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Erschienen in: Journal of Materials Science: Materials in Electronics 4/2019

18.01.2019

Microwave dielectric properties and microstructures of xBa0.33Sr0.67TiO3–(1−x)Ba4Sm9.33Ti18O54 ceramics with near-zero temperature coefficient

verfasst von: Wentao Xie, Xiaoying Zhang, Huachao Hang, Qinxian Jiang, Qinglin Cao, Jinyu Zhou

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 4/2019

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Abstract

The phase composition, microstructures, sintering behavior, and microwave dielectric properties of Ba0.33Sr0.67TiO3–Ba4Sm9.33Ti18O54 ceramics prepared via conventional solid-state route were systematically investigated as a function of the Ba0.33Sr0.67TiO3 molar fraction and sintering temperature. All the sintered ceramics only exhibited a single orthorhombic tungsten bronze structure BaSm2Ti4O12 phase. And all samples sintered at 1400 °C showed fully dense and homogeneous microstructures. The variation of bulk density and dielectric properties are related with the Ba(Zn1/3Nb2/3)O3 molar fraction, but not with a same trend. As Ba ions in A1 sites are substituted by Sr ions, Q × f values enhanced dramatically. The optimum microwave dielectric properties with an εr value of 80.13, a Q × f value of 11386 GHz (at 3.5 GHz), and a τf value of − 0.34 ppm/°C were obtained for 0.03Ba0.33Sr0.67TiO3–0.97Ba4Sm9.33Ti18O54 ceramics sintered at 1400 °C for 4 h.

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Metadaten
Titel
Microwave dielectric properties and microstructures of xBa0.33Sr0.67TiO3–(1−x)Ba4Sm9.33Ti18O54 ceramics with near-zero temperature coefficient
verfasst von
Wentao Xie
Xiaoying Zhang
Huachao Hang
Qinxian Jiang
Qinglin Cao
Jinyu Zhou
Publikationsdatum
18.01.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 4/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-00693-7

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