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Erschienen in: Journal of Materials Science 7/2015

01.04.2015 | Original Paper

Photocatalytic properties of titania/porous carbon fibers composites prepared by self-template method

verfasst von: Feng Teng, Guozhi Zhang, Youqing Wang, Caitian Gao, Zhenxing Zhang, Erqing Xie

Erschienen in: Journal of Materials Science | Ausgabe 7/2015

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Abstract

Photocatalytic degradation is one of the most popular routes applied in the wastewater treatments. But the most used nanoparticle photocatalysts have a serious drawback that the particles are not easy to precipitate and recover from water, which seriously hinder its applications. In this study, titania/porous carbon fibers composite prepared by a simple self-template method with micro-meter long carbon fibers and titania nanoparticles as precursors was investigated to solve these issues. The obtained composite can precipitate from the solution easily, which is the major reason that it can be used in actual applications. We found that the titania particles, as catalysts, could enhance the reaction between carbon fibers and oxygen during the calcinations process, and as a template, would determine the size and position of the pores on the fibers surface simultaneously. Due to the unique porous structure, the titania/porous carbon fibers composite shows considerable adsorption and high photocatalytic activity. Combining the advantages of titania and carbon fibers, the composite can be also applied in many other fields, such as water splitting for hydrogen and lithium ion batteries.

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Literatur
1.
Zurück zum Zitat Gomathi Devi L, Girish Kumar S, Mohan Reddy K, Munikrishnappa C (2009) Photo degradation of methyl orange an azo dye by advanced Fenton process using zero valent metallic iron: influence of various reaction parameters and its degradation mechanism. J Hazard Mater 164:459–467CrossRef Gomathi Devi L, Girish Kumar S, Mohan Reddy K, Munikrishnappa C (2009) Photo degradation of methyl orange an azo dye by advanced Fenton process using zero valent metallic iron: influence of various reaction parameters and its degradation mechanism. J Hazard Mater 164:459–467CrossRef
2.
Zurück zum Zitat Tang J, Chen S, Xu Y, Zhong W, Ma M, Wang Z (2012) Calibration and field performance of triolein embedded acetate membranes for passive sampling persistent organic pollutants in water. Environ Pollut 164:158–163CrossRef Tang J, Chen S, Xu Y, Zhong W, Ma M, Wang Z (2012) Calibration and field performance of triolein embedded acetate membranes for passive sampling persistent organic pollutants in water. Environ Pollut 164:158–163CrossRef
3.
Zurück zum Zitat El Saliby I, Erdei L, Kim JH, Shon HK (2013) Adsorption and photocatalytic degradation of methylene blue over hydrogen-titanate nanofibres produced by a peroxide method. Water Res 47:4115–4125CrossRef El Saliby I, Erdei L, Kim JH, Shon HK (2013) Adsorption and photocatalytic degradation of methylene blue over hydrogen-titanate nanofibres produced by a peroxide method. Water Res 47:4115–4125CrossRef
4.
Zurück zum Zitat Auta M, Hameed BH (2012) Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chem Eng J 198–199:219–227CrossRef Auta M, Hameed BH (2012) Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chem Eng J 198–199:219–227CrossRef
5.
Zurück zum Zitat Machida M, Fotoohi B, Amamo Y, Ohba T, Kanoh H, Mercier L (2012) Cadmium(II) adsorption using functional mesoporous silica and activated carbon. J Hazard Mater 221–222:220–227CrossRef Machida M, Fotoohi B, Amamo Y, Ohba T, Kanoh H, Mercier L (2012) Cadmium(II) adsorption using functional mesoporous silica and activated carbon. J Hazard Mater 221–222:220–227CrossRef
6.
Zurück zum Zitat Wu Z, Cheng Z, Ma W (2012) Adsorption of Pb(II) from glucose solution on thiol-functionalized cellulosic biomass. Bioresour Technol 104:807–809CrossRef Wu Z, Cheng Z, Ma W (2012) Adsorption of Pb(II) from glucose solution on thiol-functionalized cellulosic biomass. Bioresour Technol 104:807–809CrossRef
7.
