Skip to main content
Erschienen in: Rare Metals 2/2014

01.04.2014

Microstructure and properties of Al0.3CrFe1.5MnNi0.5Ti x and Al0.3CrFe1.5MnNi0.5Si x high-entropy alloys

verfasst von: Bo Ren, Rui-Feng Zhao, Zhong-Xia Liu, Shao-Kang Guan, Hong-Song Zhang

Erschienen in: Rare Metals | Ausgabe 2/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this article, the microstructure, hardness, and corrosion resistance of the Al0.3CrFe1.5MnNi0.5Ti x and Al0.3CrFe1.5MnNi0.5Si x (x = 0, 0.2, 0.5, 1.0) high-entropy alloys were investigated via X-ray diffraction (XRD), scanning electron microscopy (SEM), digital display Vickers hardness tester, and electrochemical technique. These alloys are mainly composed of BCC solid-solution structure. When adding high content of Ti or Si element (x ≥ 0.5), some intermetallic compounds are found in the microstructure, which makes the alloys have a high hardness, high brittleness, and easy cracking. While the alloys with low content of Ti or Si (x = 0.2) have a hardness of HV 420–HV 430, and its hardness increases about 14 % compared with that of Al0.3CrFe1.5MnNi0.5. Electrochemical results in 3.5 % NaCl solution show that the alloying elements Ti and Si have a negative influence on the corrosion resistance of the Al0.3CrFe1.5MnNi0.5 alloys.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
[1]
Zurück zum Zitat Yeh JW. Recent progress in high-entropy alloys. Ann Chim Sci Mater. 2006;31(6):633.CrossRef Yeh JW. Recent progress in high-entropy alloys. Ann Chim Sci Mater. 2006;31(6):633.CrossRef
[2]
Zurück zum Zitat Cantor B, Chang ITH, Knight P, Vincent AJB. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng A. 2004;375–377:213.CrossRef Cantor B, Chang ITH, Knight P, Vincent AJB. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng A. 2004;375–377:213.CrossRef
[3]
Zurück zum Zitat Zhu C, Lu ZP, Nieh TG. Incipient plasticity and dislocation nucleation of FeCoCrNiMn high-entropy alloy. Acta Mater. 2013;61(8):2993.CrossRef Zhu C, Lu ZP, Nieh TG. Incipient plasticity and dislocation nucleation of FeCoCrNiMn high-entropy alloy. Acta Mater. 2013;61(8):2993.CrossRef
[4]
Zurück zum Zitat Tong CJ, Chen YL, Chen SK, Yeh JW, Shun TT, Tsau CH, Lin SJ, Chang SY. Microstructure characterization of Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A. 2005;36(4):881.CrossRef Tong CJ, Chen YL, Chen SK, Yeh JW, Shun TT, Tsau CH, Lin SJ, Chang SY. Microstructure characterization of Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A. 2005;36(4):881.CrossRef
[5]
Zurück zum Zitat Li C, Li JC, Zhao M, Jiang Q. Effect of alloying elements on microstructure and properties of multiprincipal elements high-entropy alloys. J Alloy Compd. 2009;475(1–2):752.CrossRef Li C, Li JC, Zhao M, Jiang Q. Effect of alloying elements on microstructure and properties of multiprincipal elements high-entropy alloys. J Alloy Compd. 2009;475(1–2):752.CrossRef
[6]
Zurück zum Zitat Chen TK, Wong MS, Shun TT, Yeh JW. Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering. Surf Coat Technol. 2005;200(5–6):1361.CrossRef Chen TK, Wong MS, Shun TT, Yeh JW. Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering. Surf Coat Technol. 2005;200(5–6):1361.CrossRef
[7]
Zurück zum Zitat Huang YS, Chen L, Lui HW, Cai MH, Yeh JW. Microstructure, hardness, resistivity and thermal stability of sputtered oxide films of AlCoCrCu0.5NiFe high-entropy alloy. Mater Sci Eng A. 2007;457(1–2):77.CrossRef Huang YS, Chen L, Lui HW, Cai MH, Yeh JW. Microstructure, hardness, resistivity and thermal stability of sputtered oxide films of AlCoCrCu0.5NiFe high-entropy alloy. Mater Sci Eng A. 2007;457(1–2):77.CrossRef
[8]
