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Journal of Materials Science
Erschienen in: Journal of Materials Science 24/2017

11.09.2017 | Electronic materials

NaScMo2O8:RE3+ (RE = Tb, Eu, Tb/Eu, Yb/Er, Yb/Ho) phosphors: hydrothermal synthesis, energy transfer and multicolor tunable luminescence

verfasst von: Dingyi Shen, Bei Zhao, Shunrong Yang, Shanshan Hu, Jianfeng Tang, Xianju Zhou, Jun Yang

Erschienen in: Journal of Materials Science | Ausgabe 24/2017

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Abstract

NaScMo2O8:RE3+ (RE = Tb, Eu, Tb/Eu, Yb/Er, Yb/Ho) phosphors were successfully synthesized by surfactant-free hydrothermal method and post-calcination treatment. The energy transfer (ET) of MoO4 2− → Tb3+ → Eu3+ was proved by photoluminescence spectra and decay features. Multicolor emissions (green → yellow → red) were obtained by adjusting the ratio of Tb3+/Eu3+ upon excitation into the MoO4 2− at 292 nm. The ET of Tb3+ → Eu3+ was demonstrated to be a resonant type via a dipole–dipole mechanism, and the crystal distance (R c) was calculated by the quenching concentration method. Under 980 nm excitation, the emission of NaScMo2O8:RE3+ (RE = Yb/Er, Yb/Ho) showed strong green (Yb3+/Er3+: 4S3/2, 2H11/2 → 4I15/2; Yb3+/Ho3+: 5S2 → 5I8) luminescence, respectively. Moreover, the doping concentration of the Yb3+ has been optimized under a fixed concentration of Er3+ and Ho3+, respectively. The NaScMo2O8:RE3+ phosphors have potential applications for color displays and light-emitting devices due to a variety of luminous colors.
Vorheriger Artikel Three-dimensional phase-field simulation of microstructural evolution in three-phase materials with different interfacial energies and different diffusivities
Nächster Artikel Epitaxial growth and magnetic properties of h-LuFeO3 thin films

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Metadaten
Titel
NaScMo2O8:RE3+ (RE = Tb, Eu, Tb/Eu, Yb/Er, Yb/Ho) phosphors: hydrothermal synthesis, energy transfer and multicolor tunable luminescence
verfasst von
Dingyi Shen
Bei Zhao
Shunrong Yang
Shanshan Hu
Jianfeng Tang
Xianju Zhou
Jun Yang
Publikationsdatum
11.09.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 24/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1396-8

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