Skip to main content
Erschienen in: Clean Technologies and Environmental Policy 6/2015

01.08.2015 | Original Paper

Primary sewage sludge-derived activated carbon: characterisation and application in wastewater treatment

verfasst von: Anirudh Gupta, Anurag Garg

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 6/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The present study deals with the characterization of primary sewage sludge-derived activated carbons which were used for phenol adsorption from the synthetic wastewater. The waste-derived adsorbents were prepared by a two-step process: chemical activation (with ZnCl2 and KOH) followed by pyrolysis. The mesoporous adsorbents were found to have BET surface area comparable to commercial activated carbon (surface area = 495–515 m2/g). The adsorption runs were performed in orbital shaker with synthetic phenolic wastewater (phenol concentration = 50–250 mg/L) to investigate the effect of various reaction parameters. The equilibrium phenol adsorption data could be described by Redlich–Peterson isotherm model and the pseudo first-order kinetic model exhibited the best fit to time-based adsorption data. The phenol adsorption was endothermic for all adsorbents. The performance of the thermally regenerated waste-derived adsorbents in the wastewater treatment was found to reduce significantly.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
Zurück zum Zitat Albadarin AB, Mangwandi C, Al-Muhtaseb AH, Walker GM, Allen SJ, Ahmad MNM (2012) Kinetics and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent. Chem Eng J 179:193–202CrossRef Albadarin AB, Mangwandi C, Al-Muhtaseb AH, Walker GM, Allen SJ, Ahmad MNM (2012) Kinetics and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent. Chem Eng J 179:193–202CrossRef
Zurück zum Zitat Amin MN, Mustafa AI, Khalil MI, Rahman M, Nahid I (2012) Adsorption of phenol onto rice straw biowaste for water purification. Clean Technol Environ Policy 14:837–844CrossRef Amin MN, Mustafa AI, Khalil MI, Rahman M, Nahid I (2012) Adsorption of phenol onto rice straw biowaste for water purification. Clean Technol Environ Policy 14:837–844CrossRef
Zurück zum Zitat Boualem T, Debab A, Yuso AM, Izquierdo MT (2014) Activated carbons obtained from sewage sludge by chemical activation: gas-phase environmental applications. J Environ Manage 140:145–151CrossRef Boualem T, Debab A, Yuso AM, Izquierdo MT (2014) Activated carbons obtained from sewage sludge by chemical activation: gas-phase environmental applications. J Environ Manage 140:145–151CrossRef
Zurück zum Zitat Boyd GE, Adamson AW, Myers LS (1947) The exchange adsorption of ions from aqueous solutions by organic zeolites: kinetics. J Am Chem Soc 69:2836–2848CrossRef Boyd GE, Adamson AW, Myers LS (1947) The exchange adsorption of ions from aqueous solutions by organic zeolites: kinetics. J Am Chem Soc 69:2836–2848CrossRef
Zurück zum Zitat Foo KY, Hameed BH (2010) Insights into the modelling of adsorption isotherm systems. Chem Eng J 156:2–10CrossRef Foo KY, Hameed BH (2010) Insights into the modelling of adsorption isotherm systems. Chem Eng J 156:2–10CrossRef
Zurück zum Zitat Gupta A, Garg A (2013) Removal of ciprofloxacin by sewage sludge based activated carbon. Int J Appl Eng Res 8:1879–1884 Gupta A, Garg A (2013) Removal of ciprofloxacin by sewage sludge based activated carbon. Int J Appl Eng Res 8:1879–1884
Zurück zum Zitat Ho YS (2004) Selection of optimum sorption isotherm. Carbon 42:2113–2130CrossRef Ho YS (2004) Selection of optimum sorption isotherm. Carbon 42:2113–2130CrossRef
Zurück zum Zitat Jung DH, Chun YN (2009) Characteristics on carbonization and steam activation of sewage sludge. Open Process Chem J 2:12–19CrossRef Jung DH, Chun YN (2009) Characteristics on carbonization and steam activation of sewage sludge. Open Process Chem J 2:12–19CrossRef
