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Cellulose

Erschienen in:

01.02.2008

Optimization of cellouronic acid synthesis by TEMPO-mediated oxidation of cellulose III from sugar beet pulp

verfasst von: Youssef Habibi, Michel R. Vignon

Erschienen in: Cellulose | Ausgabe 1/2008

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Abstract

Microfibrillated cellulose from purified sugar beet pulp was converted into cellulose III by immersion in liquid ammonia. When freed from ammonia, this product was oxidized in water at pH-10 using NaBr, NaOCl and 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) under various conditions and concentrations. The resulting water-soluble cellouronic acid—i.e. cellulose oxidized at the C6 position- was analyzed by high performance size exclusion chromatography (HPSEC) together with ¹³C NMR spectroscopy. The oxidation parameters, namely reaction time, temperature, NaBr and TEMPO concentrations were varied to determine the optimum reaction conditions. A low TEMPO concentration, a rather fast reaction time and the conducting of the oxidation at 0 °C were critical to obtain pure cellouronic acid in high yield, high purity and high DP.

Vorheriger Artikel Upgrading of paper-grade pulps to dissolving pulps by nitren extraction: properties of nitren extracted xylans in comparison to NaOH and KOH extracted xylans

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Titel: Optimization of cellouronic acid synthesis by TEMPO-mediated oxidation of cellulose III from sugar beet pulp
verfasst von: Youssef Habibi
Michel R. Vignon
Publikationsdatum: 01.02.2008
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2008
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-007-9179-z

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