Zurück zum Zitat Tong CJ, Chen MR, Chen SK, Yeh JW, Shun TT, Lin SJ, Chang SY. Mechanical performance of the Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A. 2005;36(5):1263.CrossRef Tong CJ, Chen MR, Chen SK, Yeh JW, Shun TT, Lin SJ, Chang SY. Mechanical performance of the Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A. 2005;36(5):1263.CrossRef
[9]
Zurück zum Zitat Zhou YJ, Zhang Y, Wang YL, Chen GL. Microstructure and compressive properties of multicomponent Al x (TiVCrMnFeCoNiCu)100−x high-entropy alloys. Mater Sci Eng A. 2007;454–455:260.CrossRef Zhou YJ, Zhang Y, Wang YL, Chen GL. Microstructure and compressive properties of multicomponent Al x (TiVCrMnFeCoNiCu)100−x high-entropy alloys. Mater Sci Eng A. 2007;454–455:260.CrossRef
[10]
Zurück zum Zitat Wen LH, Kou HC, Li JS, Chang H, Xue XY, Zhou L. Effect of aging temperature on microstructure and properties of AlCoCrCuFeNi high-entropy alloy. Intermetallics. 2009;17(4):266.CrossRef Wen LH, Kou HC, Li JS, Chang H, Xue XY, Zhou L. Effect of aging temperature on microstructure and properties of AlCoCrCuFeNi high-entropy alloy. Intermetallics. 2009;17(4):266.CrossRef
[11]
Zurück zum Zitat Chen YY, Hong UT, Shih HC, Yeh JW, Duval T. Electrochemical kinetics of the high entropy alloys in aqueous environments: a comparison with type 304 stainless steel. Corros Sci. 2005;47(11):2679.CrossRef Chen YY, Hong UT, Shih HC, Yeh JW, Duval T. Electrochemical kinetics of the high entropy alloys in aqueous environments: a comparison with type 304 stainless steel. Corros Sci. 2005;47(11):2679.CrossRef
[12]
Zurück zum Zitat Tsai CW, Tsai MH, Yeh JW, Yang CC. Effect of temperature on mechanical properties of Al0.5CoCrCuFeNi wrought alloy. J Alloy Compd. 2010;490(1–2):160.CrossRef Tsai CW, Tsai MH, Yeh JW, Yang CC. Effect of temperature on mechanical properties of Al0.5CoCrCuFeNi wrought alloy. J Alloy Compd. 2010;490(1–2):160.CrossRef
[13]
Zurück zum Zitat Chen ST, Tang WY, Kuo YF, Chen SY, Tsau CH, Shun TT, Yeh JW. Microstructure and properties of age-hardenable Al x CrFe1.5MnNi0.5 alloys. Mater Sci Eng A. 2010;527(21–22):5818.CrossRef Chen ST, Tang WY, Kuo YF, Chen SY, Tsau CH, Shun TT, Yeh JW. Microstructure and properties of age-hardenable Al x CrFe1.5MnNi0.5 alloys. Mater Sci Eng A. 2010;527(21–22):5818.CrossRef
[14]
Zurück zum Zitat Shun TT, Du YC. Age hardening of the Al0.3CoCrFeNiC0.1 high entropy alloy. J Alloy Compd. 2009;478(1–2):269.CrossRef Shun TT, Du YC. Age hardening of the Al0.3CoCrFeNiC0.1 high entropy alloy. J Alloy Compd. 2009;478(1–2):269.CrossRef
[15]
Zurück zum Zitat Ranganathan S. Alloyed pleasures: multimetallic cocktails. Curr Sci. 2003;85(10):1404. Ranganathan S. Alloyed pleasures: multimetallic cocktails. Curr Sci. 2003;85(10):1404.
[16]
Zurück zum Zitat Lee CP, Chen YY, Hsu CY, Yeh JW, Shih HC. Enhancing pitting corrosion resistance of Al x CrFe1.5MnNi0.5 high-entropy alloys by anodic treatment in sulfuric acid. Thin Solid Films. 2008;517(3):1301.CrossRef Lee CP, Chen YY, Hsu CY, Yeh JW, Shih HC. Enhancing pitting corrosion resistance of Al x CrFe1.5MnNi0.5 high-entropy alloys by anodic treatment in sulfuric acid. Thin Solid Films. 2008;517(3):1301.CrossRef
[17]
Zurück zum Zitat Lee CP, Chang CC, Chen YY, Yeh JW, Shih HC. Effect of the aluminium content of Al x CrFe1.5MnNi0.5 high-entropy alloys on the corrosion behaviour in aqueous environments. Corros Sci. 2008;50(7):2053.CrossRef Lee CP, Chang CC, Chen YY, Yeh JW, Shih HC. Effect of the aluminium content of Al x CrFe1.5MnNi0.5 high-entropy alloys on the corrosion behaviour in aqueous environments. Corros Sci. 2008;50(7):2053.CrossRef
[18]
Zurück zum Zitat Tang WY, Chuang MH, Chen HY, Yeh JW. Microstructure and mechanical performance of new Al0.5CrFe1.5MnNi0.5 high-entropy alloys improved by plasma nitriding. Surf Coat Technol. 2010;204(20):3118.CrossRef Tang WY, Chuang MH, Chen HY, Yeh JW. Microstructure and mechanical performance of new Al0.5CrFe1.5MnNi0.5 high-entropy alloys improved by plasma nitriding. Surf Coat Technol. 2010;204(20):3118.CrossRef
