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Cellulose

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12.05.2016 | Original Paper

Recyclable and transparent bacterial cellulose/hemiaminal dynamic covalent network polymer nanocomposite films

Erschienen in: Cellulose | Ausgabe 4/2016

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Abstract

Recyclable and transparent nanocomposite films based on bacterial cellulose (BC) and hemiaminal dynamic covalent network polymer (HDCN) have been synthesized by in situ polymerization of 4,4′-diaminodiphenyl ether (ODA) with paraformaldehyde. Transparency and structural and mechanical properties of such nanocomposite films are investigated. It was found that BC/HDCN nanocomposite films exhibits a high optical transparency (86 % at 550 nm). Scanning electron microscopy reveals excellent compatibility of the reinforcement of BC nanofibers and HDCN matrix, which leads to the improvement of 20 and 200 % in tensile strength and storage modulus, respectively, as compared to neat HDCN films. BC hydrogels are readily recoverable from nanocomposite films by the sulphuric acid treatment and ODA monomer is deposited and also recycled.

Vorheriger Artikel Morphology and rheology of cellulose nanofibrils derived from mixtures of pulp fibres and papermaking fines

Nächster Artikel New insights into the material chemistry of polycaprolactone-grafted cellulose nanofibrils/polyurethane nanocomposites

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Araki J, Kuga S (2001) Effect of trace electrolyte on liquid crystal type of cellulose microcrystals. Langmuir 17:4493–4496. doi:10.1021/la0102455 CrossRef

Bäckdahl H, Helenius G, Bodin A, Nannmark U, Johansson BR, Risberg B, Gatenholm P (2006) Mechanical properties of bacterial cellulose and interactions with smooth muscle cells. Biomaterials 27:2141–2149. doi:10.1016/j.biomaterials.2005.10.026 CrossRef

Barud HS, Regiani T, Marques RFC, Lustri WR, Messaddeq Y, Ribeiro SJL (2011) Antimicrobial bacterial cellulose-silver nanoparticles composite membranes. J Nanomater 2011:1–8. doi:10.1155/2011/721631 CrossRef

Barud HS, Ribeiro SJL, Carone CLP et al (2013) Optically transparent membrane based on bacterial cellulose/polycaprolactone. Polímeros 23:135–142. doi:10.1590/S0104-14282013005000018

Czaja W, Romanovicz D, Rm Brown (2004) Structural investigations of microbial cellulose produced in stationary and agitated culture. Cellulose 11:403–411. doi:10.1023/B:CELL.0000046412.11983.61 CrossRef

Feng Y, Zhang X, Shen Y, Yoshino K, Feng W (2012) A mechanically strong, flexible and conductive film based on bacterial cellulose/graphene nanocomposite. Carbohydr Polym 87:644–649. doi:10.1016/j.carbpol.2011.08.039 CrossRef

Fernandes SCM, Oliveira L, Freire CSR, Silvestre AJD, Neto CP, Gandini A, Desbrieres J (2009) Novel transparent nanocomposite films based on chitosan and bacterial cellulose. Green Chem 11:2023–2029. doi:10.1039/B919112G CrossRef

García JM, Jones GO, Virwani K et al (2014) Recyclable, strong thermosets and organogels via paraformaldehyde condensation with diamines. Science 344:732–735. doi:10.1126/science.1251484 CrossRef

Gindl W, Keckes J (2004) Tensile properties of cellulose acetate butyrate composites reinforced with bacterial cellulose. Compos Sci Technol 64:2407–2413. doi:10.1016/j.compscitech.2004.05.001 CrossRef

Hirai A, Inui O, Horii F, Tsuji M (2009) Phase separation behavior in aqueous suspensions of bacterial cellulose nanocrystals prepared by sulfuric acid treatment. Langmuir 25:497–502. doi:10.1021/la802947m CrossRef

Jones GO, García JM, Horn HW, Hedrick JL (2014) Computational and experimental studies on the mechanism of formation of poly(hexahydrotriazine)s and poly(hemiaminal)s from the reactions of amines with formaldehyde. Org Lett 16:5502–5505. doi:10.1021/ol502840k CrossRef

Kim Y, Jung R, Kim H-S, Jin H-J (2009) Transparent nanocomposites prepared by incorporating microbial nanofibrils into poly(l-lactic acid). Curr Appl Phys 9:S69–S71. doi:10.1016/j.cap.2008.08.010 CrossRef

Kramer F, Klemm D, Schumann D, Heßler N, Wesarg F, Fried W, Stadermann D (2006) Nanocellulose polymer composites as innovative pool for (Bio)material development. Macromol Symp 244:136–148. doi:10.1002/masy.200651213 CrossRef