Zurück zum Zitat Khan AA, Singh RP (1987) Adsorption thermodynamics of carbofuran on Sn(IV) arsenosilicate in H+, Na+ and Ca2+ forms. Colloids Surf A 24:33–42CrossRef Khan AA, Singh RP (1987) Adsorption thermodynamics of carbofuran on Sn(IV) arsenosilicate in H+, Na+ and Ca2+ forms. Colloids Surf A 24:33–42CrossRef
Zurück zum Zitat Li D, Wu Y, Feng L, Zhang L (2012) Surface properties of SAC and its adsorption mechanisms for phenol and nitrobenzene. Bioresour Technol 113:121–126CrossRef Li D, Wu Y, Feng L, Zhang L (2012) Surface properties of SAC and its adsorption mechanisms for phenol and nitrobenzene. Bioresour Technol 113:121–126CrossRef
Zurück zum Zitat Lin QH, Cheng H, Chen GY (2012) Preparation and characterization of carbonaceous adsorbents from sewage sludge using a pilot-scale microwave heating equipment. J Anal Appl Pyrolysis 93:113–119CrossRef Lin QH, Cheng H, Chen GY (2012) Preparation and characterization of carbonaceous adsorbents from sewage sludge using a pilot-scale microwave heating equipment. J Anal Appl Pyrolysis 93:113–119CrossRef
Zurück zum Zitat Martin MJ, Artola A, Balaguer MD, Rigola M (2003) Activated carbons developed from surplus sewage sludge for the removal of dyes from dilute aqueous solutions. Chem Eng J 94:231–239CrossRef Martin MJ, Artola A, Balaguer MD, Rigola M (2003) Activated carbons developed from surplus sewage sludge for the removal of dyes from dilute aqueous solutions. Chem Eng J 94:231–239CrossRef
Zurück zum Zitat Mattson JS, Mark HB Jr, Malbin MD, Weber WJ Jr, Crittenden JC (1969) Surface chemistry of active carbon: specific adsorption of phenols. J Colloid Interface Sci 31:116–130CrossRef Mattson JS, Mark HB Jr, Malbin MD, Weber WJ Jr, Crittenden JC (1969) Surface chemistry of active carbon: specific adsorption of phenols. J Colloid Interface Sci 31:116–130CrossRef
Zurück zum Zitat Merrikpour H, Jalali M (2012) Waste calcite sludge as an adsorbent for the removal of cadmium, copper, lead and zinc from aqueous solutions. Clean Technol Environ Policy 14:845–855CrossRef Merrikpour H, Jalali M (2012) Waste calcite sludge as an adsorbent for the removal of cadmium, copper, lead and zinc from aqueous solutions. Clean Technol Environ Policy 14:845–855CrossRef
Zurück zum Zitat Mohan D, Pittman CU Jr (2007) Arsenic removal from water/wastewater using adsorbents—a critical review. J Hazard Mater 142:1–53CrossRef Mohan D, Pittman CU Jr (2007) Arsenic removal from water/wastewater using adsorbents—a critical review. J Hazard Mater 142:1–53CrossRef
Zurück zum Zitat Mohan D, Sarswat A, Singh VK, Alexandre-Franco M, Pittman CU Jr (2011) Development of magnetic activated carbon from almond shells for trinitrophenol removal from water. Chem Eng J 172:1111–1125CrossRef Mohan D, Sarswat A, Singh VK, Alexandre-Franco M, Pittman CU Jr (2011) Development of magnetic activated carbon from almond shells for trinitrophenol removal from water. Chem Eng J 172:1111–1125CrossRef
Zurück zum Zitat Monsalvo VM, Mohedano AF, Rodriguez JJ (2011) Activated carbons from sewage sludge: application to aqueous-phase adsorption of 4-chlorophenol. Desalination 277:377–382CrossRef Monsalvo VM, Mohedano AF, Rodriguez JJ (2011) Activated carbons from sewage sludge: application to aqueous-phase adsorption of 4-chlorophenol. Desalination 277:377–382CrossRef
Zurück zum Zitat Nethaji S, Sivasamy A (2014) Removal of hexavalent chromium from aqueous solution using activated carbon prepared from walnut shell biomass through alkali impregnation processes. Clean Technol Environ Policy 16:361–368CrossRef Nethaji S, Sivasamy A (2014) Removal of hexavalent chromium from aqueous solution using activated carbon prepared from walnut shell biomass through alkali impregnation processes. Clean Technol Environ Policy 16:361–368CrossRef
