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07.10.2023

Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements

verfasst von: Bojana M. Radojković, Bore V. Jegdić, Dunja D. Marunkić, Jovanka N. Pejić, Anđela R. Simović, Vladan R. Ćosović, Jelena B. Bajat

Erschienen in: Metals and Materials International | Ausgabe 3/2024

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Abstract

This paper examined the degree of sensitization (DOS) to intergranular corrosion (IGC) and the level of electrical conductivity of the welded and non-welded AISI 304 stainless steel to obtain a suitable correlation. The DOS was determined by the double loop electrochemical potentiokinetic reactivation method (DL EPR), while the level of electrical conductivity was measured using a commercial device (non-destructive method). After electrochemical etching in oxalic acid, the microstructure of the specimen surface was analyzed by scanning electron microscopy (SEM). At DOS greater than ~ 0.5%, a clear linear dependence between the electrical conductivity and the value of the DOS was obtained, while there was a higher deviation from linearity for lower DOS values. The mentioned correlations were discussed in the sense of the precipitation kinetics of the Cr-carbide and the formation of Cr-depleted areas of different levels near the grain boundaries. Cr-depleted areas during anodic polarization measurements show lower resistance to pit formation. The presence of Cr-depleted areas in the vicinity of grain boundaries and the reduction of carbon content in the austenite crystal lattice increases the electrical conductivity of the stainless steel.

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Titel: Non-Destructive Evaluation of the AISI 304 Stainless Steel Susceptibility to Intergranular Corrosion by Electrical Conductivity Measurements
verfasst von: Bojana M. Radojković
Bore V. Jegdić
Dunja D. Marunkić
Jovanka N. Pejić
Anđela R. Simović
Vladan R. Ćosović
Jelena B. Bajat
Publikationsdatum: 07.10.2023
Verlag: The Korean Institute of Metals and Materials
Erschienen in: Metals and Materials International / Ausgabe 3/2024
Print ISSN: 1598-9623
Elektronische ISSN: 2005-4149
DOI: https://doi.org/10.1007/s12540-023-01536-1

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