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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2017

16.09.2016 | Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Preparation and characterization of nanopowder nickel oxide/gadolinium-doped ceria via the sol-gel method by NiLH2 precursor

verfasst von: Somayeh Ghamari, Maryam Ranjbar, Masoomeh Nabitabar

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

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Abstract

In the present research two different kinds of nickel oxide/gadolinium-doped ceria (NiO–GDC) (I and II) nanocomposites were prepared by means of the sol-gel method. The Ni(II) complex (NiLH 2 ), [Ni(pydc)2·2(pyda·H)·2H2O], [pydc (2,6-Pyridinedicarboxylic acid), pyda (2,6-diaminopyridine)], and Ni(NO3)2·6H2O have been used as precursors. Characterization of the products was carried out by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray powder diffraction, zeta potential, thermogravimetric analysis, and nitrogen adsorption–desorption Brunauer, Emmett, and Teller measurements. The X-ray powder diffraction results showed that the crystal lattice of compound (I) was obtained as a cubic fluorite structure and was found to have an average crystalline size of 48–63 nm. The comparison of the zeta potential of compounds (I) and (II) has shown that compound (I) can carry a more positive charge and is almost stable. The scanning electron microscope and Brunauer, Emmett, and Teller analysis of compound (I) revealed large homogeneous agglomerated pores and surface area. The results show that if compound (I) is used in solid oxide fuel cells, it could be a suitable material for the anode of solid oxide fuel cells.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4182-1/MediaObjects/10971_2016_4182_Figa_HTML.gif
Vorheriger Artikel Preparation of surfactant-modified ZnTiO3–TiO2 nanostructures and their photocatalytic properties under sunlight irradiation
Nächster Artikel A new solid-phase microextraction fiber for separation and determination of methamphetamines in human urine using sol–gel technique

