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Journal of Nanoparticle Research

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01.05.2018 | Research Paper

Magnetic Pd nanocatalyst Fe₃O₄@Pd for C–C bond formation and hydrogenation reactions

verfasst von: Catalina Biglione, Ariel L. Cappelletti, Miriam C. Strumia, Sandra E. Martín, Paula M. Uberman

Erschienen in: Journal of Nanoparticle Research | Ausgabe 5/2018

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Abstract

Small core-shell Fe₃O₄@Pd superparamagnetic nanoparticles (MNPs) were obtained with good control in size and shape distribution by metal-complex thermal decomposition in organic media. The role of the stabilizer in the synthesis of MNPs was studied, employing oleylamine (OA), triphenylphosphine (TPP) and triphenylamine (TPA). The results revealed that, among the stabilizer investigated, the presence of oleylamine in the reaction media is crucial in order to obtain an uniform shell of Pd(0) in Fe₃O₄@Pd MNPs of 7 ± 1 nm. The synthesized core-shell MNPs were tested in Pd-catalyzed Heck-Mizoroki and Suzuki-Miyaura coupling reactions and p-chloronitrobenzene hydrogenation. High conversion, good reaction yields, and good TOF values were achieved in the three reaction systems with this nanocatalyst. The core-shell nanoparticle was easily recovered by a simple magnetic separation using a neodymium commercial magnet, which allowed performing up to four cycles of reuse.

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Titel: Magnetic Pd nanocatalyst Fe3O4@Pd for C–C bond formation and hydrogenation reactions
verfasst von: Catalina Biglione
Ariel L. Cappelletti
Miriam C. Strumia
Sandra E. Martín
Paula M. Uberman
Publikationsdatum: 01.05.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 5/2018
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-018-4233-3

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