[19]
Zurück zum Zitat Zhang Y, Yang X, Liaw KP. Alloy design and properties optimization of high-entropy alloys. JOM. 2012;64(7):830.CrossRef Zhang Y, Yang X, Liaw KP. Alloy design and properties optimization of high-entropy alloys. JOM. 2012;64(7):830.CrossRef
[20]
Zurück zum Zitat Kittel C. Introduction to Solid State Physics. 7th ed. New York: Wiley; 1996. 673. Kittel C. Introduction to Solid State Physics. 7th ed. New York: Wiley; 1996. 673.
[21]
Zurück zum Zitat Takeuchi A, Inoue A. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans. 2005;46(12):2817.CrossRef Takeuchi A, Inoue A. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans. 2005;46(12):2817.CrossRef
[22]
Zurück zum Zitat Ren B, Liu ZX, Li DM, Shi L, Cai B, Wang MX. Effect of elemental interaction on microstructure of CuCrFeNiMn high entropy alloy system. J Alloy Compd. 2010;493(1–2):148.CrossRef Ren B, Liu ZX, Li DM, Shi L, Cai B, Wang MX. Effect of elemental interaction on microstructure of CuCrFeNiMn high entropy alloy system. J Alloy Compd. 2010;493(1–2):148.CrossRef
[23]
Zurück zum Zitat Zhang Y, Zhou YJ, Lin JP, Chen GL, Liaw PK. Solid-solution phase formation rules for multi-component alloys. Adv Eng Mater. 2008;10(6):534.CrossRef Zhang Y, Zhou YJ, Lin JP, Chen GL, Liaw PK. Solid-solution phase formation rules for multi-component alloys. Adv Eng Mater. 2008;10(6):534.CrossRef
[24]
Zurück zum Zitat Zhang Y, Zhou YJ, Wang YL, Chen GL. Solid solution alloys of AlCoCrFeNiTi x with excellent room-temperature mechanical properties. Appl Phys Lett. 2007;90(18):181904.CrossRef Zhang Y, Zhou YJ, Wang YL, Chen GL. Solid solution alloys of AlCoCrFeNiTi x with excellent room-temperature mechanical properties. Appl Phys Lett. 2007;90(18):181904.CrossRef
[25]
Zurück zum Zitat Zhu JM, Fu HM, Zhang HF, Wang AM, Li H, Hu ZQ. Synthesis and properties of multiprincipal component AlCoCrFeNiSi x alloys. Mater Sci Eng A. 2010;527(27–28):7210.CrossRef Zhu JM, Fu HM, Zhang HF, Wang AM, Li H, Hu ZQ. Synthesis and properties of multiprincipal component AlCoCrFeNiSi x alloys. Mater Sci Eng A. 2010;527(27–28):7210.CrossRef
[26]
Zurück zum Zitat Chen MR, Lin SJ, Yeh JW, Chen SK, Huang YS, Chuang MH. Effect of vanadium addition on the microstructure, hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metall Mater Trans A. 2006;37(5):1363.CrossRef Chen MR, Lin SJ, Yeh JW, Chen SK, Huang YS, Chuang MH. Effect of vanadium addition on the microstructure, hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy. Metall Mater Trans A. 2006;37(5):1363.CrossRef
[27]
Zurück zum Zitat Hsu YJ, Chiang WC, Wu JK. Corrosion behavior of FeCoNiCrCu x high-entropy alloys in 3.5 % sodium chloride solution. Mater Chem Phys. 2005;92(1):112.CrossRef Hsu YJ, Chiang WC, Wu JK. Corrosion behavior of FeCoNiCrCu x high-entropy alloys in 3.5 % sodium chloride solution. Mater Chem Phys. 2005;92(1):112.CrossRef
[28]
Zurück zum Zitat Qiu XW. Microstructure and properties of AlCrFeNiCoCu high entropy alloy prepared by powder metallurgy. J Alloy Compd. 2013;555:246.CrossRef Qiu XW. Microstructure and properties of AlCrFeNiCoCu high entropy alloy prepared by powder metallurgy. J Alloy Compd. 2013;555:246.CrossRef
Metadaten
Titel
Microstructure and properties of Al0.3CrFe1.5MnNi0.5Ti x and Al0.3CrFe1.5MnNi0.5Si x high-entropy alloys
verfasst von
Bo Ren
Rui-Feng Zhao
Zhong-Xia Liu
Shao-Kang Guan
Hong-Song Zhang
Publikationsdatum
01.04.2014
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 2/2014
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-014-0224-4

Weitere Artikel der Ausgabe 2/2014

Rare Metals 2/2014 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.