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Cellulose

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11.01.2022 | Original Research

Preparation of cellulose beads with high homogeneity, low crystallinity, and tunable internal structure

verfasst von: Yuanyuan Xia, Xinping Li, Yue Yuan, Jingshun Zhuang, Wenliang Wang

Erschienen in: Cellulose | Ausgabe 3/2022

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Abstract

The preparation of cellulose beads has attracted much attention in the application of advanced green materials. Herein, the uniform and controllable cellulose beads were prepared by first dissolving the pulp into N-methylmorpholine N-oxide (NMMO), and then regenerated in various coagulation baths (water, alcohol, acid, NMMO, etc.). Results showed that the crystalline structure of regenerated cellulose changed from cellulose I to cellulose II. Besides, the cellulose beads regenerated in Methanol (MT-cellulose bead) had the highest porosity (90.51%) and crystallinity (62.59%). Laser confocal microscopy was employed to reveal the coagulation mechanism of cellulose beads, and the solidification process was carried out from the inside to the outside. This is a green and facile method for preparing cellulose beads with different structures and properties that can be widely used in absorbent materials, energy storage materials, and protein chromatography.

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Vorheriger Artikel Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis

Nächster Artikel Highly acetylated lignocellulose prepared by alkaline extrusion pretreatment assisted acetylation reaction

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Titel: Preparation of cellulose beads with high homogeneity, low crystallinity, and tunable internal structure
verfasst von: Yuanyuan Xia
Xinping Li
Yue Yuan
Jingshun Zhuang
Wenliang Wang
Publikationsdatum: 11.01.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04413-5

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Abstract

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