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2016 | OriginalPaper | Buchkapitel

Oxygen Permeability of Layer Silicate Reinforced Polymer Nanocomposites

verfasst von : Sarat K. Swain, Niladri Sarkar, Gyanaranjan Sahoo, Deepak Sahu

Erschienen in: Nanoclay Reinforced Polymer Composites

Verlag: Springer Singapore

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Abstract

Reinforcement of organically modified nanoclay into different synthetic and biopolymer matrices was performed by several techniques. For high density polyethylene (HDPE) and polyamide (PA6) based nanocomposites, single screw compounding process was adopted, whereas; for polymethylmethacrylate (PMMA), polyacrylonitrile (PAN) based nanocomposites in situ polymerization technique was taken into consideration. For protein and biopolymer based nanocomposites; nano clays were made to disperse through solution casting technique. The structural analysis of all the polymer/clay nanocomposites or bionanocomposites was performed through X-ray diffraction (XRD) and Fourier transform infrared (FTIR) studies, whereas; the morphological analysis was carried out through transmission electron microscope (TEM). The oxygen permeability of nano clay reinforced polymer nanocomposites was measured as function of clay content and pressure. It was found to be decreased with increase in clay content as compared to their neat polymers. Along with the clay content, ultrasonic treatment also affect the nature of dispersion of nanoclay and thereby the oxygen permeability of the fabricated nanocomposites. The enhanced obstacle towards the path of gas transportation within the fabricated polymer nanocomposite may enable the material for food packaging applications.

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Literatur
Zurück zum Zitat Abreu, D., Losada, P., Angulo, I., Cruz, J.M.: Development of new polyolefin films with nanoclays for application in food packaging. Eur. Polym. J. 43, 2229–2243 (2007)CrossRef Abreu, D., Losada, P., Angulo, I., Cruz, J.M.: Development of new polyolefin films with nanoclays for application in food packaging. Eur. Polym. J. 43, 2229–2243 (2007)CrossRef
Zurück zum Zitat Ball, A., Jones, R.A.L.: Conformational changes in adsorbed proteins. Langmuir 11, 3542–3548 (1995)CrossRef Ball, A., Jones, R.A.L.: Conformational changes in adsorbed proteins. Langmuir 11, 3542–3548 (1995)CrossRef
Zurück zum Zitat Barbee, R., Matayabas, C.: Nanocomposites for high barrier applications (2002). United States Patent WO2000078855A1, 26 Nov 2002 Barbee, R., Matayabas, C.: Nanocomposites for high barrier applications (2002). United States Patent WO2000078855A1, 26 Nov 2002
Zurück zum Zitat Boricha, A.B., Mody, H.M., Das, A., Bajaj, H.C.: Facile dehydroxylation of styrene using clay based catalyst. Appl. Catal. A Gen. 179, 5–10 (1999)CrossRef Boricha, A.B., Mody, H.M., Das, A., Bajaj, H.C.: Facile dehydroxylation of styrene using clay based catalyst. Appl. Catal. A Gen. 179, 5–10 (1999)CrossRef
Zurück zum Zitat Dash, S., Kisku, S.K., Swain, S.K.: Effect of nanoclay on morphological, thermal, and barrier properties of albumin bovine. Polym. Compos. 33, 2201–2206 (2012)CrossRef Dash, S., Kisku, S.K., Swain, S.K.: Effect of nanoclay on morphological, thermal, and barrier properties of albumin bovine. Polym. Compos. 33, 2201–2206 (2012)CrossRef
Zurück zum Zitat Dash, S., Swain, S.K.: Effect of nano-boron nitride on the physical and chemical properties of soy protein. Compos. Sci. Technol. 84, 39–43 (2013a)CrossRef Dash, S., Swain, S.K.: Effect of nano-boron nitride on the physical and chemical properties of soy protein. Compos. Sci. Technol. 84, 39–43 (2013a)CrossRef
