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Journal of Electroceramics
Erschienen in: Journal of Electroceramics 3-4/2020

26.05.2020

Oxygen vacancy-dependent multiferroic properties and the valence state of Fe in Bi6-xSmxFe1.4Ni0.6Ti3O18 ceramics prepared by combined combustion method

verfasst von: Jianan Lu, Yongjie Yin, Wei Wang, Xiangyu Mao, Xiaobing Chen

Erschienen in: Journal of Electroceramics | Ausgabe 3-4/2020

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Abstract

Sm-modified Bi6-xSmxFe1.4Ni0.6Ti3O18 (BSFNT- x) ceramics were prepared using the combined conbusiton method to investigate their multiferroic and dielectric properties. It is found that a structural phase evolution from an orthorhombic phase to a tetragonal one and then back to the orthorhombic phase over the doping range. The remanent polarization (2Pr) was increased up to 15.4 μC/cm2 when the Sm content is 0.30, which is attributed to the structural distortion and the oxygen vacancies induced by Sm modification. In the meanwhile, the remanent magnetization (2Mr) was also increased up to 1.9 emu/g in the BSFNT- 0.25 sample. The temperature spectra of the dielectric loss show the characteristics of dielectric relaxation from 120 K to 500 K, which can be ascribed to the electron-hopping between Fe3+ and Fe2+ ions. The XPS measurement indicates that a small amount of Sm modification enhances the inhibition of oxygen vacancies. However, the content of Fe2+ ions increases when Sm content is greater than 0.20.
Vorheriger Artikel The electrical and optical properties of Nb-doping PLZT (9/65/35) transparent ceramics
Nächster Artikel Effect of polyvinylidene fluoride on the acoustic impedance matching, poling enhancement and piezoelectric properties of 0–3 smart lead-free piezoelectric Portland cement composites

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Metadaten
Titel
Oxygen vacancy-dependent multiferroic properties and the valence state of Fe in Bi6-xSmxFe1.4Ni0.6Ti3O18 ceramics prepared by combined combustion method
verfasst von
Jianan Lu
Yongjie Yin
Wei Wang
Xiangyu Mao
Xiaobing Chen
Publikationsdatum
26.05.2020
Verlag
Springer US
Erschienen in
Journal of Electroceramics / Ausgabe 3-4/2020
Print ISSN: 1385-3449
Elektronische ISSN: 1573-8663
DOI
https://doi.org/10.1007/s10832-020-00213-8

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