Zurück zum Zitat Buchel R, Pratsinis SE, Baiker A (2012) Mono- and bimetallic Rh and Pt NSR-catalysts prepared by controlled deposition of noble metals on support or storage component. Appl Catal B Environ 113–114:160–171CrossRef Buchel R, Pratsinis SE, Baiker A (2012) Mono- and bimetallic Rh and Pt NSR-catalysts prepared by controlled deposition of noble metals on support or storage component. Appl Catal B Environ 113–114:160–171CrossRef
8.
Zurück zum Zitat Celorrio V, Montes de Oca MG, Plana D, Moliner R, Fermín DJ, Lázaro MJ (2012) Electrochemical performance of Pd and Au–Pd core–shell nanoparticles on surface tailored carbon black as catalyst support. Int J Hydrogen Energy 37:7152–7160CrossRef Celorrio V, Montes de Oca MG, Plana D, Moliner R, Fermín DJ, Lázaro MJ (2012) Electrochemical performance of Pd and Au–Pd core–shell nanoparticles on surface tailored carbon black as catalyst support. Int J Hydrogen Energy 37:7152–7160CrossRef
9.
Zurück zum Zitat Ben-Moshe T, Dror I, Berkowitz B (2009) Oxidation of organic pollutants in aqueous solutions by nanosized copper oxide catalysts. Appl Catal B Environ 85:207–211CrossRef Ben-Moshe T, Dror I, Berkowitz B (2009) Oxidation of organic pollutants in aqueous solutions by nanosized copper oxide catalysts. Appl Catal B Environ 85:207–211CrossRef
10.
Zurück zum Zitat Yan S, Wang J, Gao H et al (2013) Zinc gallogermanate solid solution: a novel photocatalyst for efficiently converting CO2 into solar fuels. Adv Funct Mater 23:1839–1845CrossRef Yan S, Wang J, Gao H et al (2013) Zinc gallogermanate solid solution: a novel photocatalyst for efficiently converting CO2 into solar fuels. Adv Funct Mater 23:1839–1845CrossRef
11.
Zurück zum Zitat Colmenares JC, Luque R (2014) Heterogeneous photocatalytic nanomaterials: prospects and challenges in selective transformations of biomass-derived compounds. Chem Soc Rev 43:765–778CrossRef Colmenares JC, Luque R (2014) Heterogeneous photocatalytic nanomaterials: prospects and challenges in selective transformations of biomass-derived compounds. Chem Soc Rev 43:765–778CrossRef
12.
Zurück zum Zitat Joo JB, Lee I, Dahl M, Moon GD, Zaera F, Yin Y (2013) Controllable synthesis of mesoporous TiO2 hollow shells: toward an efficient photocatalyst. Adv Funct Mater 23:4246–4254CrossRef Joo JB, Lee I, Dahl M, Moon GD, Zaera F, Yin Y (2013) Controllable synthesis of mesoporous TiO2 hollow shells: toward an efficient photocatalyst. Adv Funct Mater 23:4246–4254CrossRef
13.
Zurück zum Zitat Wang Y, Zhang Y-Y, Tang J et al (2013) Simultaneous etching and doping of TiO2 nanowire arrays for enhanced photoelectrochemical performance. ACS Nano 7:9375–9383CrossRef Wang Y, Zhang Y-Y, Tang J et al (2013) Simultaneous etching and doping of TiO2 nanowire arrays for enhanced photoelectrochemical performance. ACS Nano 7:9375–9383CrossRef
14.
Zurück zum Zitat He Y, Basnet P, Murph SE, Zhao Y (2013) Ag nanoparticle embedded TiO2 composite nanorod arrays fabricated by oblique angle deposition: toward plasmonic photocatalysis. ACS Appl Mater Interfaces 5:11818–11827CrossRef He Y, Basnet P, Murph SE, Zhao Y (2013) Ag nanoparticle embedded TiO2 composite nanorod arrays fabricated by oblique angle deposition: toward plasmonic photocatalysis. ACS Appl Mater Interfaces 5:11818–11827CrossRef
15.