Zurück zum Zitat Orfao JJM, Silva AIM, Pereira JCV, Barata SA, Fonseca IM, Faria PCC, Pereira MFR (2006) Adsorption of reactive dye on chemically modified activated carbon-influence of pH. J Colloid Interface Sci 296:480–489CrossRef Orfao JJM, Silva AIM, Pereira JCV, Barata SA, Fonseca IM, Faria PCC, Pereira MFR (2006) Adsorption of reactive dye on chemically modified activated carbon-influence of pH. J Colloid Interface Sci 296:480–489CrossRef
Zurück zum Zitat Otero M, Rozada F, Calvo LF, Garcia AI, Moran A (2003) Elimination of organic water pollutants using adsorbents obtained from sewage sludge. Dyes Pigments 57:55–65CrossRef Otero M, Rozada F, Calvo LF, Garcia AI, Moran A (2003) Elimination of organic water pollutants using adsorbents obtained from sewage sludge. Dyes Pigments 57:55–65CrossRef
Zurück zum Zitat Ping F, Chaoping C, Dingsheng C, Zhixiong T (2010) Carbonaceous adsorbents prepared from sewage sludge and its application for (Hg) adsorption in simulated Flue gas. Chin J Chem Eng 18:231–238CrossRef Ping F, Chaoping C, Dingsheng C, Zhixiong T (2010) Carbonaceous adsorbents prepared from sewage sludge and its application for (Hg) adsorption in simulated Flue gas. Chin J Chem Eng 18:231–238CrossRef
Zurück zum Zitat Przepiorski J (2006) Enhanced adsorption of phenol from water by ammonia-treated activated carbon. J Hazard Mater 135:453–456CrossRef Przepiorski J (2006) Enhanced adsorption of phenol from water by ammonia-treated activated carbon. J Hazard Mater 135:453–456CrossRef
Zurück zum Zitat Reddy KSK, Shoaibi AA, Srinivasakannan C (2014) Impact of process conditions on preparation of porous carbon from date palm seeds by KOH activation. Clean Technol Environ Policy. doi:10.1007/s10098-014-0875-8 Reddy KSK, Shoaibi AA, Srinivasakannan C (2014) Impact of process conditions on preparation of porous carbon from date palm seeds by KOH activation. Clean Technol Environ Policy. doi:10.​1007/​s10098-014-0875-8
Zurück zum Zitat Ros A, Lillo-Rodenas MA, Fuente E, Montes-Moran MA, Martin MJ, Linares-Solano A (2006) High surface area materials prepared from sewage sludge-based precursors. Chemosphere 65:132–140CrossRef Ros A, Lillo-Rodenas MA, Fuente E, Montes-Moran MA, Martin MJ, Linares-Solano A (2006) High surface area materials prepared from sewage sludge-based precursors. Chemosphere 65:132–140CrossRef
Zurück zum Zitat Rozada F, Otero M, Garcia AI, Moran I (2007) Application in fixed-bed systems of adsorbents obtained from sewage sludge and discarded tyres. Dyes Pigments 72:47–56CrossRef Rozada F, Otero M, Garcia AI, Moran I (2007) Application in fixed-bed systems of adsorbents obtained from sewage sludge and discarded tyres. Dyes Pigments 72:47–56CrossRef
Zurück zum Zitat Sabio E, Gonzalez E, Gonzalez JF, Gonzalez-Garcia CM, Ramiro A, Ganan J (2004) Thermal regeneration of activated carbon saturated with p-nitrophenol. Carbon 42:2285–2293CrossRef Sabio E, Gonzalez E, Gonzalez JF, Gonzalez-Garcia CM, Ramiro A, Ganan J (2004) Thermal regeneration of activated carbon saturated with p-nitrophenol. Carbon 42:2285–2293CrossRef
Zurück zum Zitat Seredych M, Bandosz TJ (2006) Removal of copper on composite sewage sludge/industrial sludge-based adsorbents: the role of surface chemistry. J Colloid Interface Sci 302:379–388CrossRef Seredych M, Bandosz TJ (2006) Removal of copper on composite sewage sludge/industrial sludge-based adsorbents: the role of surface chemistry. J Colloid Interface Sci 302:379–388CrossRef
Zurück zum Zitat Smith KM, Fowler GD, Pulket S, Graham NJD (2009) Sewage sludge-based adsorbents: A review of their production, properties and use in water treatment applications. Water Res 43:2569–2594CrossRef Smith KM, Fowler GD, Pulket S, Graham NJD (2009) Sewage sludge-based adsorbents: A review of their production, properties and use in water treatment applications. Water Res 43:2569–2594CrossRef
