Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Cellulose
Erschienen in: Cellulose 6/2011

01.12.2011

Polypyrrole (PPy) chemical synthesis with xylan in aqueous medium and production of highly conducting PPy/nanofibrillated cellulose films and coatings

verfasst von: Claudia Sasso, Nicolas Bruyant, Davide Beneventi, Jerôme Faure-Vincent, Elisa Zeno, Michel Petit-Conil, Didier Chaussy, Mohamed Naceur Belgacem

Erschienen in: Cellulose | Ausgabe 6/2011

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Polypyrrole was chemically synthesised by using, for the first time, Birchwood xylan as additive, and ammonium peroxydisulfate (APS) as oxidant. The impact of additive concentration, polymerisation time and reagents concentration on PPy conductivity was studied. It was shown that, once fixed the pyrrole (Py)/APS and Py/xylan optimal ratios, the best conductivities (26 S/cm) were obtained for short polymerisation times (30 min) and increased reactants concentration. Morphological analysis of PPy particles, Py depletion kinetics and oxido-reduction potential measurements of the solutions provided interpretation elements on the impact of the polymerisation time on PPy pellet conductivity. Furthermore, optimised PPy particles obtained with xylan (PPyx) were mixed with nanofibrillated cellulose (NFC) in order to obtain freestanding films. Their electrical and handling performances were evaluated at increasing PPy weight fraction in the samples. The conductivity mechanism of the most conductive sample (in comparison with a low performing sample) was investigated by measuring the conductivity as a function of temperature (4–350 K) and two transport regimes were identified. Selected formulations were finally used to produce conducting PPy/NFC coatings on non-absorbent (glass) and absorbent (copy paper) substrates. The impact of NFC in the percolation of PPy particles, then in the coating conductivity, was investigated.
Vorheriger Artikel Cellulose acetate/poly(methyl methacrylate) interpenetrating networks: synthesis and estimation of thermal and mechanical properties
Nächster Artikel Effect of alkylimidazolium based ionic liquids on the structure of UV-irradiated cellulose

