Skip to main content
Erschienen in: Journal of Nanoparticle Research 8/2012

01.08.2012 | Research Paper

Relationship between crystal structure and luminescent properties of novel red emissive BiVO4:Eu3+ and its photocatalytic performance

verfasst von: Qianming Wang, Yan Li, Zhi Zeng, Shuting Pang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Crystalline BiVO4:Eu3+ nanomaterials have been successfully synthesized by four different methods: co-precipitation, hydrothermal, solvothermal, and reverse micelles. The relationship between crystal structure and luminescent properties was studied by X-ray diffraction and steady-state fluorescence. The data indicate that Eu3+ 5D0 → 7F2 red luminescence at 618 nm can be excited by visible light at 466 nm in BiVO4 host. Furthermore, it has been found that the encapsulation of europium(III) in tetragonal phase (BiVO4) results in enhanced luminescence intensities compared with monoclinic phase. Transmission electron microscopy showed rods with sizes ranging from nanometer to micrometer and nanospheres can be obtained under different experimental conditions.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
Zurück zum Zitat Anitha M, Ramakrishnan P, Chatterjee A, Alexander G, Singh H (2002) Spectral properties and emission efficiencies of GdVO4 phosphors. Appl Phys A 74:153–162CrossRef Anitha M, Ramakrishnan P, Chatterjee A, Alexander G, Singh H (2002) Spectral properties and emission efficiencies of GdVO4 phosphors. Appl Phys A 74:153–162CrossRef
Zurück zum Zitat Bierlein JD, Sleight AW (1975) Ferroelasticity in BiVO4. Solid State Commun 16:69–70CrossRef Bierlein JD, Sleight AW (1975) Ferroelasticity in BiVO4. Solid State Commun 16:69–70CrossRef
Zurück zum Zitat David WIF (1983) Ferroelastic phase transition in BiVO4: III. Thermodynamics. J Phys C Solid State Phys 16:5093–5118CrossRef David WIF (1983) Ferroelastic phase transition in BiVO4: III. Thermodynamics. J Phys C Solid State Phys 16:5093–5118CrossRef
Zurück zum Zitat Deki S, Lizuka S, Mizuhata M, Kajinami A (2005) Fabrication of nanostructured materials from aqueous solution by liquid phase deposition. J Electroanal Chem 584:38–43CrossRef Deki S, Lizuka S, Mizuhata M, Kajinami A (2005) Fabrication of nanostructured materials from aqueous solution by liquid phase deposition. J Electroanal Chem 584:38–43CrossRef
Zurück zum Zitat Feng X, Yang L, Zhang NC, Liu YL (2010) A facile one-pot hydrothermal method to prepare europium-doped titania hollow phosphors and their sensitized luminescence properties. J Alloys Compd 506:728–733CrossRef Feng X, Yang L, Zhang NC, Liu YL (2010) A facile one-pot hydrothermal method to prepare europium-doped titania hollow phosphors and their sensitized luminescence properties. J Alloys Compd 506:728–733CrossRef
Zurück zum Zitat Frost RL, Dermot A, Henry ML et al (2006) Raman spectroscopy of three polymorphs of BiVO4 clinobisvanite, dreyerite and pucherite, with comparisons to (VO4)3− bearing minerals namibite, pottsite and schumacherite. J Raman Spectrosc 37:722–732CrossRef Frost RL, Dermot A, Henry ML et al (2006) Raman spectroscopy of three polymorphs of BiVO4 clinobisvanite, dreyerite and pucherite, with comparisons to (VO4)3− bearing minerals namibite, pottsite and schumacherite. J Raman Spectrosc 37:722–732CrossRef
Zurück zum Zitat Hirota K, Komatsu G, Yamashita M, Takemura H, Yamaguchi O (1992) Formation, characterization and sintering of alkoxy-derived bismuth vanadate. Mater Res Bull 27:823–830CrossRef Hirota K, Komatsu G, Yamashita M, Takemura H, Yamaguchi O (1992) Formation, characterization and sintering of alkoxy-derived bismuth vanadate. Mater Res Bull 27:823–830CrossRef
Zurück zum Zitat Huang HH, Yan B (2006) Sol-gel synthesis of YxGd2_xSiO5:Eu3+ phosphors derived from the in situ assembly of multicomponent hybrid precursors. Opt Mater 28:556–559CrossRef Huang HH, Yan B (2006) Sol-gel synthesis of YxGd2_xSiO5:Eu3+ phosphors derived from the in situ assembly of multicomponent hybrid precursors. Opt Mater 28:556–559CrossRef