Zurück zum Zitat Dash, S., Swain, S.K.: Synthesis of thermal and chemical resistant oxygen barrier starch with reinforcement of nano silicon carbide. Carbohydr. Polym. 97, 758–763 (2013b)CrossRef Dash, S., Swain, S.K.: Synthesis of thermal and chemical resistant oxygen barrier starch with reinforcement of nano silicon carbide. Carbohydr. Polym. 97, 758–763 (2013b)CrossRef
Zurück zum Zitat Dons, A., Steven, J., Prestrelski, S.J., Allison, S., Carpenter, J.F.: Infrared spectroscopic studies of lyophilization and temperature-induced protein aggregation. J. Pharm. Sci. 84, 415–424 (1995)CrossRef Dons, A., Steven, J., Prestrelski, S.J., Allison, S., Carpenter, J.F.: Infrared spectroscopic studies of lyophilization and temperature-induced protein aggregation. J. Pharm. Sci. 84, 415–424 (1995)CrossRef
Zurück zum Zitat Frounchi, M., Dadbin, S., Salehpour, Z., Noferesti, M.: Gas barrier properties of PP/EPDM blend nanocomposites. J. Membr. Sci. 282, 142–148 (2006)CrossRef Frounchi, M., Dadbin, S., Salehpour, Z., Noferesti, M.: Gas barrier properties of PP/EPDM blend nanocomposites. J. Membr. Sci. 282, 142–148 (2006)CrossRef
Zurück zum Zitat Fukushima, Y., Inagoki, S.: Synthesis of an intercalating compound of monontmorilonite and 6-polyamide. J Inclusion Phenom 5, 473–482 (1987)CrossRef Fukushima, Y., Inagoki, S.: Synthesis of an intercalating compound of monontmorilonite and 6-polyamide. J Inclusion Phenom 5, 473–482 (1987)CrossRef
Zurück zum Zitat Gilman, J.W.: Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites. Appl. Clay Sci. 15, 31–49 (1999)CrossRef Gilman, J.W.: Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites. Appl. Clay Sci. 15, 31–49 (1999)CrossRef
Zurück zum Zitat Halligudi, S.B., Bajaj, H.C., Bhatt, K.N., Krishnaratnam, M.: Hydrogenation of benzene to cyclohexane catalyzed by rhodium (I) complex supported an Montmorillonite clay. React. Kinet. Catal. Lett. 48, 547–552 (1992)CrossRef Halligudi, S.B., Bajaj, H.C., Bhatt, K.N., Krishnaratnam, M.: Hydrogenation of benzene to cyclohexane catalyzed by rhodium (I) complex supported an Montmorillonite clay. React. Kinet. Catal. Lett. 48, 547–552 (1992)CrossRef
Zurück zum Zitat Jang, B.Z.: Nanocomposite compositions for hydrogen storage and methods for supplying hydrogen to fuel cells (2006). US2006030483, 09 Feb 2006 Jang, B.Z.: Nanocomposite compositions for hydrogen storage and methods for supplying hydrogen to fuel cells (2006). US2006030483, 09 Feb 2006
Zurück zum Zitat Khan, B.T., Najmuddin, K., Shamsuddin, S., Annapooma, K., Bhatt, J.: synthesis, antimicrobial antitumor activity of a series of palladium (II) mixed ligand complexes. J. Inorg. Biochem. 44, 55–63 (1991)CrossRef Khan, B.T., Najmuddin, K., Shamsuddin, S., Annapooma, K., Bhatt, J.: synthesis, antimicrobial antitumor activity of a series of palladium (II) mixed ligand complexes. J. Inorg. Biochem. 44, 55–63 (1991)CrossRef
Zurück zum Zitat Kim, M.H., Lee, S.H.: Nanocomposite blend composition having excellent barrier property (2006). JP2006328426, 07 Dec 2006 Kim, M.H., Lee, S.H.: Nanocomposite blend composition having excellent barrier property (2006). JP2006328426, 07 Dec 2006
Zurück zum Zitat Kisku, S.K., Sarkar, N., Dash, S., Swain, S.K.: Preparation of starch/PVA/CaCO3 nanobiocomposite films: study of fire retardant, thermal resistant, gas barrier and biodegradable properties. Polym. Plast. Technol. Eng. 53, 1664–1670 (2014)CrossRef Kisku, S.K., Sarkar, N., Dash, S., Swain, S.K.: Preparation of starch/PVA/CaCO3 nanobiocomposite films: study of fire retardant, thermal resistant, gas barrier and biodegradable properties. Polym. Plast. Technol. Eng. 53, 1664–1670 (2014)CrossRef