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
Ali M, Sreekrishnan TR (2001) Aquatic toxicity from pulp and paper mill effluents: a review. Adv Environ Res 5(2):175–196CrossRef
Amaike M, Yamamoto H (2006) Preparation of polypyrrole by emulsion polymerization using hydroxypropyl cellulose. Polym J 38(7):703–709CrossRef
Amash A, Zugenmaier P (1998) Study on cellulose and xylan filled polypropylene composites. Polym Bull 40(2–3):251–258CrossRef
Aulin C, Gällstedt M, Lindström T (2010) Oxygen and oil barrier properties of microfibrillated cellulose films and coatings. Cellulose 17(3):559–574CrossRef
Chen X, Issi J, Devaux J, Billaud D (1995) The conducting behavior and stability of conducting polymer composites. Polym Eng Sci 35(8):642–647CrossRef
Demir I, Serhat Baspinar M, Orhan M (2005) Utilization of kraft pulp production residues in clay brick production. Build Environ 40(11):1533–1537
Denneulin A, Blayo A, Bras J, Neuman C (2008) PEDOT: PSS coating on specialty papers: process optimization and effects of surface properties on electrical performances. Progress Org Coat 63(1):87–91CrossRef
Ebringerová A, Sroková I, Talába P, Kačuráková M, Hromádková Z (1998) Amphiphilic beechwood glucuronoxylan derivatives. J Appl Polym Sci 67(9):1523–1530CrossRef
Eder F, Klauk H, Halik M, Zschieschang U, Schmid G, Dehm C (2004) Organic electronics on paper. Appl Phys Lett 84(14):2673–2675CrossRef
Fournier J, Boiteux G, Seytre G, Marichy G (1997) Percolation network of polypyrrole in conducting polymer composites. Synth Met 84(1–3):839–840CrossRef
Fuhrmann A, Krogerus B (2009) Xylan from bleached hardwood pulp-new opportunities. TAPPI engineering, pulping, environmental conference, Memphis, TN, United States, 11–14 Oct
Gabrielii I, Gatenholm P (1998) Preparation and properties of hydrogels based on hemicellulose. J Appl Polym Sci 69(8):1661–1667CrossRef
Glasser W, Kaar WE, Jain RK, Sealey JE (2000) Isolation options for non-cellulosic heteropolysaccharides (HetPS). Cellulose 7(3):299–317CrossRef
Jain RK, Sjöstedt M, Glasser WG (2000) Thermoplastic xylan derivatives with propylene oxide. Cellulose 7(4):319–336CrossRef
Kudoh Y, Akami K, Matsuya Y (1998) Properties of chemically prepared polypyrrole with an aqueous solution containing Fe2(SO4)3, a sulfonic surfactant and a phenol derivative. Synth Met 95(3):191–196CrossRef
Kuwabata S, Nakamura J, Yoneyama H (1990) Dependence of conductivity of polypyrrole film doped with p-phenol sulfonate on solution pH. J Electrochem Soc 137(7):1788–1792CrossRef
Lei J, Cai Z, Martin CR (1992) Effect of reagent concentrations used to synthesize polypyrrole on the chemical characteristics and optical and electronic properties of the resulting polymer. Synth Met 46(1):53–69CrossRef
Lowys M-P, Desbrières J, Rinaudo M (2001) Rheological characterization of cellulosic microfibril suspensions. Role of polymeric additives. Food Hydrocoll 15(1):25–32
Mahmud H, Kassim A, Zainal Z, Mat Yunus WM (2005) Electrochemical formation of polypyrrole-carboxymethylcellulose conducting polymer composite films. J Mater Sci Technol 21(5):661–665
Mahro B, Timm M (2007) Potential of biowaste from the food industry as a biomass resource. Eng Life Sci 7(5):457–468CrossRef
Mott NF, Davis EA (1971) Electronic processes in non-crystalline materials. Clarendon Press, Oxford
Moure A, Gullón P, Domínguez H, Parajó JC (2006) Advances in the manufacture, purification and applications of xylo-oligosaccharides as food additives and nutraceuticals. Process Biochem 41(9):1913–1923CrossRef
Nalwa HS (1997) Handbook of organic conductive molecules and polymers (chapter 2), vol 4. Wiley, New York
Nogi M, Yano H (2008) Transparent nanocomposites based on cellulose produced by bacteria offer potential innovation in the electronics device industry. Adv Mat 20(10):1849–1852CrossRef
Novák P (1992) Limitations of polypyrrole synthesis in water and their causes. Electrochim Acta 37(7):1227–1230CrossRef
Nyström G, Mihranyan A, Razaq A, Lindström T, Nyholm L, Strømme M (2010) A nanocellulose polypyrrole composite based on microfibrillated cellulose from wood. J Phys Chem B 114(12):4178–4182CrossRef
Okahisa Y, Yoshida A, Miyaguchi S, Yano H (2009) Optically transparent wood-cellulose nanocomposite as a base substrate for flexible organic light-emitting diode displays. Compos Sci Tech 69(11–12):1958–1961CrossRef
Omastová M, Trchová M, Kovárová J, Stejskal J (2003) Synthesis and structural study of polypyrroles prepared in the presence of surfactants. Synth Met 138(3):447–455CrossRef