Zurück zum Zitat Huignard A, Gacoin T, Boilot JP (2000) Synthesis and luminescence properties of colloidal YVO4:Eu phosphors. Chem Mater 12:1090–1094CrossRef Huignard A, Gacoin T, Boilot JP (2000) Synthesis and luminescence properties of colloidal YVO4:Eu phosphors. Chem Mater 12:1090–1094CrossRef
Zurück zum Zitat Jia CJ, Sun LD, Luo F, Jiang XC, Wei LH, Yan CH (2004) Structural transformation induced improved luminescent properties for LaVO4:Eu nanocrystals. Appl Phys Lett 84:5305–5307CrossRef Jia CJ, Sun LD, Luo F, Jiang XC, Wei LH, Yan CH (2004) Structural transformation induced improved luminescent properties for LaVO4:Eu nanocrystals. Appl Phys Lett 84:5305–5307CrossRef
Zurück zum Zitat Jia CJ, Sun LD, Yan ZG, Pang YC, Lu SZ, Yan CH (2010) Monazite and zircon type LaVO4:Eu nanocrystals—synthesis, luminescent properties, and spectroscopic identification of the Eu3+ sites. Eur J Inorg Chem 2626–2635. doi:10.1002/ejic.201000038 Jia CJ, Sun LD, Yan ZG, Pang YC, Lu SZ, Yan CH (2010) Monazite and zircon type LaVO4:Eu nanocrystals—synthesis, luminescent properties, and spectroscopic identification of the Eu3+ sites. Eur J Inorg Chem 2626–2635. doi:10.​1002/​ejic.​201000038
Zurück zum Zitat Justel T, Nikol H, Ronda C (1998) New developments in the field of luminescent materials for lighting and displays. Angew Chem Int Ed 37:3084–3103CrossRef Justel T, Nikol H, Ronda C (1998) New developments in the field of luminescent materials for lighting and displays. Angew Chem Int Ed 37:3084–3103CrossRef
Zurück zum Zitat Kohtani S, Makino S (2002) Photocatalytic degradation of 4-n-nonylphenol under irradiation from solar simulator: comparison between BiVO4 and TiO2 photocatalysts. Chem Lett 7:660–661CrossRef Kohtani S, Makino S (2002) Photocatalytic degradation of 4-n-nonylphenol under irradiation from solar simulator: comparison between BiVO4 and TiO2 photocatalysts. Chem Lett 7:660–661CrossRef
Zurück zum Zitat Kudo A, Omori K, Kato H (1999) Novel aqueous process for preparation of crystal form-controlled and highly crystalline BiVO4 powder from layered vanadates at room temperature and its photocatalytic and photophysical properties. J Am Chem Soc 121:11459–11467CrossRef Kudo A, Omori K, Kato H (1999) Novel aqueous process for preparation of crystal form-controlled and highly crystalline BiVO4 powder from layered vanadates at room temperature and its photocatalytic and photophysical properties. J Am Chem Soc 121:11459–11467CrossRef
Zurück zum Zitat Lee GH, Kim TH, Yoon CL, Kang SH (2008) Effect of local environment and Sm3+-codoping on the luminescence properties in the Eu3+-doped potassium tungstate phosphor for white LEDs. J Lumin 128:1922–1926CrossRef Lee GH, Kim TH, Yoon CL, Kang SH (2008) Effect of local environment and Sm3+-codoping on the luminescence properties in the Eu3+-doped potassium tungstate phosphor for white LEDs. J Lumin 128:1922–1926CrossRef
Zurück zum Zitat Leroy CM, Cardinal T, Jubera V, Treguer-Delapierre M, Majimel J, Manaud JP, Backov R, Boissière C, Grosso D, Sanchez C, Viana B, Pellé F (2008) Europium-doped mesoporous titania thin films: rare-earth locations and emission fluctuations under illumination. Chem Phys Chem 9:2077–2084CrossRef Leroy CM, Cardinal T, Jubera V, Treguer-Delapierre M, Majimel J, Manaud JP, Backov R, Boissière C, Grosso D, Sanchez C, Viana B, Pellé F (2008) Europium-doped mesoporous titania thin films: rare-earth locations and emission fluctuations under illumination. Chem Phys Chem 9:2077–2084CrossRef
Zurück zum Zitat Manolikas C, Amelinckx S (1980) Ferroelastic domains in BiVO4. Phys Status Solidif 60:167–172CrossRef Manolikas C, Amelinckx S (1980) Ferroelastic domains in BiVO4. Phys Status Solidif 60:167–172CrossRef
Zurück zum Zitat Molina C, Dahmouche K, Santilli CV, Craievich AF, Ribeiro SJL (2001) Structure and luminescence of Eu3+-doped class I siloxane-poly(ethylene glycol) hybrids. Chem Mater 13:2818–2823CrossRef Molina C, Dahmouche K, Santilli CV, Craievich AF, Ribeiro SJL (2001) Structure and luminescence of Eu3+-doped class I siloxane-poly(ethylene glycol) hybrids. Chem Mater 13:2818–2823CrossRef
