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Journal of Materials Science
Erschienen in: Journal of Materials Science 14/2018

17.04.2018 | Ceramics

Phase stability, microstructure and high-temperature properties of NbSi2- and TaSi2-oxide conducting ceramic composites

verfasst von: Gunes A. Yakaboylu, Katarzyna Sabolsky, Edward M. Sabolsky

Erschienen in: Journal of Materials Science | Ausgabe 14/2018

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Abstract

NbSi2- and TaSi2-based electroconductive ceramic composites with the addition of 40–70 vol% Al2O3 and ZrO2 particles were fabricated by high-temperature sintering (1400–1600 °C) under argon. Their phase stability, microstructural evolution, oxidation kinetics and electrical properties were studied at high temperatures. The densification of the composites was improved by increasing the oxide phase content and sintering temperature. The interaction of the starting metal disilicides with residual oxygen sources resulted in the formation of the hexagonal-structured 5–3 metal silicide (Nb5Si3 and Ta5Si3) phases. The increasing sintering temperature and volume percentage of the oxide phase reduced the pest oxidation, particularly for the silicide–alumina composites, which exhibited lower oxidation-induced mass changes than their dense monolithic metal silicides. Depending on the silicide–oxide volume percentage, their electrical conductivities ranged from 5.3 to 111.3 S/cm at 900 °C. Their phase stability, reduced oxidation rates and high electrical conductivities at high temperatures show promise for future high-temperature applications in advanced sensing.
Vorheriger Artikel Schiff base-assisted surface patterning of polylactide–zinc oxide films: generation, characterization and biocompatibility evaluation
Nächster Artikel Insights into structure and high-temperature oxidation behavior of plasma electrolytic oxidation ceramic coatings formed in NaAlO2–Na2CrO4 electrolyte

