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Erschienen in:
1991 | OriginalPaper | Buchkapitel
Processes on a Real Surface
verfasst von : T. Wolkenstein
Erschienen in: Electronic Processes on Semiconductor Surfaces during Chemisorption
Verlag: Springer US
Enthalten in: Professional Book Archive
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As we know, the regularities in adsorption observed experimentally often deviate from those predicted by the classical Langmuir theory of adsorption. These deviations, which also arise both in adsorption kinetics and in adsorption equilibrium (non-Langmuir isotherms and the dependence of the differential adsorption heat on surface coverage), indicate the violation of one or more of the initial assumptions unnderlying Langmuir’s theory.