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01.09.2012 | Original Contribution

Pluronic F-68 nanodots incorporating pyrimidine chromophores

verfasst von: Laeticia Vurth, Caroline Hadad, Sylvain Achelle, Joaquín C. García-Martinez, Julián Rodríguez-López, Olivier Stéphan

Erschienen in: Colloid and Polymer Science | Ausgabe 14/2012

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Abstract

We report the synthesis of nanosized particles based on bio-compatible polyethylene–polypropylene glycol (pluronic) materials. In aqueous solution, mini-emulsification of pluronic with two pyrimidine chromophores leads to nanoparticles with hydrodynamic radius below 100 nm. We have demonstrated that these probes exhibit a fast and fully reversible solvatochromic behaviour from yellow to purple when decreasing the pH solution. The average acidity constant of both dyes incorporated in pluronic mainly originate from the non-substituted pyrimidine (1,3-diazine) core. The close functionalization of the pyrimidine with pyridyl groups leads to a tridentate ligand suitable for metal cations complexation.

Vorheriger Artikel Nanoscale-confined crystallization in epoxy resin and polyethylene-block-poly(ethylene oxide) diblock copolymer blends

Nächster Artikel The formation of vesicles by N-dodecyl-N-methylpyrrolidinium bromide ionic liquid/copper dodecyl sulfate and application in the synthesis of leaflike CuO nanosheets

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Titel: Pluronic F-68 nanodots incorporating pyrimidine chromophores
verfasst von: Laeticia Vurth
Caroline Hadad
Sylvain Achelle
Joaquín C. García-Martinez
Julián Rodríguez-López
Olivier Stéphan
Publikationsdatum: 01.09.2012
Verlag: Springer-Verlag
Erschienen in: Colloid and Polymer Science / Ausgabe 14/2012
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-012-2652-8

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