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Cellulose

Erschienen in:

01.06.2010

Oxygen and oil barrier properties of microfibrillated cellulose films and coatings

verfasst von: Christian Aulin, Mikael Gällstedt, Tom Lindström

Erschienen in: Cellulose | Ausgabe 3/2010

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Abstract

The preparation of carboxymethylated microfibrillated cellulose (MFC) films by dispersion-casting from aqueous dispersions and by surface coating on base papers is described. The oxygen permeability of MFC films were studied at different relative humidity (RH). At low RH (0%), the MFC films showed very low oxygen permeability as compared with films prepared from plasticized starch, whey protein and arabinoxylan and values in the same range as that of conventional synthetic films, e.g., ethylene vinyl alcohol. At higher RH’s, the oxygen permeability increased exponentially, presumably due to the plasticizing and swelling of the carboxymethylated nanofibers by water molecules. The effect of moisture on the barrier and mechanical properties of the films was further studied using water vapor sorption isotherms and by humidity scans in dynamic mechanical analysis. The influences of the degree of nanofibrillation/dispersion on the microstructure and optical properties of the films were evaluated by field-emission scanning electron microscopy (FE-SEM) and light transmittance measurements, respectively. FE-SEM micrographs showed that the MFC films consisted of randomly assembled nanofibers with a thickness of 5–10 nm, although some larger aggregates were also formed. The use of MFC as surface coating on various base papers considerably reduced the air permeability. Environmental scanning electron microscopy (E-SEM) micrographs indicated that the MFC layer reduced sheet porosity, i.e., the dense structure formed by the nanofibers resulted in superior oil barrier properties.

Vorheriger Artikel Design, synthesis, and characterization of a combined main-chain/side-chain liquid-crystalline polymer based on ethyl cellulose

Nächster Artikel Efficient approach to high barrier packaging using microfibrillar cellulose and shellac

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Titel: Oxygen and oil barrier properties of microfibrillated cellulose films and coatings
verfasst von: Christian Aulin
Mikael Gällstedt
Tom Lindström
Publikationsdatum: 01.06.2010
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2010
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-009-9393-y

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