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Journal of Materials Science
Erschienen in: Journal of Materials Science 6/2024

25.01.2024 | Ceramics

Perovskite-type RCoO3 (R = Pr, Eu, Gd) nanofibers for supercapacitor electrodes and antiferromagnet

verfasst von: Hanqiong Luo, Quanli Hu, Bin Yue, Suxuan Du

Erschienen in: Journal of Materials Science | Ausgabe 6/2024

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Abstract

Rare earth orthocobaltates nanofibers (PrCoO3, EuCoO3, and GdCoO3) were prepared by a simple electrospinning method coupled with calcination. The PrCoO3, EuCoO3, and GdCoO3 nanofibers have orthorhombic perovskite structure. The fabricated electrodes presented the typical pseudocapacitive characteristics, which originated from the reversible redox reactions of Co2+/Co3+ and Fe(CN)63−/Fe(CN)64−. At 1 A g−1, the specific capacitances of the PrCoO3, EuCoO3, and GdCoO3 nanofibers were 119, 133, and 196 F g−1, respectively. The electrochemical characteristics of the PrCoO3, EuCoO3, and GdCoO3 nanofibers exhibited favorable specific capacitance, good long-term cycling stability, and high coulombic efficiency, proving the possible application into energy storage devices. PrCoO3 and EuCoO3 nanofibers exhibited a magnetic state transition from paramagnetic to antiferromagnetic state. GdCoO3 nanofibers showed a paramagnetic ordering at high temperature. The cooperation of the R3+ ions and the Co2+ ions contributed to the magnetism of rare earth orthocobaltates nanofibers. The antiferromagnetic behaviors of the fabricated samples confirm the potential application into spin-electronic devices.
Vorheriger Artikel Research progress on doping modification of Ca3Co4O9 thermoelectric materials: a review
Nächster Artikel The effects of modification by Gd2O3 nanoparticles on optical properties and radiation resistance of CaSiO3 powders

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Metadaten
Titel
Perovskite-type RCoO3 (R = Pr, Eu, Gd) nanofibers for supercapacitor electrodes and antiferromagnet
verfasst von
Hanqiong Luo
Quanli Hu
Bin Yue
Suxuan Du
Publikationsdatum
25.01.2024
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 6/2024
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-024-09343-8

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