nach oben

Tribology Letters

Erschienen in:

01.10.2013 | Original Paper

Mechanism of Action of WS₂ Lubricant Nanoadditives in High-Pressure Contacts

verfasst von: Monica Ratoi, Vlad Bogdan Niste, John Walker, Jurgita Zekonyte

Erschienen in: Tribology Letters | Ausgabe 1/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Because of their excellent tribological properties and potential to replace problematic lubricant additives currently in use, WS₂ nanoparticles have spurred considerable interest over the last two decades from academia and industry to decipher their mechanism of action. To elucidate the mechanism, this study carried out tribological tests at low and high temperatures and investigated the wear track and friction properties. It was found that in high-pressure, high-temperature sliding contacts, WS₂ nanoadditives react with the metal substrate to generate thick chemical tribofilms which account for their excellent tribological properties. Based on XPS and FIB/SIMS results, a layered structure was proposed for the chemically formed tribofilms. The large amount of W in the composition of the reacted tribofilm could explain the excellent mechanical and antiwear properties, while the exfoliated squashed WS₂ NPs which fill the gaps and cover the reacted tribofilm account for the striking reduction in the boundary friction.

Graphical Abstract

Vorheriger Artikel Tribological Behavior of Sheet Metal Forming Process Using Acoustic Emission Characteristics

Nächster Artikel In Situ Observation of Wax-in-Oil Flow in Rough Soft Contact

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Bakunin, V.N., Suslov, A.Y., Kuzmina, G.N., Parenago, O.P.: Synthesis and application of inorganic nanoparticles as lubricant components—a review. J. Nanopart. Res. 6(2), 273–284 (2004). doi:10.1023/B:NANO.0000034720.79452.e3 CrossRef

Rozenberg, B.A., Tenne, R.: Polymer-assisted fabrication of nanoparticles and nanocomposites. Prog. Polym. Sci. 33(1), 40–112 (2008). doi:10.1016/j.progpolymsci.2007.07.004 CrossRef

Wu, Y.Y., Tsui, W.C., Liu, T.C.: Experimental analysis of tribological properties of lubricating oils with nanoparticle additives. Wear 262(7–8), 819–825 (2007). doi:10.1016/j.wear.2006.08.021 CrossRef

Zhang, M., Wang, X., Fu, X., Xia, Y.: Performance and anti-wear mechanism of CaCO₃ nanoparticles as a green additive in poly-alpha-olefin. Tribol. Int. 42(7), 1029–1039 (2009). doi:10.1016/j.triboint.2009.02.012 CrossRef

Hernandez Battez, A., Gonzalez, R., Viesca, J.L., Fernandez, J.E., Diaz Fernandez, J.M., Machado, A., Chou, R., Riba, J.: CuO, ZrO₂ and ZnO nanoparticles as antiwear additive in oil lubricants. Wear 265(3–4), 422–428 (2008). doi:10.1016/j.wear.2007.11.013 CrossRef

Tenne, R., Redlich, M.: Recent progress in the research of inorganic fullerene-like nanoparticles and inorganic nanotubes. Chem. Soc. Rev. 39(5), 1423–1434 (2010). doi:10.1039/B901466G CrossRef

Greenberg, R., Halperin, G., Etsion, I., Tenne, R.: The effect of WS₂ nanoparticles on friction reduction in various lubrication regimes. Tribol. Lett. 17(2), 179–186 (2004). doi:10.1023/B:TRIL.0000032443.95697.1d CrossRef

Eidelman, O., Friedman, H., Rosentveig, R., Moshkovith, A., Perfiliev, V., Cohen, S.R., Feldman, Y., Rapoport, L., Tenne, R.: Chromium-rich coatings with WS₂ nanoparticles containing fullerene-like structure. NANO 6(4), 313–324 (2011). doi:10.1142/S1793292011002755 CrossRef

Redlich, M., Katz, A., Rapoport, L., Wagner, H.D., Feldman, Y., Tenne, R.: Improved orthodontic stainless steel wires coated with inorganic fullerene-like nanoparticles of WS₂ impregnated in electroless nickel-phosphorous film. Dent. Mater. 24(12), 1640–1646 (2008). doi:10.1016/j.dental.2008.03.030 CrossRef

10.

Wu, J.F., Zhai, W.S., Jie, G.F.: Preparation and tribological properties of WS₂ nanoparticles modified by trioctylamine. Proc. Inst. Mech. Eng. Part J 223(4), 695–703 (2009). doi:10.1243/13506501JET494 CrossRef

11.

Wu, J., Zhai, W., Jie, G.: Preparation and tribological properties of tungsten disulfide hollow spheres assisted by methyltrioctylammonium chloride. Tribol. Int. 43(9), 1650–1658 (2010). doi:10.1016/j.triboint.2010.03.012 CrossRef

12.

