Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Environmental Earth Sciences
Erschienen in: Environmental Earth Sciences 9/2015

01.05.2015 | Thematic Issue

PHREEQC program-based simulation of magnesium phosphates crystallization for phosphorus recovery

verfasst von: Yonghui Song, Feng Qian, Ying Gao, Xiaohui Huang, Jieyun Wu, Huibin Yu

Erschienen in: Environmental Earth Sciences | Ausgabe 9/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

To reveal the effects of solution conditions on the crystallization of magnesium phosphates during phosphorus recovery from wastewater, the geochemical aquatic modeling program PHREEQC (version 2.11) was applied to the calculations of ion speciation and saturation index (SI) of different magnesium phosphates in a chemically defined crystallization system. The results showed that the relationship between SI of magnesium ammonium phosphate (MgNH4PO4·6H2O, MAP), Mg3(PO4)2·8H2O (MP-8W) and Mg3(PO4)2·22H2O (MP-22W), and the respective composition ion concentration was of logarithmic function. There was polynomial function relationship between SI values of magnesium phosphates and solution pH value. The optimum pH for MAP crystallization was around 9.0, while it was 9.0–10.0 for MP-8W and MP-22W. The SI values decreased as the carbonate concentration increased. Meanwhile, the SI values, decreasing with the increase in solution ionic strength, were of logarithmic function to the solution ionic strength. Besides, the SI values were also of polynomial function to the solution temperature. Under different pH values, the SI values presented different variation trends as the temperature rose. For the case study of P removal from synthetic swine wastewater, the P removal trend at different pH, N:P and Mg:N was closer to the predictions of thermodynamic modeling.
Vorheriger Artikel The effects and mechanism of alkalinity on the phosphate recovery from anaerobic digester effluent using dolomite lime
Nächster Artikel Spatial distribution and diversity of microbial community in large-scale constructed wetland of the Liao River Conservation Area

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Fußnoten
1
PHREEQC (version 2.11)—A Computer Program for Speciation, Batch-Reaction, One-Dimensional Transport, and Inverse Geochemical Calculations. http://​wwwbrr.​cr.​usgs.​gov/​projects/​GWC_​coupled/​phreeqc/​.
 
