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Biomass Conversion and Biorefinery

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25.03.2020 | Original Article

One-pot hydrothermal conversion of poppy stalks over metal chloride catalysts

verfasst von: Emir Zafer Hoşgün

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 6/2021

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Abstract

Production of 5-hydroxymethylfurfural (5-HMF) and furfural (FF) from poppy stalks catalyzed by several metal chlorides (FeCl₃, AlCl₃, ZnCl₂, CuCl₂, CrCl₃, CaCl₂) was studied in water medium under one-pot hydrothermal reaction conditions at 180 °C, with a 1/20 solid to liquid ratio, for 120 min. Poppy stalks were subjected to direct hydrothermal conversion without any pretreatment. The highest 5-HMF and FF yields were achieved with CuCl₂, CrCl₃, and AlCl₃ among the studied catalysts. The effect of catalyst dosage, reaction temperature, and reaction time were investigated to obtain optimal process conditions for HMF and FF production. Among the three catalysts, CuCl₂ had the extreme performance. Maximum 5-HMF and FF yields were obtained as 12.24% and 79.86%, respectively, under hydrothermal conditions with 0.03 M CuCl₂ at 200 °C for 30 min. Poppy stalks could be used as a raw material to produce sustainable chemicals to reduce CO₂ emission and energy consumption in biorefinery concept.

Vorheriger Artikel Catalytic pyrolysis of cellulose over solid acidic catalysts: an environment-friendly method for furan production

Nächster Artikel Optimising enzymatic conditions of monkfish (Lophius vomerinus) heads hydrolysis towards potential waste biomass valorisation

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Titel: One-pot hydrothermal conversion of poppy stalks over metal chloride catalysts
verfasst von: Emir Zafer Hoşgün
Publikationsdatum: 25.03.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 6/2021
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-020-00682-5

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