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2020 | OriginalPaper | Buchkapitel

Prototypes of Molecular Gears with an Organometallic Piano-Stool Architecture

verfasst von : Seifallah Abid, Guillaume Erbland, Claire Kammerer, Gwénaël Rapenne

Erschienen in: Building and Probing Small for Mechanics

Verlag: Springer International Publishing

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Abstract

In the field of Molecular Machines, molecular gears have mainly been synthesized to be studied in solution. Then, the cogwheel subunits are restricted to be only arranged in an intramolecular manner. In the last years, the possibility to arrange a train of gears at the single molecular level and observe the propagation of a rotation motion from one molecule to its neighbor using Scanning Tunneling Microscopy (STM) opened new perspectives with the opportunity to have intermolecular arrangements on surfaces. In this chapter, we describe the research background of single molecular gears and our strategy using organometallic piano-stool complexes to anchor such gears on surfaces. Our molecules incorporate two subunits linked together through a ruthenium center acting as a ball bearing. The lower part is the anchoring tripodal ligand and the upper part the cogwheel. Various functionalities have been explored to behave as teeth, ranging from mono-dimensional phenyl rings to bi-dimensional porphyrin fragments.

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Titel: Prototypes of Molecular Gears with an Organometallic Piano-Stool Architecture
verfasst von: Seifallah Abid
Guillaume Erbland
Claire Kammerer
Gwénaël Rapenne
Verlag: Springer International Publishing
Buch: Building and Probing Small for Mechanics
Print ISBN: 978-3-030-56776-7

Electronic ISBN: 978-3-030-56777-4

Copyright-Jahr: 2020
DOI: https://doi.org/10.1007/978-3-030-56777-4_5

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