Zurück zum Zitat Teng F, Li M, Gao C et al (2014) Preparation of black TiO2 by hydrogen plasma assisted chemical vapor deposition and its photocatalytic activity. Appl Catal B Environ 148–149:339–343CrossRef Teng F, Li M, Gao C et al (2014) Preparation of black TiO2 by hydrogen plasma assisted chemical vapor deposition and its photocatalytic activity. Appl Catal B Environ 148–149:339–343CrossRef
16.
Zurück zum Zitat Carneiro JO, Azevedo S, Fernandes F et al (2014) Synthesis of iron-doped TiO2 nanoparticles by ball-milling process: the influence of process parameters on the structural, optical, magnetic, and photocatalytic properties. J Mater Sci 49:7476–7488. doi:10.1007/s10853-014-8453-3 CrossRef Carneiro JO, Azevedo S, Fernandes F et al (2014) Synthesis of iron-doped TiO2 nanoparticles by ball-milling process: the influence of process parameters on the structural, optical, magnetic, and photocatalytic properties. J Mater Sci 49:7476–7488. doi:10.​1007/​s10853-014-8453-3 CrossRef
17.
Zurück zum Zitat Lee D, Kim H-B, Yu S, Kim HJ, Lee WI, Jang D-J (2014) Facile fabrication of anatase TiO2 nanotube arrays having high photocatalytic and photovoltaic performances by anodization of titanium in mixed viscous solvents. J Mater Sci 49:3414–3422. doi:10.1007/s10853-014-8051-4 CrossRef Lee D, Kim H-B, Yu S, Kim HJ, Lee WI, Jang D-J (2014) Facile fabrication of anatase TiO2 nanotube arrays having high photocatalytic and photovoltaic performances by anodization of titanium in mixed viscous solvents. J Mater Sci 49:3414–3422. doi:10.​1007/​s10853-014-8051-4 CrossRef
18.
19.
Zurück zum Zitat Cheng X, Liu H, Chen Q, Li J, Wang P (2014) Preparation of graphene film decorated TiO2 nano-tube array photoelectrode and its enhanced visible light photocatalytic mechanism. Carbon 66:450–458CrossRef Cheng X, Liu H, Chen Q, Li J, Wang P (2014) Preparation of graphene film decorated TiO2 nano-tube array photoelectrode and its enhanced visible light photocatalytic mechanism. Carbon 66:450–458CrossRef
20.
Zurück zum Zitat Chen P, Gu L, Xue X, Li M, Cao X (2010) Engineering the growth of TiO2 nanotube arrays on flexible carbon fibre sheets. Chem Commun 46:5906–5908CrossRef Chen P, Gu L, Xue X, Li M, Cao X (2010) Engineering the growth of TiO2 nanotube arrays on flexible carbon fibre sheets. Chem Commun 46:5906–5908CrossRef
21.
Zurück zum Zitat Guo W, Zhang F, Lin C, Wang ZL (2012) Direct growth of TiO2 nanosheet arrays on carbon fibers for highly efficient photocatalytic degradation of methyl orange. Adv Mater 24:4761–4764CrossRef Guo W, Zhang F, Lin C, Wang ZL (2012) Direct growth of TiO2 nanosheet arrays on carbon fibers for highly efficient photocatalytic degradation of methyl orange. Adv Mater 24:4761–4764CrossRef
22.
Zurück zum Zitat Woan K, Pyrgiotakis G, Sigmund W (2009) Photocatalytic carbon-nanotube-TiO2 composites. Adv Mater 21:2233–2239CrossRef Woan K, Pyrgiotakis G, Sigmund W (2009) Photocatalytic carbon-nanotube-TiO2 composites. Adv Mater 21:2233–2239CrossRef
23.
