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16.02.2023 | Ceramics

Microwave-assisted hydrothermal synthesis of Sn₃O₄ and SnO for electrocatalytic reduction of CO₂ to high-added-value compounds

verfasst von: Fernanda da Costa Romeiro, Alysson Stefan Martins, João Angelo Lima Perini, Beatriz Costa e Silva, Maria Valnice Boldrin Zanoni, Marcelo Ornaghi Orlandi

Erschienen in: Journal of Materials Science | Ausgabe 8/2023

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Abstract

Sn-based electrocatalysts have recently been applied for CO₂ reduction to generate fuels. Here, tin oxide crossed architectures (SnO) and petal-like Sn₃O₄ semiconductors were synthesized using the microwave-assisted hydrothermal method. The synthesized materials were applied in electrochemical reduction of CO₂ and promoted the formation of methanol, ethanol and acetone. The best condition (greatest amount of products) was obtained with − 0.5 V vs Ag/AgCl for both electrocatalysts. For the first time, acetone formation was observed using both SnO and Sn₃O₄ materials. The SnO electrocatalyst exhibited the best electrochemical activity for CO₂ reduction, ascribed to higher charge transfer corroborated by the higher current densities and lower resistance in the Nyquist diagram. Differences in methanol concentration obtained by the samples were ascribed to the different morphology and charge transfer over the films. The results showed that Sn-based electrocatalysts can be applied to generate important products, such as methanol and ethanol, aside from promoting acetone formation.

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Vorheriger Artikel A review of thermal properties of CVD diamond films

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Titel: Microwave-assisted hydrothermal synthesis of Sn3O4 and SnO for electrocatalytic reduction of CO2 to high-added-value compounds
verfasst von: Fernanda da Costa Romeiro
Alysson Stefan Martins
João Angelo Lima Perini
Beatriz Costa e Silva
Maria Valnice Boldrin Zanoni
Marcelo Ornaghi Orlandi
Publikationsdatum: 16.02.2023
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 8/2023
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-023-08230-y

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