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01.09.2015

Preparation of highly expanded graphene with large surface area and its additional conductive effect for EDLC performance

verfasst von: Kefayat Ullah, Ick-Jun Kim, Sun-hye Yang, Won-Chun Oh

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 9/2015

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Abstract

Expanded graphene (EG) has been produced using fast oxidation/intercalation process. The as prepared EG were then used as conductive additive to study the electrochemical properties of activated carbon based electric double layered supercapacitors (EDLCs). The physiochemical properties of EG were studied using scanning electron microscopy, Raman spectroscopic techniques, atomic force microscopy and energy dispersive X-ray analysis. The electrochemical properties were studied using charge/discharge cyclic voltammetry and electrochemical impedance spectroscopy. All the electrochemical tests were carried out in 1 M, TEA BF4 in acetonitrile as a suitable electrolyte for our AC based supercapacitors. Electrochemical test reveals that EG greatly affect the conductivity of the ions through the AC/EG interface. The specific capacitance remains the same for smaller values of EG in the composites electrodes. These results also evident the optimum loading of graphene in the future graphene based EDLCs.

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Literatur
1.
Zurück zum Zitat W. Chen, C. Xia, H.N. Alshareef, Graphene based integrated tandem supercapacitors fabricated directly on separators. Nano Energy 15, 1–8 (2015)CrossRef W. Chen, C. Xia, H.N. Alshareef, Graphene based integrated tandem supercapacitors fabricated directly on separators. Nano Energy 15, 1–8 (2015)CrossRef
2.
Zurück zum Zitat P.L. Huang, X.F. Luo, Y.Y. Peng, N.W. Pu, M.D. Ger, C.H. Yang, T.Y. Wud, J.K. Chang, Ionic liquid electrolytes with various constituent ions for graphene-based supercapacitors. Electrochim. Acta 161, 371–377 (2015)CrossRef P.L. Huang, X.F. Luo, Y.Y. Peng, N.W. Pu, M.D. Ger, C.H. Yang, T.Y. Wud, J.K. Chang, Ionic liquid electrolytes with various constituent ions for graphene-based supercapacitors. Electrochim. Acta 161, 371–377 (2015)CrossRef
3.
Zurück zum Zitat B. Dunn, H. Kamath, J.M. Tarascon, Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011)CrossRef B. Dunn, H. Kamath, J.M. Tarascon, Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011)CrossRef
4.
Zurück zum Zitat G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012)CrossRef G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012)CrossRef
5.
Zurück zum Zitat J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, Anomalous increase in carbon capacitance at pore size below 1 nm. Science 313, 1760–1763 (2006)CrossRef J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, Anomalous increase in carbon capacitance at pore size below 1 nm. Science 313, 1760–1763 (2006)CrossRef
6.
Zurück zum Zitat S.M. Saufi, A.F. Ismail, Fabrication of carbon membranes for gas separation, a review. Carbon 42, 241–259 (2004)CrossRef S.M. Saufi, A.F. Ismail, Fabrication of carbon membranes for gas separation, a review. Carbon 42, 241–259 (2004)CrossRef
7.
Zurück zum Zitat L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520 (2009)CrossRef L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520 (2009)CrossRef
8.
Zurück zum Zitat H. Pan, J. Li, Y. Feng, Carbon nanotubes for supercapacitor. Nanoscale Res. Lett. 5, 654–668 (2010)CrossRef H. Pan, J. Li, Y. Feng, Carbon nanotubes for supercapacitor. Nanoscale Res. Lett. 5, 654–668 (2010)CrossRef
9.
Zurück zum Zitat P. Hao, Z. Zhao, J. Tian, H. Li, Y. Sang, G. Yu, H. Cai, H. Liu, C.P. Wong, A. Umar, Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode. Nanoscale 6(20), 12120–121229 (2014)CrossRef P. Hao, Z. Zhao, J. Tian, H. Li, Y. Sang, G. Yu, H. Cai, H. Liu, C.P. Wong, A. Umar, Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode. Nanoscale 6(20), 12120–121229 (2014)CrossRef
10.
Zurück zum Zitat T. Cai, M. Zhou, D. Ren, G. Han, S. Guan, J. Power Sources 231, 197 (2013)CrossRef T. Cai, M. Zhou, D. Ren, G. Han, S. Guan, J. Power Sources 231, 197 (2013)CrossRef
11.