Omastová M, Trchová M, Pionteck J, Prokes J, Stejskal J (2004) Effect of polymerization conditions on the properties of polypyrrole prepared in the presence of sodium bis (2-ethylhexyl) sulfosuccinate. Synth Met 143(2):153–161CrossRef
Pääkkö M, Ankerfors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Lindström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high pressure homogeneization for nanoscale cellulose fibrils and strong gels. Biomacromol 8(6):1934–1941CrossRef
Polprasert C (2007) Organic waste recycling: technology and management. IWA Publishing, London
Puls J, Schröder N, Stein A, Janzon R, Saake B (2005) Xylans from oat spelts and birch kraft pulp. Macromol Symp 232(1):85–92CrossRef
Rußler A, Sakakibara K, Rosenau T (2011) Cellulose as matrix component of conducting films. Cellulose 18(4):937–944CrossRef
Sasso C, Fenoll M, Stephan O, Beneventi D (2008) Use of wood derivatives as doping/dispersing agents in the preparation of polypyrrole aqueous dispersions. Bioresources 3(4):1187–1195
Sasso C, Beneventi D, Zeno E, Chaussy D, Petit-Conil M, Belgacem MN, Tapin-Lingua S (2010) Highly conducting polypyrrole/cellulose nanocomposite films with enhanced mechanical properties. Macromol Mat Eng 295(10):934–941CrossRef
Sasso C, Beneventi D, Zeno E, Chaussy D, Petit-Conil M, Belgacem MN (2011) Carboxymethylcellulose: a conductivity enhancer and film-forming agent for processable polypyrrole from aqueous medium. Synth Met 161(5–6):397–403CrossRef
Saxena A, Elder TJ, Pan S, Ragauskas AJ (2009) Novel nanocellulosic xylan composite film. Compos B Eng 40(8):727–730CrossRef
Schwikal K, Heinze T, Ebringerová A, Petzold K (2005) Cationic xylan derivatives with high degree of functionalization. Macromol Symp 232(1):49–56CrossRef
Shah J, Brown RM (2005) Towards electronic paper displays made from microbial cellulose. Appl Microbiol Biotech 66(4):352–355CrossRef
Shklovskii BI, Efros AL (1984) Electronic properties of doped semiconductors. Springer Series in Solid-State Sciences, Heidelberg
Sixta H (2011) Progress and challenges in the selective isolation of xylan from hardwood. 241st ACS National Meeting & Exposition, Anaheim, CA, United States, 27–31 March
Thiéblemont J, Gabelle J, Planche M (1994) Polypyrrole overoxidation during its chemical synthesis. Synth Met 66(3):243–247CrossRef
Timell TE (1967) Recent progress in the chemistry of wood hemicelluloses. Wood Sci Tech 1(1):45–70CrossRef
Wallberg O, Linde M, Jönsson A (2006) Extraction of lignin and hemicelluloses from kraft black liquor. Desalination 199(1–3):413–414CrossRef
Winther-Jensen B, Clark N, Subramanian P, Helmer R, Ashraf S, Wallace G, Spiccia L, MacFarlane DJ (2007) Application of polypyrrole to flexible substrates. J Appl Polym Sci 104(6):3938–3947CrossRef
Yang C, Liu P (2009) Water-dispersed conductive polypyrroles doped with lignosulfonate and the weak temperature dependence of electrical conductivity. Ind Eng Chem Res 48(21):9498–9503CrossRef
Yang R, Xu S, Wang Z, Yang W (2005) Aqueous extraction of corncob xylan and production of xylooligosaccharides. Food Sci Tech 38(6):677–682
Yeetsorn R, Fowler M, Tzoganakis C, Yuhua W, Taylor M (2008) Polypropylene composites for polymer electrolyte membrane fuel cell bipolar plates. Macromol Symp 264(1):34–43CrossRef
Metadaten
Titel
Polypyrrole (PPy) chemical synthesis with xylan in aqueous medium and production of highly conducting PPy/nanofibrillated cellulose films and coatings
verfasst von
Claudia Sasso
Nicolas Bruyant
Davide Beneventi
Jerôme Faure-Vincent
Elisa Zeno
Michel Petit-Conil
Didier Chaussy
Mohamed Naceur Belgacem
Publikationsdatum
01.12.2011
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 6/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-011-9583-2

Weitere Artikel der Ausgabe 6/2011

Cellulose 6/2011 Zur Ausgabe

OriginalPaper

Effect of CO2 laser treatment on cotton surface

OriginalPaper

Chromophores in cellulosics, VI. First isolation and identification of residual chromophores from aged cotton linters

OriginalPaper

An improved model for the kinetic description of the thermal degradation of cellulose

OriginalPaper

Polylysine coated bacterial cellulose nanofibers as novel templates for bone-like apatite deposition

OriginalPaper

Investigating adsorption of bovine serum albumin on cellulosic substrates using magnetic resonance imaging

OriginalPaper

Immobilization of lipase onto cellulose ultrafine fiber membrane for oil hydrolysis in high performance bioreactor