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Literatur
1.
Mahato N, Banerjee A, Gupta A, Omar S, Kantes B (2015) Progress in material selection for solid oxide fuel cell technology: a review. Prog Mater Sci 72:141–337CrossRef
2.
Salavati-Niasari M, Mohandes F, Davar F, Mazaheri M, Monemzadeh M, Yavarinia N (2009) Preparation of NiO nano particles from metal-organic frameworks via a solid-state decomposition route. Inorg Chim Acta 362:3691–3697CrossRef
3.
Gondal MA, Saleh TA, Drmosh QA (2012) Synthesis of nickel oxide nanoparticles using pulsed laser ablation in liquids and their optical characterization. Appl Surf Sci 258:6982–6986CrossRef
4.
Ghelich R, Keyanpour Rad Y, Yuzbashi AA, Khakpour Z (2012) Preparation and characterisation of NiO–Ce0.8Gd0.2O1.9 composite nanofibres via electrospinning. Electrochem Solid State Lett 7:1316–1319
5.
Jiang SP, Zhang S, Zhen YD, Koh AP (2004) Performance of GDC-Impregnated Ni Anodes of SOFCs. Electrochem Solid State Lett 7(9):A282–A285CrossRef
6.
Ghelich R, Keyanpour-Rad M, Youzbashi AA, Khakpour Z (2015) Comparative study on structural properties of NiO–GDC nanocomposites fabricated via electrospinning and gel combustion processes. Mater Res Innov 19:44–50CrossRef
7.
Lim C, Lee K (2016) Characterization of core-shell structured Ni@GDC anode materials synthesized by ultrasonic spray pyrolysis for solid oxide fuel cells. 42:13715–13722
8.
Nielsen J, Sudireddy BR, Hagen A, Hagen H (2016) Performance factors and sulfur tolerance of metal supported solid oxide fuel cells with nanostructured Ni:GDC infiltrated anodes. J Electrochem Soc 163(6):F574–F580CrossRef
9.
Müller G, Vannier R, Ringuedé A, Laberty-Robert C, Sanchez C (2013) Nanocrystalline, mesoporous NiO/Ce0.9Gd0.1O2_d thin films with tuned microstructures and electrical properties: in situ characterization of electrical responses during the reduction of NiO. J Mater Chem A 1:10753–10761CrossRef
10.
Gil V, Tartaj J, Moure C (2009) Chemical and thermomechanical compatibility between Ni–GDC anode and electrolytes based on ceria. Ceram Int 35:839–846CrossRef
11.
Prasad DH, Son J-W, Kim B-K, Lee H-W, Lee J-H (2008) Synthesis of nano-crystalline Ce0.9Gd0.1O1.95 electrolyte by novel sol–gel thermolysis process for IT-SOFCs. J Eur Ceram Soc 28:3107–3112CrossRef
12.
Ghelich R, Keyanpour Rad M, Youzbashi A (2015) Study on morphology and size distribution of electrospun NiO-GDC composite nanofibers. JEFF 10:12–19
13.
Chourashiya M, Jadhav L (2011) Synthesis and characterization of 10%Gd doped ceria (GDC) deposited on NiO-GDC anode-grade-ceramic substrate as half cell for IT-SOFC. Int J Hydrogen Energ 36:14984–14995CrossRef
14.
Zarkov A, Stanulis A, Salkus T, Kezionis A, Jasulaitiene A, Ramanauskas R, Tautkus S (2015) Synthesis of nanocrystalline gadolinium doped ceria via sol–gel combustion and sol–gel synthesis routes. Ceram Int 42: 3972–3988
15.
Martinez J, Meneses R, Silva C (2014) Synthesis of gadolinium doped ceria ceramic powder by polymeric precursor method (pechini). Mater Sci Forum 798–799:182–188CrossRef
16.
Brant M, Possa F, Lameiras F (2005) Ce0.8Gd0.2O1.9 powders synthesized by co-precipitation and amorphous citrate processes. Mater Sci Forum 498–499:624–629CrossRef
17.
Dikmen S, Shuk P, Greenblatt M, Gocmez H (2002) Hydrothermal synthesis and properties of Ce1−xGdxO2−δ solid solutions. Solid State Sci 4:585–590CrossRef
18.
Nagamori M, Shimonosono T, Sameshima S, Hirata Y, Matsunaga N, Sakka Y (2009) Densification and cell performance of gadolinium-doped ceria (GDC) electrolyte/NiO–GDC anode laminates. J Am Ceram Soc 92:S117–S121CrossRef
19.
Yoon D, Su Q, Wang H, Manthiram A (2013) Superior power density solid oxide fuel cells by enlarging the three-phase boundary region of a NiO–Ce0.8Gd0.2O1.9 composite anode through optimized surface structure. Phys Chem Chem 15:14966–14972CrossRef
20.
Misono T, Murata K, Yin J, Fukui T (2007) Morphology control of Ni-GDC cermet anode for lower temperature SOFC. ECS Trans 7(1):1355–1361CrossRef
21.
Moghimi A, Ranjbar M, Aghabozorg H, Jalali F, Shamsipur M, Yap GPA, Rahbarnoohi H (2002) A novel pyridine containing self- assembling system: synthesis, charactrization, X-ray crystal structure, 13C solid phase NMR and solution studies. J Mol Struct 605:133–149CrossRef
22.
Ranjbar M, Mozaffari SA, Kouhestanian E, Salaramoli H (2016) Sonochemical synthesis and characterization of a Zn(II) supramolecule, bis(2,6 diaminopyridinium)bis(pyridine-2,6-dicarboxylato)zincate(II), as a novel precursor for the ZnO-based dye sensitizer solar cell. J Photoch Photobio A 321:110–121CrossRef
23.
Ghorbanloo M, Ghamari S, Yahiro H (2015) Encapsulation of copper(II) complexes with three dentate NO2 ligands derived from 2,6-pyridinedicarboxylic acid in NaY zeolite. Turk J Chem 39:550–562CrossRef
24.
Jadhav LD, Pawar SH, Chourashiya MG (2007) Effect of sintering temperature on structural and electrical properties of gadolinium doped ceria (Ce0⋅9Gd0⋅1O1⋅95). Indian Acad Sci 30:97–100
25.
Fuentes RO, Baker RT (2008) Synthesis and properties of Gadolinium-doped ceria solid solutions for IT-SOFC electrolytes. Int J Hydrogen Energy 33:3480–3484CrossRef
26.
Júnior A, Baldo J (2014) The behavior of zeta potential of silica suspensions. New J Glass Ceram 4:29–37CrossRef
27.
Schartl W (2007) Light scattering from polymer solutions and nanoparticle dispersions. Springer, Berlin
28.
Sartor M, Dynamic light scattering to determine theradius of small beads in Brownian Motion in a solution. Departman of Physics, University of California, San Diego
29.
Pesora R (2000) Dynamic light scattering measurement of nanometer particles in liquids. J Nanopart Res 2:123–131CrossRef
30.
Tsay J, Fang T (1999) Effects of molar ratio of citric acid to cations and of pH value on the formation and thermal-decomposition behavior of barium titanium citrate. J Am Cera Soc 82:1409–1415CrossRef
31.
Arabacı A, Oksuzomer MFaruk (2012) Preparation and characterization of 10 mol %Gddoped CeO2 (GDC) electrolyte for SOFC applications. Ceram Int 38:6509–6515CrossRef
32.
Seok C, Moon J, Park M, Hong J, Kim H, Son J, Lee J, Kim B, Lee H and Yoon K (2015) Low-temperature co-sintering technique for the fabrication of multi-layer functional ceramics for solid oxide fuel cells. J Eur Ceram Soc 36:1417–1425
33.
Ng K, Lidiyawati S, Somalu M, Muchtar A, Rahman H (2016) Influence of calcination on the properties of nickel oxidesamarium doped ceria carbonate (NiO-SDCC) composite anodes. Procedia Chem 19:267–274CrossRef
34.
Suzuki T, Hasan Z, Funahashi Y, Yamaguchi T, Fujishiro Y, Awano M (2009) Impact of anode microstructure on solid oxide fuel cells. Science 325:852–855CrossRef
35.
Ding C, Lin H, Sato K, Kawada T, Mizusaki J, Hashida T (2010) Improvement of electrochemical performance of anode-supported SOFCs by NiO–Ce0.9Gd0.1O1.95 nanocomposite powders. Solid State Ionics 181:1238–1243CrossRef
36.
Chourashiya M, Bhardwaj S, Jadhav L (2010) Fabrication of 10%Gd-doped ceria (GDC)/NiO–GDC half cell for low or intermediate temperature solid oxide fuel cells using spray pyrolysis. J Solid State Electr 14:1868–1875CrossRef
Metadaten
Titel
Preparation and characterization of nanopowder nickel oxide/gadolinium-doped ceria via the sol-gel method by NiLH2 precursor
verfasst von
Somayeh Ghamari
Maryam Ranjbar
Masoomeh Nabitabar
Publikationsdatum
16.09.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4182-1

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