Zurück zum Zitat Y. Guo, Z.Q. Shi, M.M. Chen, C.Y. Wang, J. Power Sources 252, 235 (2014)CrossRef Y. Guo, Z.Q. Shi, M.M. Chen, C.Y. Wang, J. Power Sources 252, 235 (2014)CrossRef
12.
Zurück zum Zitat D. Choi, P.N. Kumta, Nanocrystalline tin derived by a two-step halide approach for electrochemical capacitors. J. Electrochem. Soc. 153, A2298–A2303 (2006)CrossRef D. Choi, P.N. Kumta, Nanocrystalline tin derived by a two-step halide approach for electrochemical capacitors. J. Electrochem. Soc. 153, A2298–A2303 (2006)CrossRef
13.
Zurück zum Zitat E. Frackowiak, S. Delpeux, K. Jurewicz, K. Szostak, D. Cazorla-Amoros, F. Beguin, Chem. Phys. Lett. 361, 35 (2002)CrossRef E. Frackowiak, S. Delpeux, K. Jurewicz, K. Szostak, D. Cazorla-Amoros, F. Beguin, Chem. Phys. Lett. 361, 35 (2002)CrossRef
14.
Zurück zum Zitat V. Ruiz, C. Blanco, E.R. Pinero, V. Khomenko, F. Beguin, R. Santamarı, Electrochim. Acta 52, 4969 (2007)CrossRef V. Ruiz, C. Blanco, E.R. Pinero, V. Khomenko, F. Beguin, R. Santamarı, Electrochim. Acta 52, 4969 (2007)CrossRef
15.
16.
17.
Zurück zum Zitat Y. Shao, M.F. El-Kady, L.J. Wang, Q. Zhang, Y. Li, H. Wang, M.F. Mousaviae, R.B. Kaner, Graphene-based materials for flexible supercapacitors. Chem. Soc. Rev. (2015). doi:10.1039/C4CS00316K. Review Article Y. Shao, M.F. El-Kady, L.J. Wang, Q. Zhang, Y. Li, H. Wang, M.F. Mousaviae, R.B. Kaner, Graphene-based materials for flexible supercapacitors. Chem. Soc. Rev. (2015). doi:10.​1039/​C4CS00316K. Review Article
18.
Zurück zum Zitat G. Yu, X. Xie, L. Pan, Z. Bao, Y. Cui, Hybrid nanostructured materials for high-performance electrochemical capacitors. Nano Energy 2, 213–234 (2013)CrossRef G. Yu, X. Xie, L. Pan, Z. Bao, Y. Cui, Hybrid nanostructured materials for high-performance electrochemical capacitors. Nano Energy 2, 213–234 (2013)CrossRef
19.
Zurück zum Zitat M. Armand, J.M. Tarascon, Building better batteries. Nature 451, 652–657 (2008)CrossRef M. Armand, J.M. Tarascon, Building better batteries. Nature 451, 652–657 (2008)CrossRef
20.
Zurück zum Zitat K. Wang, W.J. Zou, B.G. Quan, A.F. Yu, H.P. Wu, P. Jiang, Z.X. Wei, Adv. Energy Mater. 1, 1068–1072 (2011)CrossRef K. Wang, W.J. Zou, B.G. Quan, A.F. Yu, H.P. Wu, P. Jiang, Z.X. Wei, Adv. Energy Mater. 1, 1068–1072 (2011)CrossRef
21.
Zurück zum Zitat N. Kurra, N.A. Alhebshi, H.N. Alshareef, Adv. Energy Mater. 5, 1401303 (2015)CrossRef N. Kurra, N.A. Alhebshi, H.N. Alshareef, Adv. Energy Mater. 5, 1401303 (2015)CrossRef
22.
Zurück zum Zitat S. Zhou, H. Zhang, Q. Zhao, X. Wang, J. Li, F. Wang, Graphene-wrapped polyaniline nanofibers as electrode materials for organic supercapacitors. Carbon 52, 440–450 (2013)CrossRef S. Zhou, H. Zhang, Q. Zhao, X. Wang, J. Li, F. Wang, Graphene-wrapped polyaniline nanofibers as electrode materials for organic supercapacitors. Carbon 52, 440–450 (2013)CrossRef
23.
