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Erschienen in: Journal of Materials Science: Materials in Electronics 19/2019

12.09.2019

RGO/PDA/Bi12O17Cl2–TiO2 composite membranes based on Bi12O17Cl2–TiO2 heterojunctions with excellent photocatalytic activity for photocatalytic dyes degradation and oil–water separation

verfasst von: Zongxue Yu, XiaoFang Feng, Xia Min, XiuHui Li, LiangYan Shao, HaoJie Zeng

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 19/2019

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Abstract

In the study, the reduced graphene oxide/graphitic Bi12O17Cl2–TiO2 heterojunctions sheet membrane(RGO/PDA/Bi12O17Cl2–TiO2) was fabricated by the dopamine modification and assembling the RGO/PDA/Bi12O17Cl2–TiO2 composites on the surface of commercial CA(cellulose acetate) membrane to degrade methylene blue (MB) and p-chlorophenol (4-CP) to harmless products. These membrane materials were comprehensively characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectra (DRS). The results showed that RGO/PDA/Bi12O17Cl2–TiO2 nanofiber membrane exhibited extremely high degradation performance with a good distribution of RGO/PDA/Bi12O17Cl2–TiO2 on the CA nanofiber membrane surface. Besides, the complete photodegradation of 100 mL MB (15 mg L−1) solution and 100 mL 4-CP (15 mg L−1) solution with artificial visible-light was achieved after 100 min and 160 min, respectively. The RGO/PDA/Bi12O17Cl2–TiO2-CA composite membrane revealed the ability of continuous and simultaneous flow-through separation of oil/water emulsion and degradation of soluble organic dye under visible-light irradiation in a short time. Moreover, the nanofiber membranes exhibited excellent stability and reusability for MB-containing oil–water mixed emulsion separation has great potential to be applied in industrial application.

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Metadaten
Titel
RGO/PDA/Bi12O17Cl2–TiO2 composite membranes based on Bi12O17Cl2–TiO2 heterojunctions with excellent photocatalytic activity for photocatalytic dyes degradation and oil–water separation
verfasst von
Zongxue Yu
XiaoFang Feng
Xia Min
XiuHui Li
LiangYan Shao
HaoJie Zeng
Publikationsdatum
12.09.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 19/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02179-y

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