Zurück zum Zitat Kisku, S.K., Swain, S.K.: Synthesis and characterization of chitosan/boron nitride composites. J. Am. Ceram. Soc. 95, 2753–2757 (2012)CrossRef Kisku, S.K., Swain, S.K.: Synthesis and characterization of chitosan/boron nitride composites. J. Am. Ceram. Soc. 95, 2753–2757 (2012)CrossRef
Zurück zum Zitat Lapshin, S., Swain, S.K., Isayev, A.I.: Ultrasound aided extrusion process for preparation of polyolefin-clay nanocomposites. Polym. Eng. Sci. 48, 1584–1591 (2008)CrossRef Lapshin, S., Swain, S.K., Isayev, A.I.: Ultrasound aided extrusion process for preparation of polyolefin-clay nanocomposites. Polym. Eng. Sci. 48, 1584–1591 (2008)CrossRef
Zurück zum Zitat Lv, J., Liu, W.: Flame retardancy and mechanical properties of EVA nanocomposites based on magnesium hydroxide nanoparticles/microcapsulated red phosphorus. J. Appl. Polym. Sci. 105, 333–340 (2007)CrossRef Lv, J., Liu, W.: Flame retardancy and mechanical properties of EVA nanocomposites based on magnesium hydroxide nanoparticles/microcapsulated red phosphorus. J. Appl. Polym. Sci. 105, 333–340 (2007)CrossRef
Zurück zum Zitat Oh, J.S., Isayev, A.I., Rogunova, M.A.: Continuous ultrasonic process for in situ compatibilization of polypropylene/natural rubber blends. Polymer 44, 2337–2349 (2003)CrossRef Oh, J.S., Isayev, A.I., Rogunova, M.A.: Continuous ultrasonic process for in situ compatibilization of polypropylene/natural rubber blends. Polymer 44, 2337–2349 (2003)CrossRef
Zurück zum Zitat Osman, M., Atallah, A.: High-density polyethylene micro- and nanocomposites: effect of particle shape, size and surface treatment on polymer crystallinity and gas permeability. Macromol. Rapid Commun. 25, 1540–1544 (2004)CrossRef Osman, M., Atallah, A.: High-density polyethylene micro- and nanocomposites: effect of particle shape, size and surface treatment on polymer crystallinity and gas permeability. Macromol. Rapid Commun. 25, 1540–1544 (2004)CrossRef
Zurück zum Zitat Park, K., Chowdhury, S.R., Park, C., Kim, G.: Effect of dispersion state of organoclay on cellular foam structure and mechanical properties of ethylene vinyl acetate copolymer/ethylene-1-butenecopolymer/organoclay nanocomposite foams. J. Appl. Polym. Sci. 104, 3879–3885 (2007) Park, K., Chowdhury, S.R., Park, C., Kim, G.: Effect of dispersion state of organoclay on cellular foam structure and mechanical properties of ethylene vinyl acetate copolymer/ethylene-1-butenecopolymer/organoclay nanocomposite foams. J. Appl. Polym. Sci. 104, 3879–3885 (2007)
Zurück zum Zitat Patra, S.K., Swain, S.K.: Effect of organoclays on the thermal, mechanical, and oxygen barrier properties of poly (methylmethacrylateco-acrylonitrile)/clay nanocomposites. Polym. Compos. 33, 796–802 (2012)CrossRef Patra, S.K., Swain, S.K.: Effect of organoclays on the thermal, mechanical, and oxygen barrier properties of poly (methylmethacrylateco-acrylonitrile)/clay nanocomposites. Polym. Compos. 33, 796–802 (2012)CrossRef
Zurück zum Zitat Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted sythesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci. 35, 27–32 (2012)CrossRef Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted sythesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci. 35, 27–32 (2012)CrossRef
Zurück zum Zitat Patra, S.K., Prusty, G., Swain, S.K.: Synthesis of PAN/clay nanocomposites: study of gas permeation properties. Int. J. Nanosci. 10, 1101–1105 (2011)CrossRef Patra, S.K., Prusty, G., Swain, S.K.: Synthesis of PAN/clay nanocomposites: study of gas permeation properties. Int. J. Nanosci. 10, 1101–1105 (2011)CrossRef