Lee K-Y, Bismarck A (2012) Susceptibility of never-dried and freeze-dried bacterial cellulose towards esterification with organic acid. Cellulose 19:891–900. doi:10.1007/s10570-012-9680-x CrossRef

Marins J, Soares B, Dahmouche K, Ribeiro SL, Barud H, Bonemer D (2011) Structure and properties of conducting bacterial cellulose-polyaniline nanocomposites. Cellulose 18:1285–1294. doi:10.1007/s10570-011-9565-4 CrossRef

Martínez-Sanz M, Olsson R, Lopez-Rubio A, Lagaron J (2011) Development of electrospun EVOH fibres reinforced with bacterial cellulose nanowhiskers. Part I: characterization and method optimization. Cellulose 18:335–347. doi:10.1007/s10570-010-9471-1 CrossRef

Martins IMG, Magina SP, Oliveira L, Freire CSR, Silvestre AJD, Neto CP, Gandini A (2009) New biocomposites based on thermoplastic starch and bacterial cellulose. Compos Sci Technol 69:2163–2168. doi:10.1016/j.compscitech.2009.05.012 CrossRef

Müller D, Rambo CR, Recouvreux DOS, Porto LM, Barra GMO (2011) Chemical in situ polymerization of polypyrrole on bacterial cellulose nanofibers. Synth Met 161:106–111. doi:10.1016/j.synthmet.2010.11.005 CrossRef

Nakagaito AN, Iwamoto S, Yano H (2005) Bacterial cellulose: the ultimate nano-scalar cellulose morphology for the production of high-strength composites. Appl Phys A 80:93–97. doi:10.1007/s00339-004-2932-3 CrossRef

Nakayama A, Kakugo A, Gong JP, Osada Y, Takai M, Erata T, Kawano S (2004) High mechanical strength double-network hydrogel with bacterial cellulose. Adv Funct Mater 14:1124–1128. doi:10.1002/adfm.200305197 CrossRef

Nogi M, Yano H (2008) Transparent nanocomposites based on cellulose produced by bacteria offer potential innovation in the electronics device industry. Adv Mater 20:1849–1852. doi:10.1002/adma.200702559 CrossRef

Nogi M, Handa K, Nakagaito AN, Yano H (2005) Optically transparent bionanofiber composites with low sensitivity to refractive index of the polymer matrix. Appl Phys Lett 87:243110. doi:10.1063/1.2146056 CrossRef

Pinto EP, Barud H, Polito W, Ribeiro SL, Messaddeq Y (2013) Preparation and characterization of the bacterial cellulose/polyurethane nanocomposites. J Therm Anal Calorim 114:549–555. doi:10.1007/s10973-013-3001-y CrossRef

Quero F, Nogi M, Yano H, Abdulsalami K, Holmes SM, Sakakini BH, Eichhorn SJ (2010) Optimization of the mechanical performance of bacterial cellulose/poly(l-lactic) acid composites. ACS Appl Mater Interfaces 2:321–330. doi:10.1021/am900817f CrossRef

Trovatti E, Oliveira L, Freire CSR, Silvestre AJD, Pascoal Neto C, Cruz Pinto JJC, Gandini A (2010) Novel bacterial cellulose–acrylic resin nanocomposites. Compos Sci Technol 70:1148–1153. doi:10.1016/j.compscitech.2010.02.031 CrossRef

Wan YZ, Luo H, He F, Liang H, Huang Y, Li XL (2009) Mechanical, moisture absorption, and biodegradation behaviours of bacterial cellulose fibre-reinforced starch biocomposites. Compos Sci Technol 69:1212–1217. doi:10.1016/j.compscitech.2009.02.024 CrossRef

Yeh JT, Tsai CC, Wang CK, Shao JW, Xiao MZ, Chen SC (2014) Ultradrawing novel ultra-high molecular weight polyethylene fibers filled with bacterial cellulose nanofibers. Carbohydr Polym 101:1–10. doi:10.1016/j.carbpol.2013.08.034 CrossRef

Yoon SH, Jin H-J, Kook M-C, Pyun YR (2006) Electrically conductive bacterial cellulose by incorporation of carbon nanotubes. Biomacromolecules 7:1280–1284. doi:10.1021/bm050597g CrossRef

Zhijiang C, Guang Y (2011) Optical nanocomposites prepared by incorporating bacterial cellulose nanofibrils into poly(3-hydroxybutyrate). Mater Lett 65:182–184. doi:10.1016/j.matlet.2010.09.055 CrossRef

Titel: Recyclable and transparent bacterial cellulose/hemiaminal dynamic covalent network polymer nanocomposite films
Publikationsdatum: 12.05.2016
Erschienen in: Cellulose / Ausgabe 4/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-016-0956-4

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