Literatur
Altinbas M, Yangin C, Ozturk I (2002) Struvite precipitation from anaerobically treated municipal and landfill wastewaters. Water Sci Technol 46:271–278
Arakane M, Imai T, Murakami S, Takeuchi M, Ukita M, Sekine M, Higuchi T (2006) Resource recovery from excess sludge by subritical water combined with magnesium ammonium phosphate process. Water Sci Technol 54(9):81–86CrossRef
Battistoni P, Fava G, Pavan P, Musacco A, Cecchi F (1997) Phosphate removal in anaerobic liquors by struvite crystallization without addition of chemicals: preliminary results. Water Res 31(11):2925–2929CrossRef
Bhuiyan MIH, Mavinic DS, Beckie RD (2008) Nucleation and growth kinetics of struvite in a fluidized bed reactor. J Cryst Growth 310:1187–1194CrossRef
Çelen I, Buchanan JR, Burns RT, Robinson RB, Raman DR (2007) Using a chemical equilibrium model to predict amendments required to crystal phosphorus as struvite in liquid swine manure. Water Res 41(8):1689–1696CrossRef
Chen N, Hu WW, Feng CP, Zhang ZY (2014) Removal of phosphorus from water using scallop shell synthesized ceramic biomaterials. Environ Earth Sci 71:2133–2142CrossRef
de-Bashan LE, Bashan Y (2004) Recent advances in removing phosphorus from wastewater and its future use as fertilizer (1997–2003). Water Res 38(19):4222–4246
Diwani GE, Rafie ShE, Ibiari NNE, El-Aila HI (2007) Recovery of ammonia nitrogen from industrial wastewater treatment as struvite slow releasing fertilizer. Desalination 214:200–214CrossRef
Donnert D (1988) Investigations on phosphorus removal from wastewater. Progress Report KFK 4459. Kernforschungszentrum Karlsruhe, Karlsruhe
Doyle JD, Parsons SA (2002) Struvite formation, control and recovery. Water Res 36(16):3925–3940CrossRef
Eljamal O, Okawauchi J, Hiramatsu K, Harada M (2013) Phosphorus sorption from aqueous solution using naturalmaterials. Environ Earth Sci 65:859–863CrossRef
Escudero A, Blanco F, Lacalle A, Pinto M (2015) Struvite precipitation for ammonium removal from anaerobically treated effluents. J Environ Chem Eng 3:413–419CrossRef
Etter B, Tilley E, Khadka R, Udert KM (2011) Low-cost struvite production using source-separated urine in Nepal. Water Res 45:852–862CrossRef
Gunay A, Karadag D, Tosun I, Ozturk M (2008) Use of magnesit as a magnesium source for ammonium removal from leachate. J Hazard Mater 156(1–3):619–623CrossRef
Harris WG, Wilkie AC, Cao X (2008) Bench-scale recovery of phosphorus from flushed dairy manure wastewater. Bioresour Technol 99(8):3036–3043CrossRef
He S, Zhang Y, Yang M, Du W, Harada H (2007) Repeated use of MAP decomposition residues for the removal of high ammonium concentration from landfill leachate. Chemosphere 66:2233–2238CrossRef
Hirasawa I, Kaneko S, Kanai Y, Hosoya S, Okuyama K, Kamahara T (2002) Crystallization phenomena of magnesium ammonium phosphate (MAP) in a fluidized-bed-type crystallizer. J Cryst Growth 237–239:2183–2187CrossRef
Huang HM, Yang J, Li D (2014) Recovery and removal of ammonia-nitrogen and phosphate from swine wastewater by internal recycling of struvite chlorination product. Bioresour Technol 172:253–259CrossRef
Hutnik N, Kozik A, Mazienczuk A, Piotrowski K, Wierzbowska B, Matynia A (2013) Phosphates (V) recovery from phosphorus mineral fertilizers industry wastewater by continuous struvite reaction crystallization process. Water Res 47:3635–3643CrossRef
Liang Z, Peng XJ, Luan ZK, Li WJ, Zhao Y (2012) Reduction of phosphorus release from high phosphorus soil by red mud. Environ Earth Sci 65:581–588CrossRef
Mamais D, Pitt PA, Cheng YW, Loiacono J, Jenkins D (1994) Determination of ferric chloride dose to control struvite precipitation in anaerobic sludge digester. Water Environ Res 66(7):912–918CrossRef
Marti N, Bouzas A, Seco A, Ferrer J (2008) Struvite precipitation assessment in anaerobic digestion processes. Chem Eng J 141(1–3):67–74CrossRef
Massey MS, Ippolito JA, Davis JG, Sheffield RE (2010) Macroscopic and microscopic variation in recovered magnesium phosphate materials: implications for phosphorus removal processes and product re-use. Bioresour Technol 101(3):877–885CrossRef
Musvoto EV, Wentzel MC, Ekama GA (2000) Integrated chemical-physical processes modelling—II. Simulating aeration treatment of anaerobic digester supernatants. Water Res 34:1868–1880CrossRef
Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (Version 2)-A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. Water-Resources Investigations Report 99-4259. US Department of the Interior, US Geological Survey, Denver, Colorado
Pastor L, Mangin D, Barat R, Seco A (2008) A pilot-scale study of struvite precipitation in a stirred tank reactor: conditions influencing the process. Bioresour Technol 99(14):6285–6291CrossRef
Ronteltap M, Maurer M, Gujer W (2007) Struvite precipitation thermodynamics in source-separated urine. Water Res 41:984–997
Saidou H, Korchef A, Moussa SB, Amor MB (2009) Struvite precipitation by the dissolved CO2 degasification technique: impact of the airflow rate and pH. Chemosphere 74(2):338–343CrossRef
Shu L, Schneider P, Jegatheesan V, Johnson J (2006) An economic evaluation of phosphorus recovery as struvite from digester supernatant. Bioresour Technol 97(17):2211–2216CrossRef
Song Y, Hahn HH, Hoffmann E (2002) Effects of solution conditions on the precipitation of phosphate for recovery: a thermodynamic evaluation. Chemosphere 48:1029–1034CrossRef
Song Y, Yuan P, Zhen B, Peng J, Yuan F, Gao Y (2007) Nutrients removal and recovery by crystallization of magnesium ammonium phosphate from synthetic swine wastewater. Chemosphere 69(2):319–324CrossRef
Song YH, Dai YR, Hu Q, Yu XH, Qian F (2014) Effects of three kinds of organic acids on phosphorus recovery by magnesium ammonium phosphate (MAP) crystallization from synthetic swine wastewater. Chemosphere 101:41–48CrossRef
State Environmental Protection Administration of China (2002) Monitoring and Analytical Methods of Water and Wastewater, 4th edn. China Environmental Science Press, Beijing
Stratful I, Scrimshaw MD, Lester JN (2001) Conditions influencing the precipitation of magnesium ammonium phosphate. Water Res 35(17):4191–4199CrossRef
Strickland J (1999) Perspectives for phosphorus recovery offered by enhanced biological P removal. Environ Technol 20:721–725CrossRef
Suzuki K, Tanaka Y, Kuroda K, Hanajima D, Fukumoto Y, Yasuda T, Waki M (2007) Removal and recovery of phosphorous from swine wastewater by demonstration crystallization reactor and struvite accumulation device. Bioresour Technol 98:1573–1578CrossRef
Wang JS, Song YH, Yuan P, Peng JF, Fan MH (2006) Modeling the crystallization of magnesium ammonium phosphate for phosphorus recovery. Chemosphere 65(7):1182–1187CrossRef
Yetilmezsoy K, Sapci-Zengin Z (2009) Recovery of ammonium nitrogen from the effluent of UASB treating poultry manure wastewater by MAP precipitation as a slow release fertilizer. J Hazard Mater 166(1):260–269CrossRef
Zhang T, Ding L, Ren H, Guo Z, Tan J (2010) Thermodynamic modeling of ferric phosphate precipitation for phosphorus removal and recovery from wastewater. J Hazard Mater 176:444–450CrossRef
Metadaten
Titel
PHREEQC program-based simulation of magnesium phosphates crystallization for phosphorus recovery
verfasst von
Yonghui Song
Feng Qian
Ying Gao
Xiaohui Huang
Jieyun Wu
Huibin Yu
Publikationsdatum
01.05.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Environmental Earth Sciences / Ausgabe 9/2015
Print ISSN: 1866-6280
Elektronische ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-015-4340-8

Weitere Artikel der Ausgabe 9/2015

Environmental Earth Sciences 9/2015 Zur Ausgabe

Thematic Issue

Risk assessment methodology for Shenyang Chemical Industrial Park based on fuzzy comprehensive evaluation

Original Article

Phosphorus, organic matter and nitrogen distribution characteristics of the surface sediments in Nansi Lake, China

Original Article

Seawater intrusion in the Guanahacabibes Peninsula (Pinar del Rio Province, western Cuba): effects on karst development and water isotope composition

Thematic Issue

Simulation–optimization method based on rationality evaluation for waste load allocation in Daliao river

Thematic Issue

Overview of POPs and heavy metals in Liao River Basin

Thematic Issue

The possible allelopathic effect of Hydrilla verticillata on phytoplankton in nutrient-rich water