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Cellulose

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17.11.2018 | Original Paper

Optimum synthesis of an amino functionalized microcrystalline cellulose from corn stalk for removal of aqueous Cu²⁺

verfasst von: Yumeng Wu, Yihua Jiang, Yuejun Li, Rong Wang

Erschienen in: Cellulose | Ausgabe 2/2019

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Abstract

An amino functionalized microcrystalline cellulose from corn stalk was prepared and its synthesis and operation conditions were optimized to remove Cu²⁺ from wastewater. To prepare this adsorbent, cellulose was grafted by glycidyl methacrylate in the presence of OP-10 as emulsifiers and potassium persulfate as initiators, then the grafted cellulose was aminated by diethylenetriamine. Batch experiments were performed to evaluate its adsorption capacity for Cu²⁺. Its adsorption process for Cu²⁺ was spontaneous and well fitted with pseudo-second-order kinetics and Langmuir isotherm. The maximum adsorption capacity of this modified cellulose for Cu²⁺ was demonstrated to be 343 mg/g at 45 °C and pH 4.5. The adsorbent showed a promising future due to its high performance in the removal of toxic Cu²⁺ and reusability. From the characterization results of scanning electron microscope, X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, the adsorbent structure and adsorption mechanism could be inferred. The adsorption mechanism revealed that the primary and secondary amines were the main functional groups to adsorb Cu²⁺. The study results could provide a new route for the utilization of waste corn stalk to control water pollution caused by toxic metal ions.

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Vorheriger Artikel Extraction and characterization of fibers from Yucca Elephantine plant

Nächster Artikel Comparative moisture and heat sorption properties of fibre and shiv derived from hemp and flax

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Titel: Optimum synthesis of an amino functionalized microcrystalline cellulose from corn stalk for removal of aqueous Cu2+
verfasst von: Yumeng Wu
Yihua Jiang
Yuejun Li
Rong Wang
Publikationsdatum: 17.11.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-2113-8

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