Zurück zum Zitat Q. Zhang, Y. Li, Y. Feng, W. Feng, Electropolymerization of graphene oxide/polyaniline composite for high-performance supercapacitor. Electrochim. Acta 90, 95–100 (2013)CrossRef Q. Zhang, Y. Li, Y. Feng, W. Feng, Electropolymerization of graphene oxide/polyaniline composite for high-performance supercapacitor. Electrochim. Acta 90, 95–100 (2013)CrossRef
24.
Zurück zum Zitat X.-M. Feng, R.-M. Li, Y.-W. Ma, R.-F. Chen, N.-E. Shi, Q.-L. Fan, W. Huang, Onestep electrochemical synthesis of graphene/polyaniline composite film and its applications. Adv. Funct. Mater. 21, 2989–2996 (2011)CrossRef X.-M. Feng, R.-M. Li, Y.-W. Ma, R.-F. Chen, N.-E. Shi, Q.-L. Fan, W. Huang, Onestep electrochemical synthesis of graphene/polyaniline composite film and its applications. Adv. Funct. Mater. 21, 2989–2996 (2011)CrossRef
25.
Zurück zum Zitat K. Ullah, S. Ye, S.-B. Jo, L. Zhu, K.-Y. Cho, W.-C. Oh, Optical and photocatalytic properties of novel heterogeneous PtSe2–graphene/TiO2 nanocomposites synthesized via ultrasonic assisted techniques. Ultrason Sonochem 21(5), 1849–1857 (2014)CrossRef K. Ullah, S. Ye, S.-B. Jo, L. Zhu, K.-Y. Cho, W.-C. Oh, Optical and photocatalytic properties of novel heterogeneous PtSe2–graphene/TiO2 nanocomposites synthesized via ultrasonic assisted techniques. Ultrason Sonochem 21(5), 1849–1857 (2014)CrossRef
26.
Zurück zum Zitat M.H. Pournaghi Azar, B. Habibi, Electropolymerization of aniline in acid media on the bare and chemically pre-treated aluminum electrodes: a comparative characterization of the polyaniline deposited electrodes. Electrochim. Acta 52, 4222–4230 (2007)CrossRef M.H. Pournaghi Azar, B. Habibi, Electropolymerization of aniline in acid media on the bare and chemically pre-treated aluminum electrodes: a comparative characterization of the polyaniline deposited electrodes. Electrochim. Acta 52, 4222–4230 (2007)CrossRef
27.
Zurück zum Zitat R.L. Hand, R.F. Nelson, Anodic oxidation pathways of N-alkylanilines. J. Am. Chem. Soc 96, 850–860 (1974)CrossRef R.L. Hand, R.F. Nelson, Anodic oxidation pathways of N-alkylanilines. J. Am. Chem. Soc 96, 850–860 (1974)CrossRef
28.
Zurück zum Zitat W.C. Chen, T.C. Wen, A. Gopalan, Negative capacitance for polyaniline: an analysis via electrochemical impedance spectroscopy. Synth. Met. 128, 179–189 (2002)CrossRef W.C. Chen, T.C. Wen, A. Gopalan, Negative capacitance for polyaniline: an analysis via electrochemical impedance spectroscopy. Synth. Met. 128, 179–189 (2002)CrossRef
29.
Zurück zum Zitat M.S. Dresselhaus, A. Jorio, M. Hofmann, G. Dresselhaus, R. Saito, Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett. 10, 751 (2010)CrossRef M.S. Dresselhaus, A. Jorio, M. Hofmann, G. Dresselhaus, R. Saito, Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett. 10, 751 (2010)CrossRef
30.
Zurück zum Zitat T. Huang, J. Long, M. Zhong, J. Jiang, X. Ye, Z. Lin, L. Li, The effects of low power density CO2 laser irradiation on graphene. Appl. Surf. Sci. 273, 502 (2013)CrossRef T. Huang, J. Long, M. Zhong, J. Jiang, X. Ye, Z. Lin, L. Li, The effects of low power density CO2 laser irradiation on graphene. Appl. Surf. Sci. 273, 502 (2013)CrossRef
31.
Zurück zum Zitat Y. Wang, Z.H. Ni, T. Yu, Z.X. Shen, H.M. Wang, Y.H. Wu, W. Chen, A.T.S. Wee, Raman studies of monolayer graphene: the substrate effect. J. Phys. Chem. C 112, 10637 (2008)CrossRef Y. Wang, Z.H. Ni, T. Yu, Z.X. Shen, H.M. Wang, Y.H. Wu, W. Chen, A.T.S. Wee, Raman studies of monolayer graphene: the substrate effect. J. Phys. Chem. C 112, 10637 (2008)CrossRef
32.
