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Topics in Catalysis

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18.07.2018 | Original Paper

Photoelectrocatalytic Reduction of CO₂ to Chemicals via ZnO@Nickel Foam: Controlling C–C Coupling by Ligand or Morphology

verfasst von: Jixian Wang, Bo Han, Rong Nie, Yanjie Xu, Xiaogang Yu, Yapeng Dong, Jianguo Wang, Huanwang Jing

Erschienen in: Topics in Catalysis | Ausgabe 15-17/2018

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Abstract

The CO₂ reduction is a very attracting research field in the environmental, material and chemical sciences in light of the energy crisis and greenhouse effect. A new photoelectrocatalytic system composed of a photoanode BiVO₄ and a photocathode of nickel foam supported ZnO semiconductor was designed, assembled and applied to CO₂ reduction in water. The photocathodes with different morphology could be made from electrochemical deposition method and well characterized by SEM, UV–Vis, XRD, and XPS. The photoelectrocatalytic cell of ZnO/Ni-30|KHCO₃|BiVO₄ can produce ethanol and acetic acid in a rate of 12.5 µM h⁻¹ cm⁻² with 100% selectivity for C₂ product, attributing to the controlling of 3D-spaces of nanorod. The cell of A-ZnO/Ni-15|KHCO₃|BiVO₄ produces ethanol and acetic acid with 75% selectivity for C₂ product under 100 mW cm⁻² simulated sunlight irradiation, attributing to controlling of both amine ligand and morphology of ZnO, which reveal a new way to increase the selectivity of products.

Vorheriger Artikel Higher Hydrocarbons Synthesis from CO2 Hydrogenation Over K- and La-Promoted Fe–Cu/TiO2 Catalysts

Nächster Artikel Mg(OH)2 Films Prepared by Ink-Jet Printing and Their Photocatalytic Activity in CO2 Reduction and H2O Conversion

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Titel: Photoelectrocatalytic Reduction of CO2 to Chemicals via ZnO@Nickel Foam: Controlling C–C Coupling by Ligand or Morphology
verfasst von: Jixian Wang
Bo Han
Rong Nie
Yanjie Xu
Xiaogang Yu
Yapeng Dong
Jianguo Wang
Huanwang Jing
Publikationsdatum: 18.07.2018
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 15-17/2018
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-018-1018-y

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