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Journal of Polymer Research

Erschienen in:

01.03.2017 | ORIGINAL PAPER

Nanosized dispersions based on chitosan and NaPSS

verfasst von: C. R. M. de Lima, M. R. Pereira, J. L. C. Fonseca

Erschienen in: Journal of Polymer Research | Ausgabe 3/2017

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Abstract

Interpolyelectrolyte complexes (IPECs) were obtained by the solution mixing method from chitosan and poly(sodium 4-styrenesulfonate), NaPSS. XRD, FTIR spectroscopy, and thermogravimetric analysis indicated that IPEC formation inhibits the occurrence of crystalline regions in the resultant solid IPECs. Turbidimetry, viscometry, conductometry, and zeta potential measurements showed that at a sulfonate to aminium molar ratio = 1, the process of IPEC production is optimum. Average hydrodynamic diameters, calculated from DLS measurements, showed that IPEC formation occurs in two stages: first there is a decrease in macromolecular dimensions, as sulfonate to aminium molar ratio is increased. At a characteristic sulfonate to aminium molar ratio, soluble IPEC structures collapse to form phase segregated clusters that begin to nucleate the formation of larger, insoluble, IPEC particles.

Vorheriger Artikel Nitrocellulose-based hybrid materials with T7-POSS as a modifier: effective reinforcement for thermal stability, combustion safety, and mechanical properties

Nächster Artikel Morphological, structural, dielectric and electrical properties of PEO–ZnO nanodielectric films

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Titel: Nanosized dispersions based on chitosan and NaPSS
verfasst von: C. R. M. de Lima
M. R. Pereira
J. L. C. Fonseca
Publikationsdatum: 01.03.2017
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 3/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-017-1214-7

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