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Literatur
1.
Chu F, Lei M, Maloy SA, Petrovic JJ, Mitchell TE (1996) Elastic properties of C40 transition metal disilicides. Acta Mater 44:3035–3048CrossRef
2.
Xu N, Xu Y, Ma J (2015) Investigations on the structural, electronic, elastic and thermodynamic properties of niobium silicide under high temperature and pressure. Mater Sci Semicond Process 30:636–644CrossRef
3.
Ravindra NM, Jin L, Ivanov D, Mehta VR, Dieng LM, Popov G, Gokce OH, Grow J, Fiory AT (2002) Electrical and compositional properties of TaSi2 films. J Electron Mater 31:1074–1079CrossRef
4.
Shon I-J, Park H-K, Kim H-C, Yoon J-K, Ko I-Y (2008) Simultaneous pulsed current activated combustion synthesis and densification of NbSi2–SiC composite. Ceram Int 34:615–619CrossRef
5.
Wan B, Xiao F, Zhang Y, Zhao Y, Wu L, Zhang J, Gou H (2016) Theoretical study of structural characteristics, mechanical properties and electronic structure of metal (TM = V, Nb and Ta) silicides. J Alloys Compd 681:412–420CrossRef
6.
Ostling M, Zaring C (1995) Thermal properties of TM silicides. In: Maex K, Rossum MV (eds) Properties of metal silicides. Inspec/IEE, London, pp 31–44
7.
Nava F, Tu KN, Mazzega E, Michelini M, Queirolo G (1987) Electrical transport properties of transition-metal disilicides films. J Appl Phys 61:1085–1093CrossRef
8.
Pomoni K, Krontiras C, Salmi J (1990) Electrical transport properties of NbSi2 thin films. J Phys D Appl Phys 23:354–357CrossRef
9.
Chow TP, Steckl AJ (1983) Refractory metal silicides: thin-film properties and processing technology. IEEE Trans Electron Dev ED-30:1480–1497CrossRef
10.
Murarka SP, Read MH, Doherty CJ, Fraser DB (1982) Resistivities of thin film transition metal silicides. J Electrochem Soc Electrochem Sci Technol 129:293–301CrossRef
11.
Huang MT, Martin TL, Malhotra V, Mahan JE (1985) Electron transport properties of tantalum disilicide thin films. J Vac Sci Technol B 3:836–845CrossRef
12.
Binbin S, Peizhong F, Jianzhong W, Yuan G, Guangzhi W, Xiaohong W, Farid A (2014) Oxidation properties of self-propagating high temperature synthesized niobium disilicide. Corros Sci 85:311–317CrossRef
13.
Li CY, Yu ZH, Liu HZ, Lu TQ (2013) High pressure and high temperature in situ X-ray diffraction study on the structural stability of tantalum disilicide. Solid State Commun 157:1–5CrossRef
14.
Kurokawa K, Matsuoka H, Nagai T (1994) High temperature oxidation of some MSi2-type silicides. In: Yoshimura M, Maruyama T, Saito Y, Przybylski K, Stringer J (eds) Advanced materials’93. Elsevier, Amsterdam, pp 255–258
15.
Kreider KG (1995) Thin film high temperature silicide thermocouples. U.S. Patent No. 5474619
16.
Berztiss DA, Cerchiara RR, Gulbransen EA, Pettit FS, Meier GH (1992) Oxidation of MoSi2 and comparison with other silicide materials. Mater Sci Eng A 155:165–181CrossRef
17.
Yeh C-L, Huang Y-S (2012) Thermite-based combustion synthesis of niobium silicides/Al2O3 composites. High Temp Mater Process 16:57–69CrossRef
18.
Jo H-G, Shon I-J (2014) Simultaneous synthesis and consolidation of nanostructured WSi2–NbSi2 composite by pulsed current activated heating and its mechanical properties. J Ceram Process Res 15:371–375
19.
Li W, Yang H, Shan A, Zhang L, Jiansheng W (2005) Microstructure and properties of directionally solidified NbSi2/Nb5Si3 composites. Mater Sci Forum 475–479:733–736CrossRef
20.
Yazdani Z, Karimzadeh F, Abbasi MH (2014) Formation mechanism of NbSi2–Al2O3 nanocomposite subject to mechanical alloying. Adv Powder Technol 25:1357–1361CrossRef
21.
Carrillo-Heian EM, Unuvar C, Gibeling JC, Paulino GH, Munir ZA (2001) Simultaneous synthesis and densification of niobium silicide/niobium composites. Scr Mater 45:405–412CrossRef
22.
Rigney JD, Lewandowski JJ (1996) Loading rate and test temperature effects on fracture of in situ niobium silicide–niobium composites. Metall Mater Trans A 27A:3292–3306CrossRef
23.
Jo H-G, Shon I-J (2014) Pulsed current activated synthesis and consolidation of nanostructured MoSi2–NbSi2 composite and its mechanical properties. Mater Trans 55:391–394CrossRef
24.
Silvestroni L, Sciti D (2011) Densification of ZrB2–TaSi2 and HfB2–TaSi2 ultra-high-temperature ceramic composites. J Am Ceram Soc 94:1920–1930CrossRef
25.
Talmy IG, Zaykoski JA, Opeka MM (2008) High-temperature chemistry and oxidation of ZrB2 ceramics containing SiC, Si3N4, Ta5Si3, and TaSi2. J Am Ceram Soc 91:2250–2257CrossRef
26.
Wang S, Xu C, Ding Y, Zhang X (2013) Thermal shock behavior of ZrB2–SiC composite ceramics with added TaSi2. Int J Refract Metals Hard Mater 41:507–516CrossRef
27.
Sciti D, Silvestroni L, Guicciardi S, Fabbriche DD, Bellosi A (2009) Processing, mechanical properties and oxidation behavior of TaC and HfC composites containing 15 vol% TaSi2 or MoSi2. J Mater Res 24:2056–2065CrossRef
28.
Kobel S, Pluschke J, Vogt U, Graule TJ (2004) MoSi2–Al2O3 electroconductive ceramic composites. Ceram Int 30:2105–2110CrossRef
29.
Yamamoto H, Sendai S (1989) Study on high temperature thermistor made of MoSi2-granular Al2O3 composite. J Ceram Soc Jpn 97:783–786CrossRef
30.
Yakaboylu GA, Pillai RC, Sabolsky K, Sabolsky EM (2017) Stability and electrical properties of MoSi2- and WSi2-oxide electroconductive composites. J Am Ceram Soc 100:4461–4475CrossRef
31.
Yakaboylu GA, Pillai RC, Sabolsky K, Sabolsky EM (2018) MoSi2- and WSi2-based embedded ceramic composite thermocouples for high-temperature and harsh-environment sensing. Sens Actuators A Phys 272:139–152CrossRef