Zurück zum Zitat Kefayat Ullah, Zhu Lei, Shu Ye, Asghar Ali, Oh Won-Chun, Microwave synthesis of a CoSe2/graphene–TiO2 heterostructure for improved hydrogen evolution from aqueous solutions in the presence of sacrificial agents. RSC Adv. 5, 18841 (2015)CrossRef Kefayat Ullah, Zhu Lei, Shu Ye, Asghar Ali, Oh Won-Chun, Microwave synthesis of a CoSe2/graphene–TiO2 heterostructure for improved hydrogen evolution from aqueous solutions in the presence of sacrificial agents. RSC Adv. 5, 18841 (2015)CrossRef
33.
Zurück zum Zitat D. Pan, S. Wang, B. Zhao, M. Wu, H. Zhang, Y. Wang et al., Li storage properties of disordered graphene nanosheets. Chem. Mater. 21, 3136–3142 (2009)CrossRef D. Pan, S. Wang, B. Zhao, M. Wu, H. Zhang, Y. Wang et al., Li storage properties of disordered graphene nanosheets. Chem. Mater. 21, 3136–3142 (2009)CrossRef
34.
Zurück zum Zitat C. He, S.P. Jiang, P.K. Shen, Large-scale and rapid synthesis of disk-shaped and nano-sized graphene. Sci. Rep (2013). doi:10.1038/srep02144 C. He, S.P. Jiang, P.K. Shen, Large-scale and rapid synthesis of disk-shaped and nano-sized graphene. Sci. Rep (2013). doi:10.​1038/​srep02144
35.
Zurück zum Zitat W. Tang, L. Peng, C. Yuan, J. Wang, S. Mo, C. Zhao, Y. Youhai, Y. Min, A.J. Epstein, Facile synthesis of 3D reduced graphene oxide and its polyaniline composite for super capacitor application. Synth. Met. 202, 140–146 (2015)CrossRef W. Tang, L. Peng, C. Yuan, J. Wang, S. Mo, C. Zhao, Y. Youhai, Y. Min, A.J. Epstein, Facile synthesis of 3D reduced graphene oxide and its polyaniline composite for super capacitor application. Synth. Met. 202, 140–146 (2015)CrossRef
36.
Zurück zum Zitat L. Zhu, A. Ali, S. Ye, K. Ullah, C.S. Lim, W.C. Oh, Thermal and physical performance of heat sink for light-emitting diode improved with expanded graphite. Asian J. Chem. 27(6), 2298–2302 (2015)CrossRef L. Zhu, A. Ali, S. Ye, K. Ullah, C.S. Lim, W.C. Oh, Thermal and physical performance of heat sink for light-emitting diode improved with expanded graphite. Asian J. Chem. 27(6), 2298–2302 (2015)CrossRef
37.
Zurück zum Zitat J. Yun, D. Kim, G. Lee, J.S. Ha, All-solid-state flexible micro-supercapacitor arrays with patterned graphene/MWNT electrodes. Carbon 79, 156–164 (2014)CrossRef J. Yun, D. Kim, G. Lee, J.S. Ha, All-solid-state flexible micro-supercapacitor arrays with patterned graphene/MWNT electrodes. Carbon 79, 156–164 (2014)CrossRef
38.
Zurück zum Zitat H. Hamoudi, Carbon-metal nanosheets from the water-hexane interface. J. Mater. Chem. C 3(15), 3636–3644 (2015)CrossRef H. Hamoudi, Carbon-metal nanosheets from the water-hexane interface. J. Mater. Chem. C 3(15), 3636–3644 (2015)CrossRef
39.
Zurück zum Zitat D. Li, Y. Liu, B. Lin, Y. Sun, H. Yang, X. Zhang, Graphene/metal oxide composites as electrode material for supercapacitors. Prog. Chem. 27(4), 404–415 (2015) D. Li, Y. Liu, B. Lin, Y. Sun, H. Yang, X. Zhang, Graphene/metal oxide composites as electrode material for supercapacitors. Prog. Chem. 27(4), 404–415 (2015)
40.