Zurück zum Zitat Snoeyink VL, Weber WJ Jr, Mark HB (1969) Sorption of phenol and nitrophenol by active carbon. Environ Sci Technol 3:918–926CrossRef Snoeyink VL, Weber WJ Jr, Mark HB (1969) Sorption of phenol and nitrophenol by active carbon. Environ Sci Technol 3:918–926CrossRef
Zurück zum Zitat Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM (2006) Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloids Surf A 272:89–104CrossRef Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM (2006) Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloids Surf A 272:89–104CrossRef
Zurück zum Zitat Tay JH, Chen XG, Jayseelan S, Graham N (2001) A comparative study of anaerobically digested and undigested sewage sludges in preparation of activated carbons. Chemosphere 44:53–57CrossRef Tay JH, Chen XG, Jayseelan S, Graham N (2001) A comparative study of anaerobically digested and undigested sewage sludges in preparation of activated carbons. Chemosphere 44:53–57CrossRef
Zurück zum Zitat Wang X, Zhu N, Yin B (2008) Preparation of sludge-based activated carbon and its application in dye wastewater treatment. J Hazard Mater 153:22–27CrossRef Wang X, Zhu N, Yin B (2008) Preparation of sludge-based activated carbon and its application in dye wastewater treatment. J Hazard Mater 153:22–27CrossRef
Zurück zum Zitat Weber WJ, Morris JC (1962) Advances in water pollution research: removal of biologically resistant pollutant from waste water by adsorption. In: Proceedings of international conference on water pollution symposium, vol 2. Permagon Press, New York, pp 231–262 Weber WJ, Morris JC (1962) Advances in water pollution research: removal of biologically resistant pollutant from waste water by adsorption. In: Proceedings of international conference on water pollution symposium, vol 2. Permagon Press, New York, pp 231–262
Zurück zum Zitat Wen Q, Li C, Cai Z, Zhang W, Gao H, Chen L, Zeng G, Shu X, Zhao Y (2011) Study on activated carbon from sewage sludge for adsorption of gaseous formaldehyde. Bioresour Technol 102:942–947CrossRef Wen Q, Li C, Cai Z, Zhang W, Gao H, Chen L, Zeng G, Shu X, Zhao Y (2011) Study on activated carbon from sewage sludge for adsorption of gaseous formaldehyde. Bioresour Technol 102:942–947CrossRef
Zurück zum Zitat Yu L, Zhong Q (2006) Preparation of adsorbents made from sewage sludges for adsorption of organic materials from wastewater. J Hazard Mater 137:359–366CrossRef Yu L, Zhong Q (2006) Preparation of adsorbents made from sewage sludges for adsorption of organic materials from wastewater. J Hazard Mater 137:359–366CrossRef
Zurück zum Zitat Zhuang H, Han H, Hou B, Jia S, Zhao Q (2014) Heterogenous catalytic ozonation of biologically treated Lurgi coal gasification wastewater using sewage sludge based activated carbon supported manganese and ferric oxides as catalysts. Bioresour Technol 166:178–186CrossRef Zhuang H, Han H, Hou B, Jia S, Zhao Q (2014) Heterogenous catalytic ozonation of biologically treated Lurgi coal gasification wastewater using sewage sludge based activated carbon supported manganese and ferric oxides as catalysts. Bioresour Technol 166:178–186CrossRef
Metadaten
Titel
Primary sewage sludge-derived activated carbon: characterisation and application in wastewater treatment
verfasst von
Anirudh Gupta
Anurag Garg
Publikationsdatum
01.08.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Clean Technologies and Environmental Policy / Ausgabe 6/2015
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-014-0895-4

Weitere Artikel der Ausgabe 6/2015

Clean Technologies and Environmental Policy 6/2015 Zur Ausgabe