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Journal of Materials Science

Erschienen in:

29.10.2020 | Chemical routes to materials

Preparation of nano Fe₃O₄ pigment using CO₃²⁻/HCO₃⁻ as precipitant and DFT study on the formation process of its intermediate product FeOOH

verfasst von: Lingyun Cao, Jian Hu, Lei Zhang, Hongbin Zhao, Lijuan Liu

Erschienen in: Journal of Materials Science | Ausgabe 5/2021

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Abstract

The nano Fe₃O₄ pigment was prepared with a precipitation method using the carbonate/bicarbonate as precipitant. The chemical structure, crystal phase and morphology of prepared pigment samples were determined by fourier transform infrared spectroscopy (FT-IR), X-ray diffraction spectrometer (XRD), transmission electron microscope (TEM), high-resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED), and its color performance was tested. The results showed that the prepared pigment sample showed high purity and excellent crystallinity of bulk Fe₃O₄, and better black property (L^* = 35.51) than the commercially available standard pigment sample. The characterization results of pigment samples obtained under different preparation parameters showed that the precipitant reaction temperature and reaction time showed obvious effect on the morphology, crystallization degree and color performance of prepared nano Fe₃O₄ pigment. In addition, it was found that the FeOOH was the intermediate product. The density functional theory (DFT) calculation results revealed that the generation of FeOOH was realized through a series of reaction steps including dehydrogenative oxidation, dehydration, and dimerization, in which the FeCO₃ instead of the Fe(OH)₂ was served as the initial phase of Fe(II) compounds.

Vorheriger Artikel Starting monomer of graphdiyne–hexakis[(trimethylsilyl)ethynyl]benzene: a superior nonlinear absorption material

Nächster Artikel Thermal oxidation of graphite as the first step for graphene preparation: effect of heating temperature and time

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Titel: Preparation of nano Fe3O4 pigment using CO32−/HCO3− as precipitant and DFT study on the formation process of its intermediate product FeOOH
verfasst von: Lingyun Cao
Jian Hu
Lei Zhang
Hongbin Zhao
Lijuan Liu
Publikationsdatum: 29.10.2020
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 5/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-05477-7

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