence for functional materials and bio-sciences. Chem Soc Rev 39(1):189–227PubMed
24.
Feng J, Zhang HJ (2013) Hybrid materials based on lanthanide organic complexes: a review. Chem Soc Rev 42(1):387–410PubMed
25.
Binnemans K (2009) Lanthanide-based luminescent hybrid materials. Chem Rev 109(9):4283–4374PubMed
26.
dos Santos CMG, Harte AJ, Quinn SJ, Gunnlaugsson T (2008) Recent developments in the field of supramolecular lanthanide luminescent sensors and self-assemblies. Coord Chem Rev 252(23–24):2512–2572
27.
Rajendran M, Yapici E, Miller LW (2014) Lanthanide-based imaging of protein interactions in live cells. Inorg Chem 53(4):1839–1853PubMed
28.
Shavaleev NM, Eliseeva SV, Scopelliti R, Bünzli JG (2015) Influence of symmetry on the luminescence and radiative lifetime of nine-coordinate europium complexes. Inorg Chem 54(18):9166–9173PubMed
29.
Kotova O, Daly R, dos Santosv CMG, Boese M, Kruger PE, Boland JJ, Gunnlaugsson T (2012) Europium-directed self-assembly of a luminescent supramolecular gel from a tripodal terpyridine-based ligand. Angew Chem Int Ed 51(1):1–6
30.
Martínez-Calvo M, Kotova O, Möbius ME, Bell AP, McCabe T, Boland JJ, Gunnlaugsson T (2015) Healable luminescent self-assembly supramolecular metallogels possessing lanthanide (Eu/Tb) dependent rheological and morphological properties. J Am Chem Soc 137(5):1983–1992PubMed
31.
Chen PK, Li QC, Grindy S, Holten-Andersen N (2015) White-light-emitting lanthanide metallogels with tunable luminescence and reversible stimuli-responsive properties. J Am Chem Soc 137(36):11590–11593PubMed
32.
Ma XX, Cui YQ, Liu SW, Wu JC (2017) A thermo-responsive supramolecular gel and its luminescence enhancement induced by rare earth Y3+. Soft Matter 13(44):8027–8030PubMed
33.
Pedireddi VR, Varughese S (2004) Solvent-dependent coordination polymers: cobalt complexes of 3,5-dinitrobenzoic acid and 3,5-dinitro-4-methylbenzoic acid with 4,4′-bipyrdine. Inorg Chem 43(2):450–457PubMed
34.
Carlucci L, Ciani G, Proserpio DM, Sironi A (1995) Novel networks of unusually coordinated silver (I) cations: the wafer-like structure of [Ag(pyz)2][Ag2(pyz)5](PF6)3•2G and the simple cubic frame of [Ag(pyz)3](SbF6). Angew Chem Int Ed Engl 34(17):1895–1898
35.
Ma XX, Yu DW, Tang N, Wu JC (2014) Tb3+-containing supramolecular hydrogels: luminescence properties and reversible sol-gel transitions induced by external stimuli. Dalton Trans 43(26):9856–9859PubMed
36.
Hu JS, Guo YG, Liang HP, Wan LJ, Jiang L (2005) Three-dimensional self-organization of supramolecular self-assembled porphyrin hollow hexagonal nanoprisms. J Am Chem Soc 127(48):17090–17095PubMed
37.
Kim HJ, Zin WC, Lee M (2004) Anion-directed self-assembly of coordination polymer into tunable secondary structure. J Am Chem Soc 126(22):7009–7014PubMed
38.
Qiao Y, Lin YY, Zhang SF, Huang JB (2011) Lanthanide-containing photoluminescent materials: from hybrid hydrogel to inorganic nanotubes. Chem Eur J 17(18):5180–5187PubMed
39.
Harada A, Takashima Y, Nakahata M (2014) Supramolecular polymeric materials via cyclodextrin-guest interactions. Acc Chem Res 47(7):2128–2140PubMed
40.
Brantley JN, Wiggins KM, Bielawski CW (2013) Squeezing new life out of polymers. Angew Chem Int Ed 52(14):3806–3808
41.
Kirilov P, Gauffre F, Franceschi-Messant S, Perez E, Rico-Lattes I (2009) Rheological characterization of a new type of colloidal dispersion based on nanoparticles of gelled oil. J Phys Chem B 113(32):11101–11108PubMed
42.
Yuan JC, Fang XL, Zhang LX, Hong GN, Lin YJ, Zheng QF, Xu YZ, Ruan YH, Weng WG, Xia HP, Chen GH (2012) Multi-responsive self-healing metallo-supramolecular gels based on “click” ligand. J Mater Chem 22(23):11515–11522
Metadaten
Titel
Luminescent lanthanide metallogels: situ fabrication, self-healing and rheological properties
verfasst von
Min Xue
Ming Chen
Wenhao Chang
Ruiyang Chen
Pengna Li
Publikationsdatum
13.01.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 3/2020
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-020-04598-4

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