Hubert, T., Hattermann, H., Griepentrog, M.: Sol-gel-derived nanocomposite coatings filled with inorganic fullerene-like WS₂. J. Sol-Gel. Sci. Technol. 51(3), 295–300 (2009). doi:10.1007/s10971-009-1896-3 CrossRef

13.

Chang, L., Yang, H., Fu, W., Yang, N., Chen, J., Li, M., Zou, G., Li, J.: Synthesis and thermal stability of W/WS₂ inorganic fullerene-like nanoparticles with core-shell structure. Mater. Res. Bull. 41(7), 1242–1248 (2006). doi:10.1016/j.materresbull.2006.01.019 CrossRef

14.

Abate, F., D’Agostino, V., Di Giuda, R., Senatore, A.: Tribological behaviour of MoS₂ and inorganic fullerene-like WS₂ nanoparticles under boundary and mixed lubrication regimes. Tribology 4(2), 91–98 (2010). doi:10.1179/175158310X12678019274282

15.

Rapoport, L., Bilik, Y., Feldman, Y., Homyonfer, M., Cohen, S.B., Tenne, R.: Hollow nanoparticles of WS₂ as potential solid-state lubricants. Nature 387, 791–793 (1997)CrossRef

16.

Rapoport, L., Feldman, Y., Homyonfer, M., Cohen, H., Sloan, J., Hutchinson, J.L., Tenne, R.: Inorganic fullerene-like material as additives to lubricants: structure-function relationship. Wear 225–229(2), 975–982 (1999). doi:10.1016/S0043-1648(99)00040-X CrossRef

17.

Cizaire, L., Vacher, B., Le Mogne, T., Martin, J.M., Rapoport, L., Margolin, A., Tenne, R.: Mechanisms of ultra-low friction by hollow inorganic fullerene-like MoS₂ nanoparticles. Surf. Coat. Technol. 160(2–3), 282–287 (2002). doi:10.1016/S0257-8972(02)00420-6 CrossRef

18.

Rapoport, L., Leshchinsky, V., Lapsker, I., Volovik, Y., Nepomnyashchy, O., Lvovsky, M., Popovitz-Biro, R., Feldman, Y., Tenne, R.: Tribological properties of WS₂ nanoparticles under mixed lubrication. Wear 255(7), 785–793 (2003). doi:10.1016/S0043-1648(03)00044-9 CrossRef

19.

Rapoport, L., Nepomnyashchy, O., Lapsker, I., Verdyan, A., Moshkovich, A., Feldman, Y., Tenne, R.: Behaviour of fullerene-like WS₂ nanoparticles under severe contact conditions. Wear 259(1–6), 703–707 (2005). doi:10.1016/j.wear.2005.01.009 CrossRef

20.

Joly-Pottuz, L., Dassenoy, F., Belin, M., Vacher, B., Martin, J.M., Fleischer, N.: Ultralow-friction and wear properties of IF-WS₂ under boundary lubrication. Tribol. Lett. 18(4), 477–484 (2005). doi:10.1007/s11249-005-3607-8 CrossRef

21.

Tevet, O., Von-Huth, P., Popovitz-Biro, R., Rosentsveig, R., Wagner, H.D., Tenne, R.: Friction mechanism of individual multi-layered nanoparticles. Proc. Natl. Acad. Sci. U.S.A., Early Ed. 108(50), 19901–19906 (2011). doi:10.1073/pnas.1106553108 CrossRef

22.

Lahouij, I., Dassenoy, F., de Knoop, L., Martin, J.M., Vacher, B.: In situ TEM observation of the behavior of an individual fullerene-like MoS₂ nanoparticle in a dynamic Contact. Tribol. Lett. 42, 133–140 (2011)CrossRef

23.

Golan, Y., Drummond, C., Israelachvili, J., Tenne, R.: In situ imaging of shearing contacts in the surface forces apparatus. Wear 245(1–2), 190–195 (2000). doi:10.1016/S0043-1648(00)00478-6 CrossRef

24.

Yadgarov, L., Petrone, V., Rosentsveig, R., Feldman, Y., Tenne, R., Senatore, A.: Tribological studies of rhenium doped fullerene-like MoS₂ nanoparticles in boundary, mixed and elasto-hydrodynamic lubrication conditions. Wear 297, 1103–1110 (2013)CrossRef

25.

Martin, J.M., Ohmae, N.: Nanoparticles made of metal dichalcogenides. In: Neale, M.J., Priest, M., Stachowiak, G. (eds.) Nanolubricants; Volume 13 of Tribology in Practice Series, pp. 15–40. Wiley, Chichester (2008). doi:10.1002/9780470987711

26.