Zurück zum Zitat Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted synthesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci 35, 27–32 (2012) Patra, S.K., Prusty, G., Swain, S.K.: Ultrasound assisted synthesis of PMMA/clay nanocomposites: study of oxygen permeation and flame retardant properties. Bull. Mater. Sci 35, 27–32 (2012)
Zurück zum Zitat Pradhan, A.K., Swain, S.K.: Electrical conductivity and oxygen permeability of polyacrylonitrile/multiwalled carbon nanotubes composites. Polym. Compos. 33, 1114–1119 (2012)CrossRef Pradhan, A.K., Swain, S.K.: Electrical conductivity and oxygen permeability of polyacrylonitrile/multiwalled carbon nanotubes composites. Polym. Compos. 33, 1114–1119 (2012)CrossRef
Zurück zum Zitat Prasad, K., Grubb, D.T.: Direct observation of taut tie molecules in high-strength polyethylene fibers by Raman spectroscopy. J. Polym. Sci. Part B Polym. Phys. 27, 381–403 (1989)CrossRef Prasad, K., Grubb, D.T.: Direct observation of taut tie molecules in high-strength polyethylene fibers by Raman spectroscopy. J. Polym. Sci. Part B Polym. Phys. 27, 381–403 (1989)CrossRef
Zurück zum Zitat Rana, P.K., Swain, S.K., Sahoo, P.K.: Synthesis, characterization, and properties of intercalated poly (2-ethyl hexylacrylate)/silicate nanocomposites: XRD, TEM, IR, TGA, superabsorbency, pressure-sensitive adhesion, and biodegradation. J. Appl. Polym. Sci. 93, 1007–1011 (2004) Rana, P.K., Swain, S.K., Sahoo, P.K.: Synthesis, characterization, and properties of intercalated poly (2-ethyl hexylacrylate)/silicate nanocomposites: XRD, TEM, IR, TGA, superabsorbency, pressure-sensitive adhesion, and biodegradation. J. Appl. Polym. Sci. 93, 1007–1011 (2004)
Zurück zum Zitat Sahoo, P.K., Dey, M., Swain, S.K.: Emulsifier-free emulsion polymerization of acrylonitrile: effect of in situ developed Cu (II)/glycine chelate complex initiated by monopersulfate. J. Appl. Polym. Sci. 74, 2785–2790 (1999) Sahoo, P.K., Dey, M., Swain, S.K.: Emulsifier-free emulsion polymerization of acrylonitrile: effect of in situ developed Cu (II)/glycine chelate complex initiated by monopersulfate. J. Appl. Polym. Sci. 74, 2785–2790 (1999)
Zurück zum Zitat Sahoo, P.K., Samal, R., Swain, S.K., Rana, P.K.: Synthesis of poly (butyl acrylate)/sodium silicate nanocomposite fire retardant. Eur. Polym. J. 44, 3522–3528 (2008)CrossRef Sahoo, P.K., Samal, R., Swain, S.K., Rana, P.K.: Synthesis of poly (butyl acrylate)/sodium silicate nanocomposite fire retardant. Eur. Polym. J. 44, 3522–3528 (2008)CrossRef
Zurück zum Zitat Sikdar, D., Katti, D., Kalpana, K., Mohanty, B.: Effect of organic modifiers on dynamic and static nano-mechanical properties and crystallinity of intercalated clay-polycaprolactam nanocomposites. J. Appl. Polym. Sci. 105, 790–802 (2007) Sikdar, D., Katti, D., Kalpana, K., Mohanty, B.: Effect of organic modifiers on dynamic and static nano-mechanical properties and crystallinity of intercalated clay-polycaprolactam nanocomposites. J. Appl. Polym. Sci. 105, 790–802 (2007)
Zurück zum Zitat Swain, S.K.: Ultrasound assisted process of PA6/clay nanocomposites: mechanical, rheological and barrier properties. J. Polym. Eng. 31, 185–189 (2011)CrossRef Swain, S.K.: Ultrasound assisted process of PA6/clay nanocomposites: mechanical, rheological and barrier properties. J. Polym. Eng. 31, 185–189 (2011)CrossRef
Zurück zum Zitat Swain, S.K., Isayev, J.S.: Effect of ultrasound on HDPE/clay nanocomposites: rheology, structure and properties. Polymer 48, 281–289 (2007)CrossRef Swain, S.K., Isayev, J.S.: Effect of ultrasound on HDPE/clay nanocomposites: rheology, structure and properties. Polymer 48, 281–289 (2007)CrossRef