Zurück zum Zitat Xing M, Qi D, Zhang J et al (2012) Super-hydrophobic fluorination mesoporous MCF/TiO2 composite as a high-performance photocatalyst. J Catal 294:37–46CrossRef Xing M, Qi D, Zhang J et al (2012) Super-hydrophobic fluorination mesoporous MCF/TiO2 composite as a high-performance photocatalyst. J Catal 294:37–46CrossRef
24.
Zurück zum Zitat Daranyi M, Csesznok T, Kukovecz A et al (2011) Layer-by-layer assembly of TiO2 nanowire/carbon nanotube films and characterization of their photocatalytic activity. Nanotechnology 22:195701CrossRef Daranyi M, Csesznok T, Kukovecz A et al (2011) Layer-by-layer assembly of TiO2 nanowire/carbon nanotube films and characterization of their photocatalytic activity. Nanotechnology 22:195701CrossRef
25.
Zurück zum Zitat Yuan R, Guan R, Zheng J (2005) Effect of the pore size of TiO2-loaded activated carbon fiber on its photocatalytic activity. Scr Mater 52:1329–1334CrossRef Yuan R, Guan R, Zheng J (2005) Effect of the pore size of TiO2-loaded activated carbon fiber on its photocatalytic activity. Scr Mater 52:1329–1334CrossRef
26.
Zurück zum Zitat Shi J, Zheng J, Wu P, Ji X (2008) Immobilization of TiO2 films on activated carbon fiber and their photocatalytic degradation properties for dye compounds with different molecular size. Catal Commun 9:1846–1850CrossRef Shi J, Zheng J, Wu P, Ji X (2008) Immobilization of TiO2 films on activated carbon fiber and their photocatalytic degradation properties for dye compounds with different molecular size. Catal Commun 9:1846–1850CrossRef
27.
Zurück zum Zitat Wu X, Yin S, Dong Q et al (2013) Synthesis of high visible light active carbon doped TiO2 photocatalyst by a facile calcination assisted solvothermal method. Appl Catal B Environ 142–143:450–457CrossRef Wu X, Yin S, Dong Q et al (2013) Synthesis of high visible light active carbon doped TiO2 photocatalyst by a facile calcination assisted solvothermal method. Appl Catal B Environ 142–143:450–457CrossRef
28.
Zurück zum Zitat Zhang G, Teng F, Wang Y et al (2013) Preparation of carbon–TiO2 nanocomposites by a hydrothermal method and their enhanced photocatalytic activity. RSC Adv 3:24644–24649CrossRef Zhang G, Teng F, Wang Y et al (2013) Preparation of carbon–TiO2 nanocomposites by a hydrothermal method and their enhanced photocatalytic activity. RSC Adv 3:24644–24649CrossRef
29.
Zurück zum Zitat Zhang G, Teng F, Zhao C et al (2014) Enhanced photocatalytic activity of TiO2/carbon@TiO2 core–shell nanocomposite prepared by two-step hydrothermal method. Appl Surf Sci 311:384–390CrossRef Zhang G, Teng F, Zhao C et al (2014) Enhanced photocatalytic activity of TiO2/carbon@TiO2 core–shell nanocomposite prepared by two-step hydrothermal method. Appl Surf Sci 311:384–390CrossRef
30.
Zurück zum Zitat Imae T, Muto K, Ikeda S (1991) The pH dependence of dispersion of TiO2 particles in aqueous surfactant solutions. Colloid Polym Sci 269:43–48CrossRef Imae T, Muto K, Ikeda S (1991) The pH dependence of dispersion of TiO2 particles in aqueous surfactant solutions. Colloid Polym Sci 269:43–48CrossRef
31.
Zurück zum Zitat Barbé CJ, Arendse F, Comte P et al (1997) Nanocrystalline titanium oxide electrodes for photovoltaic applications. J Am Ceram Soc 80:3157–3171CrossRef Barbé CJ, Arendse F, Comte P et al (1997) Nanocrystalline titanium oxide electrodes for photovoltaic applications. J Am Ceram Soc 80:3157–3171CrossRef
32.