Zurück zum Zitat S.M. Li, S.Y. Yang, Y.S. Wang, H.P. Tsai, H.W. Tien, S.T. Hsiao, W.H. Liao, C.L. Chang, C.C.M. Ma, C.C. Hu, N-doped structures and surface functional groups of reduced graphene oxide and their effect on the electrochemical performance of supercapacitor with organic electrolyte. J. Power Sources 278, 218–229 (2015)CrossRef S.M. Li, S.Y. Yang, Y.S. Wang, H.P. Tsai, H.W. Tien, S.T. Hsiao, W.H. Liao, C.L. Chang, C.C.M. Ma, C.C. Hu, N-doped structures and surface functional groups of reduced graphene oxide and their effect on the electrochemical performance of supercapacitor with organic electrolyte. J. Power Sources 278, 218–229 (2015)CrossRef
41.
Zurück zum Zitat H.S. Park, M.H. Lee, R.Y. Hwang, O.K. Park, K. Jo, T. Lee, B.S. Kim, H.K. Song, Kinetically enhanced pseudo capacitance of conducting polymer doped with reduced graphene oxide through a miscible electron transfer interface. Nano Energy 3, 1–9 (2014)CrossRef H.S. Park, M.H. Lee, R.Y. Hwang, O.K. Park, K. Jo, T. Lee, B.S. Kim, H.K. Song, Kinetically enhanced pseudo capacitance of conducting polymer doped with reduced graphene oxide through a miscible electron transfer interface. Nano Energy 3, 1–9 (2014)CrossRef
42.
Zurück zum Zitat X. Xiao, S. Li, H. Wei, D. Sun, Y. Wu, G. Jin, F. Wang, Y. Zou, Synthesis and characterization of VO2(B)/graphene nanocomposite for supercapacitors. J. Mater. Sci.: Mater. Electron. 26(6), 4226–4233 (2015) X. Xiao, S. Li, H. Wei, D. Sun, Y. Wu, G. Jin, F. Wang, Y. Zou, Synthesis and characterization of VO2(B)/graphene nanocomposite for supercapacitors. J. Mater. Sci.: Mater. Electron. 26(6), 4226–4233 (2015)
43.
Zurück zum Zitat G. Sun, B. Li, J. Ran, X. Shen, H. Tong, Three-dimensional hierarchical porous carbon/graphene composites derived from graphene oxide-chitosan hydrogels for high performance supercapacitors. Electrochim. Acta 171, 13–22 (2015)CrossRef G. Sun, B. Li, J. Ran, X. Shen, H. Tong, Three-dimensional hierarchical porous carbon/graphene composites derived from graphene oxide-chitosan hydrogels for high performance supercapacitors. Electrochim. Acta 171, 13–22 (2015)CrossRef
44.
Zurück zum Zitat K. Ullah, S. Ye, L. Zhu, S.G. Kim, B.J. Lee, E.H. Yoon, Y.R. Kim, B.S. Kim, W.C. Oh, Additional materials effect for improved electrochemical performance of activated carbon fiber based electric double layer capacitors. Asian J. Chem. 27(6), 2260–2266 (2015)CrossRef K. Ullah, S. Ye, L. Zhu, S.G. Kim, B.J. Lee, E.H. Yoon, Y.R. Kim, B.S. Kim, W.C. Oh, Additional materials effect for improved electrochemical performance of activated carbon fiber based electric double layer capacitors. Asian J. Chem. 27(6), 2260–2266 (2015)CrossRef
45.
Zurück zum Zitat A.I. Inamdar, Y.S. Kim, S.M. Pawar, J.H. Kim, H. Im, H. Kim, Chemically grown, porous, nickel oxide thin-film for electrochemical supercapacitors. J. Power Sources 196(4), 2393–2397 (2011)CrossRef A.I. Inamdar, Y.S. Kim, S.M. Pawar, J.H. Kim, H. Im, H. Kim, Chemically grown, porous, nickel oxide thin-film for electrochemical supercapacitors. J. Power Sources 196(4), 2393–2397 (2011)CrossRef
Metadaten
Titel
Preparation of highly expanded graphene with large surface area and its additional conductive effect for EDLC performance
verfasst von
Kefayat Ullah
Ick-Jun Kim
Sun-hye Yang
Won-Chun Oh
Publikationsdatum
01.09.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 9/2015
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-3313-8

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