Fang, X., Hua, C., Wu, C., Wang, X., Shen, L., Kong, Q., Wang, J., Hu, Y., Wang, Z., Chen, L.: Synthesis and electrochemical performance of graphene-like WS₂. Chem-Eur. J. 19(18), 5694–5700 (2013). doi:10.1002/chem.201204254 CrossRef

27.

Dumcenco, D.O., Chen, K.Y., Wang, Y.P., Huang, Y.S., Tiong, K.K.: Raman study of 2H-Mo_1-xW_xS₂ layered mixed crystals. J. Alloys Compd. 506(12), 940–943 (2010). doi:10.1016/j.jallcom.2010.07.120 CrossRef

28.

Ratoi, M., Castle, R.C., Bovington, C.H., Spikes, H.A.: The influence of soot and dispersant on ZDDP film thickness and friction. Lubr. Sci. 17(1), 25–43 (2004). doi:10.1002/ls.3010170103 CrossRef

29.

Aktary, M., McDermott, M.T., McAlpine, G.A.: Morphology and nanomechanical properties of ZDDP antiwear films as a function of tribological contact time. Tribol. Lett. 12(3), 155–162 (2001)CrossRef

30.

PCS Instruments. MTM (Mini Traction Machine). Retrieved: http://www.pcs-instruments.com/brochures/brochures.shtml#page=page-7

31.

Spikes, H.A.: The history and mechanisms of ZDDP. Tribol. Lett. 17, 465–485 (2004)

32.

Ratoi, M., Bovington, C.H., Spikes, H.A.: In situ study of metal oleate friction modifier additives. Tribol. Lett. 14(1), 33–40 (2003). doi:10.1023/A:1021714231949 CrossRef

33.

Xie, F.Y., Gong, L., Liu, X., Tao, Y.T., Zhang, W.H., Chen, S.H., Meng, H., Chen, J.: XPS studies on surface reduction of tungsten oxide nanowire film by Ar + bombardment. J. Electron Spectrosc. Relat. Phenom. 185(3–4), 112–118 (2012). doi:10.1016/j.elspec.2012.01.004 CrossRef

34.

Spath, B., Kopnov, F., Cohen, H., Zak, A., Moshkovich, A., Rapoport, L., Jagermann, W., Tenne, R.: X-ray photoelectron spectroscopy and tribology studies of annealed fullerene-like WS₂ nanoparticles. Phys. Status Solidi B 245(9), 1779–1784 (2008). doi:10.1002/pssb.200779531 CrossRef

35.

Beake, B.D., Zheng, S., Alexander, M.R.: Nanoindentation testing of plasma-polymerised hexane films. J. Mater. Sci. 37(18), 3821–3826 (2002). doi:10.1023/A:1019626732319 CrossRef

36.

Oliver, W.C., Pharr, G.M.: An improved technique for determining hardness and elastic-modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7(6), 1564–1583 (1992). doi:10.1557/JMR.1992.1564 CrossRef

37.

Pereira, G., Lachenwitzer, A., Kasrai, M., Bancroft, G.M., Norton, P.R., Abrecht, M., Gilbert, P.U.P.A., Regier, T., Blyth, R.I.R., Thompson, J.: Chemical and mechanical analysis of tribofilms from fully formulated oils part 1—films on 52100 steel. Tribology 1(1), 48–61 (2007). doi:10.1179/175158407X189293

38.

Bec, S., Tonck, A., Georges, J.M., Roper, G.W.: Synergistic effects of MoDTC and ZDDP on frictional behaviour of tribofilms at the nanometer scale. Tribol. Lett. 17(4), 797–809 (2004). doi:10.1007/s11249-004-8088-7 CrossRef

Titel: Mechanism of Action of WS2 Lubricant Nanoadditives in High-Pressure Contacts
verfasst von: Monica Ratoi
Vlad Bogdan Niste
John Walker
Jurgita Zekonyte
Publikationsdatum: 01.10.2013
Verlag: Springer US
Erschienen in: Tribology Letters / Ausgabe 1/2013
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI: https://doi.org/10.1007/s11249-013-0195-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 1/2013

Dry-Blasting of α- and κ-Al2O3 CVD Hard Coatings: Friction Behaviour and Thermal Stress Relaxation

Tribological and Mechanical Behaviour of Epoxy/Nanoclay Composites

Flying Height Drop Due to Air Entrapment in Lubricant

Tribological Behavior of Sheet Metal Forming Process Using Acoustic Emission Characteristics

Lubricant Flow and Evaporation Model for Heat-Assisted Magnetic Recording Including Functional End-Group Effects and Thin Film Viscosity

In Situ Observation of Wax-in-Oil Flow in Rough Soft Contact

Premium Partner

Marktübersichten