Zurück zum Zitat Swain, S.K., Kisku, S.K., Sahoo, G.: Preparation of thermal resistant gas barrier chitosan nanobiocomposites. Polym. Compos. 35, 2324–2328 (2014)CrossRef Swain, S.K., Kisku, S.K., Sahoo, G.: Preparation of thermal resistant gas barrier chitosan nanobiocomposites. Polym. Compos. 35, 2324–2328 (2014)CrossRef
Zurück zum Zitat Swain, S.K., Priyadarshini, P.P., Patra, S.K.: Soy protein/clay bionanocomposites as ideal packaging materials. Polym. Plast. Technol. Eng. 51, 1282–1287 (2012)CrossRef Swain, S.K., Priyadarshini, P.P., Patra, S.K.: Soy protein/clay bionanocomposites as ideal packaging materials. Polym. Plast. Technol. Eng. 51, 1282–1287 (2012)CrossRef
Zurück zum Zitat Swain, S.K., Prusty, G., Jena, I.: Conductive, gas barrier, and thermal resistant behaviour of poly (methyl methacrylate) composite by dispersion of ZrO2 nanoparticles. Int. J. Polym. Mater. Polym. Biomater. 62, 733–736 (2013)CrossRef Swain, S.K., Prusty, G., Jena, I.: Conductive, gas barrier, and thermal resistant behaviour of poly (methyl methacrylate) composite by dispersion of ZrO2 nanoparticles. Int. J. Polym. Mater. Polym. Biomater. 62, 733–736 (2013)CrossRef
Zurück zum Zitat Swain, S.K., Isayev, A.I.: PA6/clay nanocomposites by continuous sonication process. J. Appl. Polym. Sci. 114, 2378–2387 (2009)CrossRef Swain, S.K., Isayev, A.I.: PA6/clay nanocomposites by continuous sonication process. J. Appl. Polym. Sci. 114, 2378–2387 (2009)CrossRef
Zurück zum Zitat Wang, X., Du, Y., Yang, J., Wang, X., Shi, Y., Hu, X.: Preparation, characterization and antimicrobial activity of chitosan/layered silicate nanocomposites. Polymer 47, 6738–6744 (2006)CrossRef Wang, X., Du, Y., Yang, J., Wang, X., Shi, Y., Hu, X.: Preparation, characterization and antimicrobial activity of chitosan/layered silicate nanocomposites. Polymer 47, 6738–6744 (2006)CrossRef
Zurück zum Zitat Yang, Y., Gu, H.: Preparation and properties of deep dye fibers from poly (ethylene terephthalate)/SiO2 nanocomposites by in situ polymerization. J. Appl. Polym. Sci. 105, 2363–2369 (2007)CrossRef Yang, Y., Gu, H.: Preparation and properties of deep dye fibers from poly (ethylene terephthalate)/SiO2 nanocomposites by in situ polymerization. J. Appl. Polym. Sci. 105, 2363–2369 (2007)CrossRef
Zurück zum Zitat Zhang, J., Zhuag, W., Zhang, Q., Liu, B., Wang, W., Hu, B., Shen, J.: Novel polylactide/vermiculite nanocomposites by in situ intercalative polymerization. I. Preparation, characterization, and properties. Polym. Compos. 28, 545–550 (2007)CrossRef Zhang, J., Zhuag, W., Zhang, Q., Liu, B., Wang, W., Hu, B., Shen, J.: Novel polylactide/vermiculite nanocomposites by in situ intercalative polymerization. I. Preparation, characterization, and properties. Polym. Compos. 28, 545–550 (2007)CrossRef
Zurück zum Zitat Zhong, Y., Janes, D., Zhang, Y., Hetzer, M., Kee, D.: Mechanical and oxygen barrier properties of organoclay-polyethylene nanocomposite films. Polym. Eng. Sci. 47, 1101–1107 (2007)CrossRef Zhong, Y., Janes, D., Zhang, Y., Hetzer, M., Kee, D.: Mechanical and oxygen barrier properties of organoclay-polyethylene nanocomposite films. Polym. Eng. Sci. 47, 1101–1107 (2007)CrossRef
Metadaten
Titel
Oxygen Permeability of Layer Silicate Reinforced Polymer Nanocomposites
verfasst von
Sarat K. Swain
Niladri Sarkar
Gyanaranjan Sahoo
Deepak Sahu
Copyright-Jahr
2016
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-10-1953-1_6

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