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01.07.2022 | Composites & nanocomposites

Poly(hydromethylsiloxane)-derived high internal phase emulsion-templated materials (polyHIPEs) containing palladium for catalytic applications

verfasst von: Jan Mrówka, Robert Kosydar, Mariusz Gackowski, Jacek Gurgul, Lidia Lityńska-Dobrzyńska, Bartosz Handke, Alicja Drelinkiewicz, Magdalena Hasik

Erschienen in: Journal of Materials Science | Ausgabe 26/2022

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Abstract

Cross-linking of poly(hydromethylsiloxane) (PHMS) with 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (D₄^Vi) in water-in-oil high internal phase emulsion (HIPE) whose aqueous phase comprises PdCl₂ is developed as a new, one-step route for the fabrication of polysiloxane-based, porous HIPE-templated materials (polyHIPEs) containing palladium. It is shown that the microstructure of the systems depends on the amount of D₄^Vi with respect to PHMS and is also significantly influenced by the presence of PdCl₂ in HIPE. PolyHIPEs thus obtained contain metallic Pd nanoparticles (~ 4–10 nm in size) that strongly interact with the polysiloxane matrix they are dispersed in. The materials catalyse phenylacetylene hydrogenation to styrene yielding this product with fair selectivity. Incorporation of Pd into the pre-formed PHMS-based polyHIPE (the two-step procedure) conducted for comparison results in the material containing nanoclusters of Pd and displaying highly selective hydrogenation of phenylacetylene to styrene, but at a relatively low rate.

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Vorheriger Artikel ZnO energy transfer and enhanced photoluminescence in MEH-PPV/ZnO hybrid nanocomposite

Nächster Artikel Revealing sulfur- and phosphorus-induced embrittlement and local structural phase transformation of superlattice intrinsic stacking faults in L12-Ni3Al

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Titel: Poly(hydromethylsiloxane)-derived high internal phase emulsion-templated materials (polyHIPEs) containing palladium for catalytic applications
verfasst von: Jan Mrówka
Robert Kosydar
Mariusz Gackowski
Jacek Gurgul
Lidia Lityńska-Dobrzyńska
Bartosz Handke
Alicja Drelinkiewicz
Magdalena Hasik
Publikationsdatum: 01.07.2022
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 26/2022
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-022-07414-2

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