32.
Schneider CA, Rasband WS, Eliceiri KW (2012) NIH image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675CrossRef
33.
Lutterotti L, Matthies S, Wenk H-R (1999) MAUD: a friendly Java program for material analysis using diffraction. IUCr Newsl CPD 21:14–15
34.
ASTM B193-16 Standard test method for resistivity of electrical conductor materials. ASTM International, West Conshohocken
35.
Razavi-Tousi SS, Yazdani-Rad R, Manafi SA (2011) Effect of volume fraction and particle size of alumina reinforcement on compaction and densification behavior of Al–Al2O3 nanocomposites. Mater Sci Eng A 528:1105–1110CrossRef
36.
Rahaman MN (2003) Ceramic processing and sintering. Marcel Dekker, New York
37.
Guo S-Q (2009) Densification of ZrB2-based composites and their mechanical and physical properties: a review. J Eur Ceram Soc 29:995–1011CrossRef
38.
Yan Z, Martin CL, Guillon O, Bouvard D (2013) Effect of size and homogeneity of rigid inclusions on the sintering of composites. Scr Mater 69:327–330CrossRef
39.
Bauer JT, Scholz A, Berger C, Weiler L, Achtermann M (2008) Influence of metastable tetragonal ZrO2-reinforcements on the properties of MoSi2-composites. Int J Mater Res 99:352–358CrossRef
40.
Skandan G, Hahn H, Roddy M, Cannon WR (1994) Ultrafine-grained dense monoclinic and tetragonal zirconia. J Am Ceram Soc 77:1706–1710CrossRef
41.
Okada S, Okita K, Hamano K, Lundstrom T (2011) Growth conditions of Nb3Si, α-Nb5Si3 and NbSi2 single crystals from high-temperature metal solutions and properties of the crystals. High Temp Mater Process 13:311–318
42.
Talmy IG, Zaykoski JA, Opeka MM, Smith AH (2006) Properties of ceramics in the system ZrB2–Ta5Si3. J Mater Res 21:2593–2599CrossRef
43.
Schlesinger ME (1994) The Si–Ta (silicon–tantalum) system. J Phase Equilib 15:90–95CrossRef
44.
Chow TP, Lu WJ, Steckl AJ, Baliga BJ (1986) Thin film properties of sputtered niobium silicide on SiO2, Si3N4 and N+ poly-Si. J Electrochem Soc 133:175–178CrossRef
45.
Pinnow CU, Bicker M, Geyer U, Schneider S, Goerigk G (2001) Decomposition and nanocrystallization in reactively sputtered amorphous Ta–Si–N thin films. J Appl Phys 90:1986–1991CrossRef
46.
Choi Y-J, Yoon J-K, Kim G-H, Yoon W-Y, Doh J-M, Hong K-T (2017) High temperature isothermal oxidation behavior of NbSi2 coating at 1000–1450 °C. Corros Sci 129:102–114CrossRef
47.
Tougas IM, Amani M, Gregory OJ (2013) Metallic and ceramic thin film thermocouples for gas turbine engines. Sensors 13:15324–15347CrossRef
48.
Grobnic D, Smelser CW, Mihailov SJ, Walker RB (2006) Long-term thermal stability tests at 1000 °C of silica fibre Bragg gratings made with ultrafast laser radiation. Meas Sci Technol 17:1009–1013CrossRef
49.
Bennethum WH, Sherwood LT (1988) Sensors for ceramic components in advanced propulsion systems. NASA Contractor Report 180900
50.
Yeh CL, Huang YS (2011) Thermite reduction of Ta2O5/SiO2 powder mixtures for combustion synthesis of Ta-based silicides. J Alloys Compd 509:6302–6306CrossRef
51.
52.
Petrovic JJ, Pena MI, Reimanis IE, Sandlin MS, Conzone SD, Kung HH, Butt DP (1997) Mechanical behavior of MoSi2 reinforced-Si3N4 matrix composites. J Am Ceram Soc 80:3070–3076CrossRef
53.
Lemus-Ruiz J, Leon-Patino CA, Aguilar-Reyes EA (2006) Interface behavior during the self-joining of Si3N4 using a Nb-foil interlayer. Scr Mater 54:1339–1343CrossRef
54.
Zhang F, Zhang LT, Shan AD, Wu JS (2005) In situ observations of the pest oxidation process of NbSi2 at 1023 K. Scr Mater 53:653–656CrossRef
55.
Mitra R (2006) Mechanical behaviour and oxidation resistance of structural silicides. Int Mater Rev 51:13–64CrossRef
56.
Zhang F, Zhang LT, Shan AD, Wu JS (2006) Microstructural effect on oxidation kinetics of NbSi2 at 1023 K. J Alloys Compd 422:308–312CrossRef
57.
Niu Y, Huang L, Zhai C, Zeng Y, Zheng X, Ding C (2015) Microstructure and thermal stability of TaSi2 coating fabricated by vacuum plasma spray. Surf Coat Technol 279:1–8CrossRef
58.
Voglewede B, Rangel VR, Varma SK (2012) The effects of uncommon silicides on the oxidation behavior of alloys from the Nb–Cr–Si system. Corros Sci 61:123–133CrossRef
59.
Kurokawa K, Yamauchi A, Matsushita S (2005) Improvement of oxidation resistance of NbSi2 by addition of boron. Mater Sci Forum 502:243–248CrossRef
60.
Wang W, Yuan B, Zhou C (2014) Formation and oxidation resistance of germanium modified silicide coating on Nb based in situ composites. Corros Sci 80:164–168CrossRef
61.
Stergiou A, Tsakiropoulos P (1997) The intermediate and high-temperature oxidation behaviour of (Mo, X)Si2 (X = W, Ta) intermetallic alloys. Intermetallics 5:117–126CrossRef
62.
Chan KS (2004) Cyclic oxidation response of multiphase niobium-based alloys. Metall Mater Trans A 35A:589–597CrossRef
63.
Ito Y, Sato M, Wakisaka K, Yoshikado S (2009) Improvement of heating characteristics of molybdenum silicide thin film electric heaters. Electr Eng Jpn 168:452–458CrossRef
64.
Gottlieb U, Nava F, Affronte M, Laborde O, Madar R (1995) Electrical transport in metallic TM silicides. In: Maex K, Rossum MV (eds) Properties of metal silicides. Inspec/IEE, London, pp 189–204
Metadaten
Titel
Phase stability, microstructure and high-temperature properties of NbSi2- and TaSi2-oxide conducting ceramic composites
verfasst von
Gunes A. Yakaboylu
Katarzyna Sabolsky
Edward M. Sabolsky
Publikationsdatum
17.04.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 14/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2297-1

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