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Environmental Earth Sciences

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01.05.2015 | Thematic Issue

Occurrence and distribution of phthalic acid esters and phenols in Hun River Watersheds

verfasst von: Bin Li, Xinqi Hu, Ruixia Liu, Ping Zeng, Yonghui Song

Erschienen in: Environmental Earth Sciences | Ausgabe 9/2015

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Abstract

The Xi River (XR) and Pu River (PR) are the tributaries of Hun River Watersheds (HRW), located in Liao River Basin (LRB), northeast China. These riverine waters are historically polluted by effluents from printing and dyeing enterprises, and pharmaceutical and chemical industries. The concentrations of phthalic acid esters (PAEs), e.g., dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), diisobutyl phthalate (DIBP), di-n-octyl phthalate (DNOP) and bis(2-ethylhexyl) phthalate (DEHP), as well as phenols including phenol, 4-methylphenol, 2,3-dimethylphenol, 2,4-dimethylphenol, 3,5-dimethylphenol, 2,4,6-trimethylphenol, 2,4-di-tert-butylphenol and 2,6-di-tert-butyl-4-ethylphenol in surface water of the XR and PR were determined by gas chromatograph (GC) coupled with a mass spectrometer (MS), respectively, during spring (dry), summer (wet) and autumn (normal) seasons. DMP, DIBP, DBP, phenol, 4-methylphenol and 3,5-dimethylphenol were identified as the dominant pollutants in the XR, and DBP, DIBP, DEHP and phenol were the main pollutants in the PR. Seasonal variations of the geometric mean concentrations in the XR ranged from 6.88 to 19.5 μg/L for ∑₆PAEs and 24.5–1195 μg/L for ∑₈phenols with the highest level in summer. The temporal distribution of ∑₆PAEs or ∑₈phenols in the PR was similar to that in the XR, i.e. the highest levels were observed in summer (24.1 μg/L for ∑₆PAEs and 26.8 μg/L for ∑₈phenols).The concentrations of pollutants were highly variable across sampling sites. The geographic concentrations of ∑₆PAEs were in the range of 9.92–17.9 μg/L in the XR and 7.42–37.6 μg/L in the PR. As for ∑₈phenols, the greater spatial variations were observed, ranging from 14.0–2008 μg/L in the XR and from 4.00 to 80.5 μg/L in the PR. Cluster analysis (CA) showed that the 19 sampling stations were divided into three clusters: cluster A was made up of the majority of sampling sites in the PR, slightly polluted by PAEs and phenols; cluster B consisted of the sites from both the XR and PR; cluster C included the sampling sites in the XR, where was heavily polluted by PAEs and phenols.

Vorheriger Artikel Spatial distribution and diversity of microbial community in large-scale constructed wetland of the Liao River Conservation Area

Nächster Artikel Seasonal variation of enrichment, accumulation and sources of heavy metals in suspended particulate matter and surface sediments in the Daliao river and Daliao river estuary, Northeast China

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Titel: Occurrence and distribution of phthalic acid esters and phenols in Hun River Watersheds
verfasst von: Bin Li
Xinqi Hu
Ruixia Liu
Ping Zeng
Yonghui Song
Publikationsdatum: 01.05.2015
Verlag: Springer Berlin Heidelberg
Erschienen in: Environmental Earth Sciences / Ausgabe 9/2015
Print ISSN: 1866-6280
Elektronische ISSN: 1866-6299
DOI: https://doi.org/10.1007/s12665-015-4299-5

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