Zurück zum Zitat Spurr RA, Myers H (1957) Quantitative analysis of anatase-rutile mixtures with an X-ray diffractometer. Anal Chem 29:760–762CrossRef Spurr RA, Myers H (1957) Quantitative analysis of anatase-rutile mixtures with an X-ray diffractometer. Anal Chem 29:760–762CrossRef
33.
Zurück zum Zitat Zhang W, He Y, Zhang M, Yin Z, Chen Q (2000) Raman scattering study on anatase TiO2 nanocrystals. J Phys D Appl Phys 33:912–916CrossRef Zhang W, He Y, Zhang M, Yin Z, Chen Q (2000) Raman scattering study on anatase TiO2 nanocrystals. J Phys D Appl Phys 33:912–916CrossRef
34.
Zurück zum Zitat Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134:6575–6578CrossRef Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134:6575–6578CrossRef
35.
Zurück zum Zitat Hung M-C, Yuan S-Y, Hung C-C, Cheng C-L, Ho H-C, Ko T-H (2014) Effectiveness of ZnO/carbon-based material as a catalyst for photodegradation of acrolein. Carbon 66:93–104CrossRef Hung M-C, Yuan S-Y, Hung C-C, Cheng C-L, Ho H-C, Ko T-H (2014) Effectiveness of ZnO/carbon-based material as a catalyst for photodegradation of acrolein. Carbon 66:93–104CrossRef
36.
Zurück zum Zitat Zheng ZQ, Zhou XP, Damjanovic D (2013) Reduction of Ti4+ to Ti3+ in boron-doped BaTiO3 at very low temperature. J Am Ceram Soc 96:3504–3510CrossRef Zheng ZQ, Zhou XP, Damjanovic D (2013) Reduction of Ti4+ to Ti3+ in boron-doped BaTiO3 at very low temperature. J Am Ceram Soc 96:3504–3510CrossRef
37.
Zurück zum Zitat Lin Y-T, Weng C-H, Lin Y-H, Shiesh C-C, Chen F-Y (2013) Effect of C content and calcination temperature on the photocatalytic activity of C-doped TiO2 catalyst. Sep Purif Technol 116:114–123CrossRef Lin Y-T, Weng C-H, Lin Y-H, Shiesh C-C, Chen F-Y (2013) Effect of C content and calcination temperature on the photocatalytic activity of C-doped TiO2 catalyst. Sep Purif Technol 116:114–123CrossRef
38.
Zurück zum Zitat Nakamura I, Negishi N, Kutsuna S, Ihara T, Sugihara S, Takeuchi K (2000) Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal. J Mol Catal A: Chem 161:205–212CrossRef Nakamura I, Negishi N, Kutsuna S, Ihara T, Sugihara S, Takeuchi K (2000) Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal. J Mol Catal A: Chem 161:205–212CrossRef
39.
Zurück zum Zitat Long J, Chang H, Gu Q et al (2014) Gold-plasmon enhanced solar-to-hydrogen conversion on the 001 facets of anatase TiO2 nanosheets. Energy Environ Sci 7:973–977CrossRef Long J, Chang H, Gu Q et al (2014) Gold-plasmon enhanced solar-to-hydrogen conversion on the 001 facets of anatase TiO2 nanosheets. Energy Environ Sci 7:973–977CrossRef
40.
Zurück zum Zitat Hsiao Y-C, Wu T-F, Wang Y-S, Hu C-C, Huang C (2014) Evaluating the sensitizing effect on the photocatalytic decoloration of dyes using anatase-TiO2. Appl Catal B Environ 148–149:250–257CrossRef Hsiao Y-C, Wu T-F, Wang Y-S, Hu C-C, Huang C (2014) Evaluating the sensitizing effect on the photocatalytic decoloration of dyes using anatase-TiO2. Appl Catal B Environ 148–149:250–257CrossRef
Metadaten
Titel
Photocatalytic properties of titania/porous carbon fibers composites prepared by self-template method
verfasst von
Feng Teng
Guozhi Zhang
Youqing Wang
Caitian Gao
Zhenxing Zhang
Erqing Xie
Publikationsdatum
01.04.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-8857-8

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