Zurück zum Zitat Neeraj S, Kijima N, Cheetham AK (2004) Novel red phosphors for solid state lighting; the system BixLn1−xVO4; Eu3+/Sm3+ (Ln = Y, Gd). Solid State Commun 131:65–69CrossRef Neeraj S, Kijima N, Cheetham AK (2004) Novel red phosphors for solid state lighting; the system BixLn1−xVO4; Eu3+/Sm3+ (Ln = Y, Gd). Solid State Commun 131:65–69CrossRef
Zurück zum Zitat Ren L, Jin L, Wang JB, Yang F, Qiu MQ, Yu Y (2009) Template-free synthesis of BiVO4 nanostructures: I. Nanotubes with hexagonal cross sections by oriented attachment and their photocatalytic property for water splitting under visible light. Nanotechnology 20:15603CrossRef Ren L, Jin L, Wang JB, Yang F, Qiu MQ, Yu Y (2009) Template-free synthesis of BiVO4 nanostructures: I. Nanotubes with hexagonal cross sections by oriented attachment and their photocatalytic property for water splitting under visible light. Nanotechnology 20:15603CrossRef
Zurück zum Zitat Riwotzki K, Haase M (1998) Wet-chemical synthesis of doped colloidal nanoparticles: YVO4:Ln (Ln = Eu, Sm, Dy). J Phys Chem B 102:10129–10135CrossRef Riwotzki K, Haase M (1998) Wet-chemical synthesis of doped colloidal nanoparticles: YVO4:Ln (Ln = Eu, Sm, Dy). J Phys Chem B 102:10129–10135CrossRef
Zurück zum Zitat Sayama K, Nomura A, Zou ZG, Abe R, Abe Y, Arakawa H (2003) Photoelectrochemical decomposition of water on nanocrystalline BiVO4 film electrodes under visible light. Chem Commun 23:2908–2910CrossRef Sayama K, Nomura A, Zou ZG, Abe R, Abe Y, Arakawa H (2003) Photoelectrochemical decomposition of water on nanocrystalline BiVO4 film electrodes under visible light. Chem Commun 23:2908–2910CrossRef
Zurück zum Zitat Shantha K, Varma KBR (1999) Preparation and characterization of nanocrystalline powders of bismuth vanadate. Mater Sci Eng B 60:66–75CrossRef Shantha K, Varma KBR (1999) Preparation and characterization of nanocrystalline powders of bismuth vanadate. Mater Sci Eng B 60:66–75CrossRef
Zurück zum Zitat Smith HM (2002) Toxicology and ecotoxicology issues with high performance pigments. In: High performance pigments Wiley, Weinheim, p 411–417 Smith HM (2002) Toxicology and ecotoxicology issues with high performance pigments. In: High performance pigments Wiley, Weinheim, p 411–417
Zurück zum Zitat Sun YF, Xie Y, Wu CZ, Long R (2010) First experimental identification of BiVO4·0.4H2O and its evolution mechanism to final monoclinic BiVO4. Cryst Growth Des 10:602–607CrossRef Sun YF, Xie Y, Wu CZ, Long R (2010) First experimental identification of BiVO4·0.4H2O and its evolution mechanism to final monoclinic BiVO4. Cryst Growth Des 10:602–607CrossRef
Zurück zum Zitat Tokunaga S, Kato H, Kudo A (2001) Selective preparation of monoclinic and tetragonal BiVO4 with Scheelite structure and their photocatalytic properties. Chem Mater 13:4624–4628CrossRef Tokunaga S, Kato H, Kudo A (2001) Selective preparation of monoclinic and tetragonal BiVO4 with Scheelite structure and their photocatalytic properties. Chem Mater 13:4624–4628CrossRef
Zurück zum Zitat Yan B, Su XQ (2006) Chemical co-precipitation synthesis of luminescent BixY1−xVO4:RE (RE = Eu3+, Dy3+, Er3+) phosphors from hybrid precursors. J Non Cryst Solids 352:30–31 Yan B, Su XQ (2006) Chemical co-precipitation synthesis of luminescent BixY1−xVO4:RE (RE = Eu3+, Dy3+, Er3+) phosphors from hybrid precursors. J Non Cryst Solids 352:30–31
Zurück zum Zitat Yu JQ, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–2169CrossRef Yu JQ, Kudo A (2006) Effects of structural variation on the photocatalytic performance of hydrothermally synthesized BiVO4. Adv Funct Mater 16:2163–2169CrossRef
Metadaten
Titel
Relationship between crystal structure and luminescent properties of novel red emissive BiVO4:Eu3+ and its photocatalytic performance
verfasst von
Qianming Wang
Yan Li
Zhi Zeng
Shuting Pang
Publikationsdatum
01.08.2012
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 8/2012
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-1076-1

Weitere Artikel der Ausgabe 8/2012

Journal of Nanoparticle Research 8/2012 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.