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Journal of Materials Science
Erschienen in: Journal of Materials Science 3/2018

25.09.2017 | Ceramics

Oxygen ion mobility and conductivity prediction in cubic yttria-stabilized zirconia single crystals

verfasst von: Mohammad Asadikiya, Yu Zhong

Erschienen in: Journal of Materials Science | Ausgabe 3/2018

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Abstract

The CALPHAD (calculation of phase diagrams) approach is applied to predict the oxygen vacancy concentration at different temperatures and yttria concentrations of cubic yttria-stabilized zirconia (c-YSZ) single crystals. The quantitative mobility diagrams of oxygen ions are developed in a wide range of temperature and yttria concentration, using the experimental data from the literature. Therefore, the ionic conductivity of c-YSZ single crystals is predicted, using the mobility and oxygen vacancy concentration. Particularly, the conductivity of low-yttria c-YSZ is predicted by applying the CALPHAD approach for the first time. The conductivity prediction of low-yttria c-YSZ can be crucial, since new applications may be designed based on this new information. The activation energy and pre-exponential factor diagrams versus yttria concentration are also plotted.
Vorheriger Artikel Modeling the final sintering stage of doped ceramics: mutual interaction between grain growth and densification
Nächster Artikel Kinetics of dissolution of glass fibre in hot alkaline solution

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Metadaten
Titel
Oxygen ion mobility and conductivity prediction in cubic yttria-stabilized zirconia single crystals
verfasst von
Mohammad Asadikiya
Yu Zhong
Publikationsdatum
25.09.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 3/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1625-1

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